Citation: HU Li-Fang, HE Jie, LIU Yuan, ZHAO Yun-Lei, CHEN Kai. Structural Features and Photocatalytic Performance of TiO₂-HNbMoO₆ Composite[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 737-744. doi: 10.3866/PKU.WHXB201512184 shu

Structural Features and Photocatalytic Performance of TiO₂-HNbMoO₆ Composite

HU Li-Fang ^1,2 ,
HE Jie ^1,, ,
LIU Yuan ¹ ,
ZHAO Yun-Lei ¹ ,
CHEN Kai ¹

1.
1 School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, Anhui Province P. R. China;
2.
2 School of Earth and Environment, Anhui University of Science and Technology, Huainan 232001, Anhui Province P. R. China

Corresponding author: HE Jie,
Received Date: 9 November 2015
Available Online: 14 December 2015
Fund Project: 国家自然科学基金(21271008) (21271008)国家级大学生创新创业训练计划项目(AH201410361062)资助 (AH201410361062)

A novel composite material TiO₂-HNbMoO₆ was prepared by an intercalation-pillar route. The phase and its microstructure, skeleton feature, spectral-response characteristics, and the interaction between interlayer species and nanosheets were characterized using powder X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), laser Raman spectroscopy (LRS), X-ray photoelectron spectroscopy (XPS), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), and H₂ temperature-programmed reduction (H₂-TPR). The specific surface areas of the samples were measured by N₂ adsorption-desorption isotherms. The synergistic effect between the host and the guest of the composites was evaluated by the degradation of methylene blue (MB) dye under simulated sunlight. The results, such as the increase of the d-spacing, the absence of TiO₂ crystalline phase, and the change of the Nb―O bond in the main body and the Ti―O bond in TiO₂ before and after composition, demonstrate that TiO₂ is uniformly dispersed in the interlayer of HNbMoO₆, indicating the interaction between the host laminates and the guest titanium oxide species. The specific surface area of the composite was four times that of its host material, the narrowing band gap, the better adsorption ability, and the superior photocatalytic activity of TiO₂-HNbMoO₆ were because of the synergistic effect between the host and the guest.
- HNbMoO₆,
- TiO₂,
- Composite structure,
- Photocatalysis,
- Synergistic effect
1. [1]
  (1) Hou, W. H.; Yan, Q. J.; Peng, B. C.; Fu, X. C. Acta Phys. -Chim. Sin. 1994, 10, 289. [侯文华, 颜其洁, 彭秉成, 傅献彩. 物理化学学报, 1994, 10, 289.] doi: 10.3866/PKU.WHXB19940401
2. [2]
  (2) He, J.; Li, Q. J.; Tang, Y.; Yang, P.; Li, A.; Li, R.; Li, H. Z.Appl. Catal. A-Gen. 2012, 443-444, 145. doi: 10.1016/j.apcata.2012.07.036
3. [3]
  (3) He, J.; Hu, L. F.; Tang, Y.; Li, H. Z.; Yang, P.; Li, Z. RSC Adv.2014, 4, 22334. doi: 10.1039/c4ra01482k
4. [4]
  (4) Wu, J. H.; Uchida, S.; Fujishiro, Y.; Yin, S.; Sato, T. J. Photochem. Photobiol. A 1999, 128, 129. doi: 10.1016/S1010-6030(99)00157-4
5. [5]
  (5) Wu, J. H.; Uchida, S.; Fujishiro, Y.; Yin, S.; Sato, T. Int. J. Inorg. Mater. 1999, 1, 253. doi: 10.1016/S1466-6049(99)00038-0
6. [6]
  (6) Wu, J. H.; Yin, S.; Lin, Y.; Lin, J. M.; Huang, M. L.; Sato, T. J. Mater. Sci. 2001, 36, 3055.
7. [7]
  (7) Wang, L. L.; Wu, J. H.; Li, T. H.; Cheng, Y. G.; Huang, M. L.; Lin. J. M. J. Porous Mat. 2005, 12, 23. doi: 10.1007/s10934-005-5229-9
8. [8]
  (8) Botella, P.; Solsona, B.; Nieto, J. M. L.; Concepción, P.; Jordá, J. L.; Doménech-Carbó, M. T. Catal. Today 2010, 158, 162. doi: 10.1016/j.cattod.2010.05.024
9. [9]
  (9) Murayama, T.; Chen, J.; Hirata, J.; Matsumoto, K.; Ueda, W.Catal. Sci. Technol. 2014, 4, 4250. doi: 10.1039/C4CY00713A
10. [10]
  (10) Zhang, H.; Liu, X. J.; Wang, R. L.; Mi, R.; Li, S. M.; Cui, Y.H.; Deng, Y. F.; Mei, J.; Liu, H. J. Power Sources 2015, 274, 1063. doi: 10.1016/j.jpowsour.2014.10.136
11. [11]
  (11) Alemán-Vázquez, L. O.; Hernández-Pérez, F.; Cano-Domínguez, J. L.; Rodríguez-Hernández, A.; García-Gutiérrez, J. L. Fuel 2014, 117, 463. doi: 10.1016/j.fuel.2013.08.085
12. [12]
  (12) Tian, H.; Wang, H. X.; Shi, W. M.; Xu, Y. Acta Phys. -Chim. Sin. 2014, 30, 1543. [田红, 王会香, 史卫梅, 徐耀.物理化学学报, 2014, 30, 1543.] doi: 10.3866/PKU.WXHB201406161
13. [13]
  (13) Kioka, K.; Honma, T.; Komatsu, T. Opt. Mater. 2011, 33, 1203. doi: 10.1016/j.optmat.2011.02.011
14. [14]
  (14) Hsu, S. M.; Wu, J. J.; Yung, S.W.; Chin, T. S.; Zhang, T.; Lee, Y. M.; Chu, C. M.; Ding, J. Y. J. Non-Cryst. Solids 2012, 358, 14. doi: 10.1016/j.jnoncrysol.2011.08.006
15. [15]
  (15) Idrees, F.; Cao, C.; Butt, F. K.; Tahir, M.; Shakir, I.; Rizwan, M.; Aslam, I.; Tanveer, M.; Ali, Z. Int. J. Hydrog. Energy2014, 39, 13174. doi: 10.1016/j.ijhydene.2014.06.142
16. [16]
  (16) Li, W.; Meitzner, G. D.; Borry, R.W.; Iglesia, E. J. Catal.2000, 191, 373. doi: 10.1006/jcat.1999.2795
17. [17]
  (17) Huang, H.; Wang, C.; Huang, J.; Wang, X.M.; Du, Y. K.; Yang, P. Nanoscale 2014, 6, 7274. doi: 10.1039/c4nr00505h
18. [18]
  (18) Usha, N.; Sivakumar, R.; Sanjeeviraja, C. Mat. Sci. Semicon. Proc. 2015, 30, 31. doi: 10.1016/j.mssp.2014.09.043
19. [19]
  (19) Ou, J. Z.; Campbell, J. L.; Yao, D.; Wlodarski, W.; Kalantarzadeh, K. J. Phys. Chem. C 2011, 115, 10757. doi: 10.1021/jp202123a
20. [20]
  (20) de Paiva, J. B., Jr.; Monteiro, W. R.; Zacharias, M. A.; Rodrigues, J. A. J.; Cortez, G. G. Braz. J. Chem. Eng. 2006, 4, 517.
21. [21]
  (21) Botto, I. L.; Cabello, C. I.; Thomas, H. J. Mater. Chem. Phys.1997, 47, 37. doi: 10.1016/S0254-0584(97)80025-9
22. [22]
  (22) Guan, J. Q.; Xu, C.; Wang, Z. Q.; Yang, Y.; Liu, Bo. Catal. Lett. 2008, 124, 428. doi: 10.1007/s10562-008-9496-3
23. [23]
  (23) Xu, B. L.; Fan, Y. N.; Liu, L.; Lin, M.; Chen, Y. Science in China (Series B) 2002, 32, 235. [许波连, 范以宁, 刘浏, 林明, 陈懿. 中国科学(B 辑), 2002, 32, 235.]
24. [24]
  (24) Fan, F. Q.; Meng, M.; Tian, Y.; Zheng, L. R.; Zhang, J.; Hu, T.D. Acta Phys.-Chim. Sin. 2015, 31, 1761. [范丰奇, 孟明, 田野, 郑黎荣, 张静, 胡天斗. 物理化学学报, 2015, 31, 1761.] doi: 10.3866/PKU.WHXB201507291
25. [25]
  (25) Sanderson, R. T. J. Chem. Educ. 1988, 65, 112. doi: 10.1021/ed065p112
26. [26]
  (26) Beccaria, A. M.; Poggi, G.; Castello, G. Brit. Corros. J. 1995, 30, 283. doi: 10.1179/000705995798113709
27. [27]
  (27) Wang, Q. Q.; Lin, B. Z.; Xu, B. H.; Li, X. L.; Chen, Z. J.; Pian, X. T. Microporous Mesoporous Mat. 2010, 130, 344. doi: 10.1016/j.micromeso.2009.11.033
28. [28]
  (28) Xu, Y.; Schoonen, M. A. A. Am. Mineral. 2000, 85, 543. doi: 10.2138/am-2000-0416
1. [1]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
2. [2]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
3. [3]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
4. [4]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
5. [5]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-0. doi: 10.3866/PKU.WHXB202310013
6. [6]
  Mingjie Lei , Wenting Hu , Kexin Lin , Xiujuan Sun , Haoshen Zhang , Ye Qian , Tongyue Kang , Xiulin Wu , Hailong Liao , Yuan Pan , Yuwei Zhang , Diye Wei , Ping Gao . Accelerating the reconstruction of NiSe₂ by Co/Mn/Mo doping for enhanced urea electrolysis. Acta Physico-Chimica Sinica, 2025, 41(8): 100083-0. doi: 10.1016/j.actphy.2025.100083
7. [7]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
8. [8]
  Ruolin CHENG , Yue WANG , Xiyao NIU , Huagen LIANG , Ling LIU , Shijian LU . Efficient photothermal catalytic CO₂ cycloaddition over W₁₈O₄₉/rGO composites. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1276-1284. doi: 10.11862/CJIC.20240424
9. [9]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
10. [10]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
11. [11]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
12. [12]
  Zhiqiang Wang , Yajie Gao , Tianjun Wang , Wei Chen , Zefeng Ren , Xueming Yang , Chuanyao Zhou . Photocatalyzed oxidation of water on oxygen pretreated rutile TiO₂(110). Chinese Chemical Letters, 2025, 36(4): 110602-. doi: 10.1016/j.cclet.2024.110602
13. [13]
  Jiatong Li , Linlin Zhang , Peng Huang , Chengjun Ge . Carbon bridge effects regulate TiO₂–acrylate fluoroboron coatings for efficient marine antifouling. Chinese Chemical Letters, 2025, 36(2): 109970-. doi: 10.1016/j.cclet.2024.109970
14. [14]
  Jia Wang , Qing Qin , Zhe Wang , Xuhao Zhao , Yunfei Chen , Liqiang Hou , Shangguo Liu , Xien Liu . P-Doped Carbon-Supported Zn_xP_yO_z for Efficient Ammonia Electrosynthesis under Ambient Conditions. Acta Physico-Chimica Sinica, 2024, 40(3): 2304044-0. doi: 10.3866/PKU.WHXB202304044
15. [15]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
16. [16]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
17. [17]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
18. [18]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005
19. [19]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-0. doi: 10.3866/PKU.WHXB202404030
20. [20]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(456)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Structural Features and Photocatalytic Performance of TiO2-HNbMoO6 Composite

Metrics

通讯作者: 陈斌, bchen63@163.com

Structural Features and Photocatalytic Performance of TiO₂-HNbMoO₆ Composite