Citation: ZHAO Sheng-Jun, ZHANG Wei, DENG Hui-Ning, LIU Wei. Layer-by-Layer Assembly of Graphene Oxide and Polyelectrolyte Composite Membranes for Monovalent Cation Separation[J]. Acta Physico-Chimica Sinica, ;2016, 32(3): 723-727. doi: 10.3866/PKU.WHXB201512141 shu

Layer-by-Layer Assembly of Graphene Oxide and Polyelectrolyte Composite Membranes for Monovalent Cation Separation

1.
1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, P. R. China;
2.
2 School of Marine Science and Engineering, Hebei University of Technology, Tianjin 300130, P. R. China

Corresponding author: DENG Hui-Ning,
Received Date: 28 September 2015
Available Online: 8 December 2015
Fund Project: 国家自然科学基金(20906017) (20906017)河北省自然科学基金(B2013202087,D2014202074) (B2013202087,D2014202074)天津市应用基础与前沿技术研究重点项目(14JCZDJC38900)资助 (14JCZDJC38900)

Graphene oxide (GO) composite membranes were fabricated via layer-by-layer (LBL) assembling poly(ethylenimine) (PEI) and a mixture of GO and poly(acrylic acid) (PAA) on a poly(acrylonitrile) (PAN) support membrane. The composite membranes and their application performance were characterized and evaluated. The X-ray powder diffraction (XRD) spectrum shows that GO was successfully synthesized by the modified Hummers method, and it was homogenously dispersed in the composite membranes. Scanning electron microscopy (SEM) shows the successful assembly of multiple polyelectrolyte PEI and a mixture of GO and PAA bilayers on the PAN support membrane. The ultraviolet-visible (UV-Vis) spectrum indicates that the uniformity and continuity of the composite membrane were enhanced with the increasing number of assembled layers. The hydrophilic and selectivity tests reveals that the addition of GO decreased the water contact angle and enhanced the selectivity for monovalent cations of the multilayer polyelectrolyte composite membranes. All these advantages combine to fabricate a high-flux, high selectivity, and anti-fouling composite membrane for separation applications and water softening.
- Multilayer structure,
- Layer-by-layer assembly,
- Deposition,
- Graphene oxide,
- Selectivity
1. [1]
  (1) Xu, Y. X.; Hong, W. J.; Bai, H.; Li, C.; Shi, G. Q. Carbon2009, 47, 3538. doi: 10.1016/j.carbon.2009.08.022
2. [2]
  (2) Lee, D. C.; Yang, H. N.; Park, S. H.; Kim, W. J. J. Membr. Sci.2014, 452, 20. doi: 10.1016/j.memsci.2013.10.018
3. [3]
  (3) Cao, C. H.; Daly, M.; Singh, C. V.; Sun, Y.; Filleter, T. Carbon2015, 81, 497. doi: 10.1016/j.carbon.2014.09.082
4. [4]
  (4) Liang, L.; Lu, Y.; Yao, W. S.; Zhang, X. T. Acta Phys. -Chim. Sin. 2015, 31, 1180. [梁祎, 卢赟, 姚维尚, 张学同. 物理化学学报, 2015, 31, 1180.] doi: 10.3866/PKU.WHXB201504146
5. [5]
  (5) Ji, T. H.; Sun, M.; Zou, L. F.; Ma, N. Mater. Lett. 2014, 120, 30. doi: 10.1016/j.matlet.2014.01.035
6. [6]
  (6) Dreyer, D. R.; Park, S. J.; Bielawski, C.W.; Ruoff, R. S.Chem. Soc. Rev. 2010, 39, 228. doi: 10.1039/B917103G
7. [7]
  (7) Nair, R. R.; Wu, H. A.; Jayaram, P. N.; Grigorieva, I. V.; Geim, A. K. Science 2012, 335, 442. doi: 10.1126/science.1211694
8. [8]
  (8) Mi, B. X. Science 2014, 343, 740. doi: 10.1126/science.1250247
9. [9]
  (9) Valentini, L. Mater. Lett. 2015, 157, 266. doi: 10.1016/j.matlet.2015.05.23
10. [10]
  (10) Li, W. Y.; He, Y. Q.; Li, Y. M. Acta Phys. -Chim. Sin. 2015, 31, 458. [李文有, 贺蕴秋, 李一鸣. 物理化学学报, 2015, 31, 458.] doi: 10.3866/PKU.WHXB201501093
11. [11]
  (11) Dikin, D. A.; Stankovich, S.; Zimney, E. J.; Piner, R. D.; Dommett, G. H. B.; Evmenenko, G.; Nguyen, S. T.; Ruoff, R.S. Nature 2007, 448, 458. doi: 10.1038/nature06016
12. [12]
  (12) Rajasekar, R.; Kim, N. H.; Jung, D.; Kuila, T.; Lim, J. K.; Park, M. J.; Lee, J. H. Compos. Sci. Technol. 2013, 89, 171. doi: 10.1016/j.compscitech.2013.10.004
13. [13]
  (13) Hu, M.; Mi, B. X. J. Membr. Sci. 2014, 469, 80. doi: 10.1016/j.memsci.2014.06.036
14. [14]
  (14) Hummers, W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017
15. [15]
  (15) Wang, J. D.; Peng, T. J.; Xian, H. Y.; Sun, H. J. Acta Phys. -Chim. Sin. 2015, 31, 91. [汪建德, 彭同江, 鲜海洋, 孙红娟. 物理化学学报, 2015, 31, 91.] doi: 10.3866/PKU.WHXB201411202
16. [16]
  (16) Goh, K. L.; Setiawan, L.; Wei, L.; Si, R. M.; Fane, A. G.; Wang, R.; Chen, Y. J. Membr. Sci. 2015, 474, 245. doi: 10.1016/j.memsci.2014.09.057
17. [17]
  (17) Zhou, T. N.; Chen, F.; Tang, C. Y.; Bai, H.W.; Zhang, Q.; Deng, H.; Fu, Q. Compos. Sci. Technol. 2011, 71, 1267. doi: 10.1016/j.compscitech.2011.04.016
18. [18]
  (18) Suresh, D.; Udayabhanu; Kumar, M. A. P.; Nagabhushana, H.; Sharma, S. C. Mater. Lett. 2015, 151, 93. doi: 10.1016/j.matlet.2015.03.035
19. [19]
  (19) Zhang, G. J.; Yan, H. H.; Ji, S. L.; Liu, Z. Z. J. Membr. Sci.2007, 292, 2. doi: 10.1016/j.memsci.2006.11.023
20. [20]
  (20) Wang, N. X.; Ji, S. L.; Zhang, G. J.; Li, J.; Wang, L. Chem. Eng. Technol. 2012, 213, 321. doi: 10.1016/j.cej.2012.09.080
21. [21]
  (21) Wang, X.; Guo, X. Y.; Shao, H. Q.; Zhou, Q. X.; Hu, W. L.; Song, X. J. Prog. Chem. 2015, 27, 1475. [王茜, 郭晓燕, 邵怀启, 周启星, 胡万里, 宋晓静. 化学进展, 2015, 27, 1475.] doi: 10.7536/PC150321
22. [22]
  (22) Schniepp, H. C.; Li, J. L.; McAllister, M. J.; Sai, H.; Herrera-Alonso, M.; Adamson, D. H.; Prud'homme, R. K.; Car, R.; Saville, D. A.; Aksay, I. A. J. Phys. Chem. 2006, 110, 8537. doi: 10.1021/jp060936f
23. [23]
  (23) Zhang, J. G.; Xu, Z.W.; Shan, M. J.; Zhou, B. M.; Li, Y. L.; Li, B. D.; Niu, J. R.; Qian, X. M. J. Membr. Sci. 2013, 448, 91. doi: 10.1016/j.memsci.2013.07.064
24. [24]
  (24) Ben Ameur, S.; Barhoumi, A.; Mimouni, R.; Amlouk, M.; Guermazi, H. Superlattice. Microst. 2015, 84, 110. doi: 10.1016/j.spmi.2015.04.028
25. [25]
  (25) Marmur, A. Langmuir 2004, 20, 3519. doi: 10.1021/la036369u
26. [26]
  (26) Malaisamy, R.; Talla-Nwafo, A.; Jones, K. L. Sep. Purif. Technol. 2011, 77, 370. doi: 10.1016/j.seppur.2011.01.005
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