Citation: SONG Bing-Lei, ZHAI Zhao-Lan, ZHAO Jian-Xi, SUN Guo-Jing. Interfacial Adsorption, Dilational Visco-Elasticity and Foam Stability in a Mixed System of Gemini Surfactant/C₁₂E_n[J]. Acta Physico-Chimica Sinica, ;2015, 31(12): 2324-2331. doi: 10.3866/PKU.WHXB201510231 shu

Interfacial Adsorption, Dilational Visco-Elasticity and Foam Stability in a Mixed System of Gemini Surfactant/C₁₂E_n

1.
1 The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China;
2.
2 Institute of Colloid and Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China

Corresponding author: ZHAO Jian-Xi,
Received Date: 19 August 2015
Available Online: 21 October 2015
Fund Project: 国家自然科学基金(21473032, 21273040)资助项目 (21473032, 21273040)

The mixed adsorption of a cationic gemini surfactant, ethanediyl-1,2-bis(dodecyldimethylammonium bromide) 12-2-12), and a nonionic surfactant, polyoxyethylene mono-dodecyl ether (C₁₂E_n, where n = 4, 10, 23) at the air/water interface was studied using surface tension measurements. The dilational viscoelastic properties of the films that formed at the air/water interface were examined using an interfacial rheology technique that was described using the Lucassen-van den Tempel (LVT) model. The values of the limit elasticity were fitted accordingly. Foams were generated by the mixed surfactant aqueous solutions and the stability of foams determined using the half-life. C₁₂E_n exhibited attractive interactions towards 12-2-12 within the adsorption films. The average minimum area (Amin) of the adsorbed molecules decreased in the order: 12-2-12/C₁₂E₂₃ > 12-2-12/C₁₂E₁₀ > 12-2-12/C₁₂E₄, while the limit elasticity decreased in the reverse order: ε_0,fit(12-2-12/C₁₂E₄) > ε_0,fit(12-2-12/C₁₂E₁₀) > ε_0,fit(12-2-12/C₁₂E₂₃) at a comparable concentration of the surfactant in the bulk. Compared with the film adsorbed by 12-2-12 alone, only 12-2-12/C₁₂E₄ form had denser structure. Thus, by adding the nonionic component C₁₂E₄, which contained a small hydrophilic head group, the interfacial elasticity of the 12-2-12 film increased significantly and the stability of the corresponding foams was effectively enhanced.
- Mixed adsorption,
- Cationic gemini surfactant,
- Nonionic conventional surfactant,
- Interfacial elasticity,
- Foam stability
1. [1]
  (1) Joye, J. L.; Hirasaki, G.; Miller, C. A. Langmuir 1994, 10, 3174. doi: 10.1021/la00021a046
2. [2]
  (2) Joye, J. L.; Hirasaki, G.; Miller, C. A. J. Colloid Interface Sci. 1996, 177, 542. doi: 10.1006/jcis.1996.0068
3. [3]
  (3) Bergeron, V. Langmuir 1997, 13, 3474. doi: 10.1021/la970004q
4. [4]
  (4) Espert, A.; Klitzing, R. V.; Poulin, P.; Colin, A.; Zana, R.; Langevin, D. Langmuir 1998, 14, 4251. doi: 10.1021/la9800957
5. [5]
  (5) Koelsch, P.; Motschmann, H. Langmuir 2005, 21, 6265. doi: 10.1021/la050459c
6. [6]
  (6) Sonin, A.; Bonfillon, A.; Langevin, D. J. Colloid Interface Sci. 1994, 162, 323. doi: 10.1006/jcis.1994.1046
7. [7]
  (7) Stubenrauch, C.; Miller, R. J. Phys. Chem. B 2004, 108, 6412. doi: 10.1021/jp049694e
8. [8]
  (8) Santini, E.; Ravera, F.; Ferrari, M.; Stubenrauch, C.; Makievski, A.; Krä gel, J. Colloids Surf. A 2007, 298, 12. doi: 10.1016/j.colsurfa.2006.12.004
9. [9]
  (9) Wang, L.; Yoon, R. H. Int. J. Miner. Process 2008, 85, 101.
10. [10]
  (10) Acharya, D. P.; Gutiérrez, J. M.; Aramaki, K.; Aratani, K.; Kunieda, H. J. Colloid Interface Sci. 2005, 291, 236. doi: 10.1016/j.jcis.2005.04.105
11. [11]
  (11) Georgieva, D.; Cagna, A.; Langevin, D. Soft Matter 2009, 5, 2063. doi: 10.1039/b822568k
12. [12]
  (12) Stenvot, C.; Langevin, D. Langmuir 1988, 4, 1179. doi: 10.1021/la00083a022
13. [13]
  (13) Monroy, F.; Giemanska Kahn, J.; Langevin, D. Colloids Surf. A 1998, 143, 251. doi: 10.1016/S0927-7757(98)00373-2
14. [14]
  (14) Wu, X. N.; Zhao, J. X.; Li, E. J.; Zou, W. S. Colloid Polym. Sci. 2011, 289 (9), 1025. doi: 10.1007/s00396-011-2425-9
15. [15]
  (15) You, Y.; Wu, X. N.; Zhao, J. X.; Ye, Y. Z.; Zou, W. S. Colloids Surf. A 2011, 384, 164. doi: 10.1016/j.colsurfa.2011.03.050
16. [16]
  (16) Wu, X. N.; Zou, W. S.; Zhao, J. X. Acta Phys. -Chim. Sin. 2012, 28, 1213. [吴晓娜, 邹文生, 赵剑曦. 物理化学学报, 2012, 28, 1213.] doi: 10.3866/PKU.WHXB201203053
17. [17]
  (17) Sharma, K. S.; Rodgers, C.; Palepu, R. M.; Rakshit, A. K. J. Colloid Interface Sci. 2003, 268, 482. doi: 10.1016/j.jcis.2003.07.038
18. [18]
  (18) Kabir-ud-Din; Sheikh, M. S.; Dar, A. A. Colloids Surf. A 2009, 333, 605. doi: 10.1016/j.jcis.2009.01.041
19. [19]
  (19) Kabir-ud-Din; Sheikh, M. S.; Dar, A. A. J. Phys. Chem. B 2010, 114, 6023. doi: 10.1021/jp909853u
20. [20]
  (20) Kabir-ud-Din; Sharma, G.; Naqvi, A. Z. Colloids Surf. A 2011, 385, 63. doi: 10.1016/j.colsurfa.2011.05.053
21. [21]
  (21) Rosen, M. J. Surfactants and Interfacial Phenomena; Wiley: New York, 1988
22. [22]
  (22) Holland, P. M.; Rubingh, D. N. Mixed Surfactant Systems, ACS symposium series 501, American Chemical Society, Washington DC, 1992.
23. [23]
  (23) Rubingh, D. N. In Solution Chemistry of Surfactants, 1st ed.; Plenum Press: New York, 1979; pp: 337-354.
24. [24]
  (24) Rosen, M. J.; Hua, X. Y. J. Colloid Interface Sci. 1982, 86, 164. doi: 10.1016/0021-9797(82)90052-2
25. [25]
  (25) Zana, R. J. Colloid Interface Sci. 2002, 248, 203. doi: 10.1006/jcis.2001.8104
26. [26]
  (26) Li, Z. X.; Dong, C. C.; Thomas, R. K. Langmuir 1999, 15, 4392. doi: 10.1021/la981551u
27. [27]
  (27) Sikirić , M.; Primǒ zič , I.; Filipović -Vinceković , N. J. Colloid Interface Sci. 2002, 250, 221. doi: 10.1006/jcis.2002.8304
28. [28]
  (28) Sun, Y.; Feng, Y.; Dong, H.; Chen, Z.; Han, L. Central Euro. J. Chem. 2007, 5, 620. doi: 10.2478/s11532-006-0072-7
29. [29]
  (29) Lucassen, J.; van den Tempel, M. Chem. Eng. Sci. 1972, 27, 1283. doi: 10.1016/0009-2509(72)80104-0
30. [30]
  (30) Monroy, F.; Rivillon, S.; Ortega, F.; Rubio, R. G. J. Chem. Phys. 2001, 115, 530. doi: 10.1063/1.1373643
31. [31]
  (31) Lucassen, J.; van den Tempel, M. J. Colloid Interface Sci. 1972, 41, 491. doi: 10.1016/0021-9797(72)90373-6
32. [32]
  (32) Kovalchuk, V. I.; Krä gel, J.; Makievski, A. V.; Ravera, F.; Liggieri, L.; Loglio, G.; Fainerman, V. B.; Miller, R. J. Colloid Interface Sci. 2004, 280, 498. doi: 10.1016/j.jcis.2004.08.004
33. [33]
  (33) Tehrani-Bagha, A. R.; Holmberg, K. Langmuir 2010, 26, 9276. doi: 10.1021/la1001336
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Interfacial Adsorption, Dilational Visco-Elasticity and Foam Stability in a Mixed System of Gemini Surfactant/C12En

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Interfacial Adsorption, Dilational Visco-Elasticity and Foam Stability in a Mixed System of Gemini Surfactant/C₁₂E_n