Citation: CHEN Feng-Ying, XIAO Li, YANG Cui-Xia, ZHUANG Lin. Preparation and Electrocatalytic Properties of Perovskite Type Oxides CaVO₃ for Oxygen Reduction Reaction[J]. Acta Physico-Chimica Sinica, ;2015, 31(12): 2310-2315. doi: 10.3866/PKU.WHXB201510162 shu

Preparation and Electrocatalytic Properties of Perovskite Type Oxides CaVO₃ for Oxygen Reduction Reaction

CHEN Feng-Ying ^1,2 ,
XIAO Li ^1,, ,
YANG Cui-Xia ¹ ,
ZHUANG Lin ^1,,

1.
1 College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, P. R. China;
2.
2 College of Chemical Engineering and Modern Materials/Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources, Shangluo University, Shangluo 726000, Shaanxi Province, P. R. China

Corresponding author: XIAO Li, ZHUANG Lin,
Received Date: 13 July 2015
Available Online: 15 October 2015
Fund Project: 国家自然科学基金(21273171) (21273171)商洛市科技计划基金(SK2014-01-09)资助项目 (SK2014-01-09)

The precursor powder of CaVO₃ was prepared by sol-gel method using vanadium pentoxide, calcium nitrate, citric acid, and oxalic acid as raw materials. The target product CaVO₃ was obtained by calcining the precursor powder in argon atmosphere at 1000 ℃. In order to determine the appropriate calcination temperature, thermal stability of the precursor powder was tested. The target product CaVO₃ was characterized by Fourier transform infrared (FTIR) spectrometry, thermogravimetry (TG), X-ray diffraction (XRD), and conductivity. In addition, the properties for oxygen reduction reaction (ORR) were also investigated, and the results showed that the electron transfer number of ORR on the modified electrode was 1.5-1.7, which indicating that ORR was a two-electron process.
- Perovskite,
- Sol-gel method,
- Oxygen reduction reaction
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Preparation and Electrocatalytic Properties of Perovskite Type Oxides CaVO3 for Oxygen Reduction Reaction

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Preparation and Electrocatalytic Properties of Perovskite Type Oxides CaVO₃ for Oxygen Reduction Reaction