Citation: WANG Xiao-Chen, WANG Ying-Ming, LIU Wei, BAI Ruo-Peng, LIU Yan-Fang, XIAO Li, LU Jun-Tao, ZHUANG Lin. Influence of 12-Crown-4 on Oxygen Electrode of Aprotic Li-O₂ Battery[J]. Acta Physico-Chimica Sinica, ;2016, 32(1): 343-348. doi: 10.3866/PKU.WHXB201510133 shu

Influence of 12-Crown-4 on Oxygen Electrode of Aprotic Li-O₂ Battery

1.
College of Chemistry and Molecular Sciences, Hubei Key Lab of Electrochemical Power Sources, Wuhan University, Wuhan 430072, P. R. China

Corresponding author: XIAO Li,
Received Date: 12 August 2015
Available Online: 9 October 2015
Fund Project: 国家重点基础研究发展规划项目(973)(2012CB932800,2012CB215500) (973)(2012CB932800,2012CB215500)国家自然科学基金(21125312,21203142,21573167) (21125312,21203142,21573167)国家教育部博士点专项基金(20110141130002) (20110141130002)中央高校基本科研业务费专项资金(2014203020207)资助 (2014203020207)

One of the major challenges with Li-O₂ batteries is that the discharge product, Li₂O₂, blocks the gas pathway because of its poor solubility in aprotic solvents. In this work, 12-crown-4 ether was used as an additive to capture Li⁺, and its influence on the solubility of the discharge products of the oxygen electrode was investigated. Multiple electrochemical methods, including cyclic voltammetry and rotatingring disk electrode, were used. The results show that the addition of only 5% of 12-crown-4 ether significantly improves the stability of the oxygen reduction product O₂^-, and decreases the formation of solid Li₂O₂. We used a combination of the hard-soft-acid-base theory and ab initio calculations to explain these observations.
- Li-O₂ battery,
- Oxygen electrode,
- Crown ether,
- Hard-soft-acid-base theory
1. [1]
  (1) Abraham, K. M.; Jiang, Z. J. Electrochem. Soc. 1996, 143, 1. doi: 10.1149/1.1836378
2. [2]
  (2) Girishkumar, G.; McCloskey, B.; Luntz, A. C.; Swanson, S.; Wilcke, W. J. Phys. Chem. C 2010, 1, 2193.
3. [3]
  (3) Wang, Y. G.; Zhou, H. S. J. Power Sources 2010, 195, 358. doi: 10.1016/j.jpowsour.2009.06.109
4. [4]
  (4) Ogasawara, T.; Debart, A.; Holzapfel, M.; Novak, P.; Bruce, P. G. J. Am. Chem. Soc. 2006, 128, 1390. doi: 10.1021/ja056811q
5. [5]
  (5) Leskes, M.; Drewett, N. E.; Hardwick, L. J.; Bruce, P. G.; Goward, G. R.; Grey, C. P. Angew. Chem. Int. Edit. 2012, 51, 8560. doi: 10.1002/anie.201202183
6. [6]
  (6) Choi, N.; Chen, Z. H.; Freunberger, S. A.; Ji, X. L.; Sun, Y.; Amine, K.; Yushin, G.; Nazar, L. F.; Cho, J.; Bruce, P. G. Angew. Chem. Int. Edit. 2012, 51, 9994. doi: 10.1002/anie.201201429
7. [7]
  (7) Yoshino, A. Angew. Chem. Int. Edit. 2012, 51, 5798. doi: 10.1002/anie.201105006
8. [8]
  (8) Wang, Z. L.; Xu, D.; Xu, J. J.; Zhang, L. L.; Zhang, X. B. Adv. Funct. Mater. 2012, 22, 3699. doi: 10.1002/adfm.v22.17
9. [9]
  (9) Shao, Y. Y.; Ding, F.; Xiao, J.; Zhang, J.; Xu, W.; Park, S.; Zhang, J. G.; Wang, Y.; Liu, J. Adv. Funct. Mater. 2013, 23, 987. doi: 10.1002/adfm.v23.8
10. [10]
  (10) Park, M.; Sun, H.; Lee, H.; Lee, J.; Cho, J. Adv. Funct. Mater. 2012, 2, 780.
11. [11]
  (11) Cao, R. G.; Lee, J.; Liu, M. L.; Cho, J. Adv. Funct. Mater. 2012, 2, 816.
12. [12]
  (12) Oh, S. H.; Nazar, L. F. Adv. Funct. Mater. 2012, 2, 903.
13. [13]
  (13) Lim, H.; Park, K.; Song, H.; Jang, E. Y.; Gwon, H.; Kim, J.; Kim, Y. H.; Lima, M. D.; Robles, R. O.; Lepró, X.; Baughman, R. H.; Kang, K. Adv. Mater. 2013, 25, 1348. doi: 10.1002/adma.v25.9
14. [14]
  (14) Shao, Y. Y.; Park, S.; Xiao, J.; Zhang, J. G.; Wang, Y.; Liu, J. ACS Catal. 2012, 2, 844. doi: 10.1021/cs300036v
15. [15]
  (15) Schaetz, A.; Zeltner, M.; Stark, W. J. ACS Catal. 2012, 2, 1267. doi: 10.1021/cs300014k
16. [16]
  (16) Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J. M. Nat. Mater. 2011, 11, 19. doi: 10.1038/nmat3191
17. [17]
  (17) Ren, X. D.; Wu, Y. Y. J. Am. Chem. Soc. 2013, 135, 2923. doi: 10.1021/ja312059q
18. [18]
  (18) Hartmann, P.; Bender, C. L.; Vracar, M.; Dürr, A. K.; Garsuch, A.; Janek, J.; Adelhelm, P. Nat. Mater. 2013, 12, 228.
19. [19]
  (19) Li, C. M.; Fontaine, O.; Freunberger, S. A.; Johnson, L.; Grugeon, S.; Laruelle, S.; Bruce, P. G.; Armand, M. J. Phys. Chem. C 2014, 118, 3393.
20. [20]
  (20) Laoire, C.; Mukerjee, S.; Plichta, E. J.; Hendrickson, M. A.; Abraham, K. M. J. Electrochem. Soc. 2011, 158, A302.
21. [21]
  (21) Aetukuri, N. B.; McCloskey, B. D.; García, J. M.; Krupp, L. E.; Viswanathan, V.; Luntz, A. C. Nat. Chem. 2015, 7, 50.
22. [22]
  (22) Liu, T.; Leskes, M.; Yu, W. J.; Moore, A. J.; Zhou, L. N.; Bayley, P. M.; Kim, G.; Grey, C. P. Science 2015, 350, 530. doi: 10.1126/science.aac7730
23. [23]
  (23) Li, L. F.; Lee, H. S.; Li, H.; Yang, X. Q.; Huang, X. J. Electrochem. Commun. 2009, 11, 2296. doi: 10.1016/j.elecom.2009.10.015
24. [24]
  (24) Zheng, D.; Lee, H. S.; Yang, X. Q.; Qu, D. Electrochem. Commun. 2013, 28, 17. doi: 10.1016/j.elecom.2012.12.003
25. [25]
  (25) Shanmukaraj, D.; Grugeon, S.; Gachot, G.; Laruelle, S.; Mathiron, D.; Tarascon, J. M.; Armand, M. J. Am. Chem. Soc. 2010, 132, 3055. doi: 10.1021/ja9093814
26. [26]
  (26) Xie, B.; Lee, H. S.; Li, H.; Yang, X. Q.; McBreen, J.; Chen, L. Q. Electrochem. Commun. 2008, 10, 1195. doi: 10.1016/j.elecom.2008.05.043
27. [27]
  (27) Lopez, N.; Graham, D. J.; McGuire, R., Jr.; Alliger, G. E.; Yang, S. H.; Cummins, C. C.; Nocera, D. G. Science 2012, 335, 3243.
28. [28]
  (28) Schmidt, M. W.; Baldridge, K. K.; Boatz, J. A.; Elbert, S. T.; Gordon, M. S.; Jensen, J. H.; Koseki, S.; Matsunaga, N.; Nguyen, K. A.; Su, S. J.; Windus, T. L.; Dupuis, M. J. Comput. Chem. 1993, 14, 1347.
29. [29]
  (29) Laoire, C. O.; Mukerjee, S.; Abraham, K. M.; Plichta, E. J.; Hendrickson, M. A. J. Phys. Chem. C 2010, 114, 9178. doi: 10.1021/jp102019y
30. [30]
  (30) Trahan, M. J.; Mukerjee, S.; Plichta, E. J.; Hendrickson, M. A.; Abrahama, K. M. J. Electrochem. Soc. 2013, 160, A259.
31. [31]
  (31) Allen, C. J.; Hwang, J.; Kautz, R.; Mukerjee, S.; Plichta, E. J.; Hendrickson, M. A.; Abraham, K. M. J. Phys. Chem. C 2012, 116, 20755. doi: 10.1021/jp306718v
32. [32]
  (32) Herranz, J.; Garsuch, A.; Gasteiger, H. A. J. Phys. Chem. C 2012, 116, 19084.
33. [33]
  (33) Albery, J. W.; Hitchman, L. M.; Ulstrup, J. Trans. Faraday Soc. 1968, 64, 2831. doi: 10.1039/tf9686402831
34. [34]
  (34) Bard, J.; Faulkner, L. R. Electrochemical Methods: Fundamentals & Applications, 2nd ed.; Wiley: Hoboken, 2001; p 669.
35. [35]
  (35) Pearson, G. R. J. Am. Chem. Soc. 1963, 85, 3533. doi: 10.1021/ja00905a001
36. [36]
  (36) Freunberger, S. A.; Chen, Y. H.; Drewett, N. E.; Hardwick, L. J.; Bardé F.; Bruce, P. G. Angew. Chem. Int. Edit. 2011, 50, 8609. doi: 10.1002/anie.201102357
37. [37]
  (37) Peng, Z. Q.; Freunberger, S. A.; Hardwick, L. J.; Chen, Y. H.; Giordani, V.; Bardé, F.; Novák, P.; Graham, D.; Tarascon, J. M.; Bruce, P. G. Angew. Chem. Int. Edit. 2011, 50, 6351. doi: 10.1002/anie.201100879
1. [1]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
2. [2]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
3. [3]
  Yuhao Chen , Zhuo Cheng , Qijun Hu , Jian Pei . 酸碱理论的发展历程. University Chemistry, 2025, 40(8): 368-375. doi: 10.12461/PKU.DXHX202412001
4. [4]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
5. [5]
  Wuxin Bai , Qianqian Zhou , Zhenjie Lu , Ye Song , Yongsheng Fu . Co-Ni Bimetallic Zeolitic Imidazolate Frameworks Supported on Carbon Cloth as Free-Standing Electrode for Highly Efficient Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305041-0. doi: 10.3866/PKU.WHXB202305041
6. [6]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
7. [7]
  Jiamin Li , Wenyue Zhong , Kin Shing Chan . “烯”君入瓮又入学——据元素周期表与酸碱理论谈烯烃教学. University Chemistry, 2025, 40(6): 177-182. doi: 10.12461/PKU.DXHX202408040
8. [8]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
9. [9]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
10. [10]
  Yan Xin , Yunnian Ge , Zezhong Li , Qiaobao Zhang , Huajun Tian . Research Progress on Modification Strategies of Organic Electrode Materials for Energy Storage Batteries. Acta Physico-Chimica Sinica, 2024, 40(2): 2303060-0. doi: 10.3866/PKU.WHXB202303060
11. [11]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 695-701. doi: 10.11862/CJIC.20240302
12. [12]
  Hao Chen , Dongyue Yang , Gang Huang , Xinbo Zhang . Progress on Liquid Organic Electrolytes of Li-O₂ Batteries. Acta Physico-Chimica Sinica, 2024, 40(7): 2305059-0. doi: 10.3866/PKU.WHXB202305059
13. [13]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
14. [14]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d-Band Center Regulated O₂ Adsorption on Transition Metal Single Atoms Loaded COF: A DFT Study. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-0. doi: 10.3866/PKU.WHXB202407013
15. [15]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
16. [16]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021
17. [17]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
18. [18]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
19. [19]
  Jianqiao ZHANG , Yang LIU , Yan HE , Yaling ZHOU , Fan YANG , Shihui CHENG , Bin XIA , Zhong WANG , Shijian CHEN . Ni-doped WP₂ nanowire self-standingelectrode: Preparation and alkaline electrocatalytic hydrogen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1610-1616. doi: 10.11862/CJIC.20240444
20. [20]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell. Acta Physico-Chimica Sinica, 2025, 41(1): 100005-0. doi: 10.3866/PKU.WHXB202309037

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(442)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of 12-Crown-4 on Oxygen Electrode of Aprotic Li-O2 Battery

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of 12-Crown-4 on Oxygen Electrode of Aprotic Li-O₂ Battery