Citation: YU Hua-Feng, ZHANG Guo-Pei, HAN Li-Na, CHANG Li-Ping, BAO Wei-Ren, WANG Jian-Cheng. Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NO_x from Vehicle Exhaust[J]. Acta Physico-Chimica Sinica, ;2015, 31(11): 2165-2173. doi: 10.3866/PKU.WHXB201509184 shu

Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NO_x from Vehicle Exhaust

1.
1 Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, P. R. China;
2.
2 College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China

Corresponding author: WANG Jian-Cheng,
Received Date: 19 August 2015
Available Online: 17 September 2015
Fund Project: 国家自然科学基金(20906067) (20906067)山西省高校 “131” 领军人才工程和山西省回国留学人员科研项目(2015-039)资助 (2015-039)

Cu-SSZ-13 catalysts had been prepared by using a microwave irradiation (MW) method and a conventional hydrothermal (CH) method, which were applied to removal of NO_x from diesel vehicles by NH₃. The physical and chemical properties of the samples were characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, H₂ temperature-programmed reduction (H₂-TPR), electron paramagnetic resonance (EPR), NH₃ temperature-programmed desorption (NH₃-TPD), inductively coupled plasma-mass spectroscopy (ICP-MS), and X-ray photoelectron spectroscopy (XPS). The MW had some significant advantages, greatly shortening the crystallization time of SSZ-13 and improving its physical and chemical properties. The sample synthesized using MW with a crystallization time of 9 h had similar crystallinity to that synthesized by the CH with a crystallization time of 72 h. The sample synthesized by the MW had improved pore structure and amounts of Lewis (L) acid and Brönsted (B) acid. The great increase in Cu load as an active component indicated that the MW enhanced the ability of SSZ-13 to perform Cu exchange. The Cu-SSZ-13 synthesized by MW had improved low-temperature activity and anti-aging ability.
- Microwave irradiation method,
- Conventional hydrothermal method,
- Cu-SSZ-13,
- DeNO_x,
- Hydrothermal aging
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Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NOx from Vehicle Exhaust

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通讯作者: 陈斌, bchen63@163.com

Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NO_x from Vehicle Exhaust