Citation: MA Yi-Ran, ZHOU Wei, CAO Wei, ZHENG Jin-Long, GUO Lin. Preparation of Hierarchical Ni@CuS Composites and the Application of the Enhanced Catalysis for 4-Nitrophenol Reduction[J]. Acta Physico-Chimica Sinica, ;2015, 31(10): 1949-1955. doi: 10.3866/PKU.WHXB201509091 shu

Preparation of Hierarchical Ni@CuS Composites and the Application of the Enhanced Catalysis for 4-Nitrophenol Reduction

1.
School of Chemistry and Environment, Beihang University, Beijing 100191, P. R. China

Received Date: 24 July 2015
Available Online: 9 September 2015
Fund Project: 国家自然科学基金(11079002, 51472014) (11079002, 51472014)高等学校全国优秀博士学位论文作者专项资金(201331)资助项目 (201331)

Three types of hierarchical, flower-like CuS particles were prepared by a hydrothermal method and samples were formulated as thin nanosheets. The aggregation density of the sheets could be readily controlled with the aid of polyvinylpyrrolidone (PVP) or 1,3,5-benzenetricarboxylic acid (BTC) organic molecules. The three substrates were then used for the growth of nickel nanocatalysts and the structures of the composites characterized by environment scanning electron microscopy (SEM), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Ultraviolet-visible absorption spectrometry was applied to study the catalytic reduction of 4-nitrophenol. Results show that a sample of Ni nanoparticles (Ni NPs, ~5 nm in diameter) grown on CuS micro-flowers, composed of the sparsest nanosheets (Ni@SUB2) with an ultralow loading of 0.469% (w), showed the best catalytic properties amongst the three Ni@SUB composites. During reduction of 4-nitrophenol with initial 4-nitrophenol concentrations of 0.2 mmol·L^-1, the Ni@SUB2 showed almost 100% transformation within 4 min, while the same quantity of pure Ni NPs showed a transformation of only ~43%. The enhanced catalytic properties for 4-nitrophenol degradation could be ascribed to well-dispersed Ni NPs supported on the CuS substrate providing greater numbers of catalytic active sites. Furthermore, because of CuS is insoluble, it can be easily collected by centrifugation, which can be environmentally beneficial.
- Substrate,
- Copper sulfide,
- Nickel,
- Nano-catalyst,
- 4-Nitrophenol
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沈阳化工大学材料科学与工程学院沈阳 110142