Citation: ZHANG Jie, DOU Mei-Ling, WANG Feng, LIU Jing-Jun, LI Zhi-Lin, JI Jing, SONG Ye. Synthesis of PDDA-Decorating MWCNTs Supported Pt Electrocatalysts and Catalytic Properties for Oxygen Reduction Reaction in Alkaline Medium[J]. Acta Physico-Chimica Sinica, ;2015, 31(9): 1727-1732. doi: 10.3866/PKU.WHXB201507161 shu

Synthesis of PDDA-Decorating MWCNTs Supported Pt Electrocatalysts and Catalytic Properties for Oxygen Reduction Reaction in Alkaline Medium

1.
State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received Date: 6 May 2015
Available Online: 16 July 2015
Fund Project: 国家自然科学基金(51125007)资助项目 (51125007)

Multi-walled carbon nanotubes (MWCNTs) were modified with the long-chain polymer poly (diallyldimethylammonium chloride) (PDDA) and used as support for Pt nanoparticles (NPs). Pt/PDDA/ MWCNTs electrocatalysts were prepared by electrostatic adsorption of Pt NPs on the PDDA/MWCNTs support. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) characterization revealed that the Pt NPs were well dispersed on the PDDA/MWCNTs support, with an average diameter of ~3.6 nm. Thermo gravimetric analysis showed that the loading of Pt was 36%(w). Rotating disk electrode (RDE) measurements showed that the Pt/PDDA/MWCNTs catalyst had excellent electrocatalytic activity for oxygen reduction in alkaline medium. Compared with commercial Pt/C (40%(w)), the Pt/PDDA/MWCNTs catalyst exhibited a positive shift of 30 mV for the oxygen reduction onset and half-wave potential. Kinetics study further confirmed the significantly enhanced oxygen reduction activity of the Pt/PDDA/MWCNTs catalyst in the alkaline medium.
- Platinum,
- Poly(diallyldimethylammonium chloride),
- Multi-walled carbon nanotubes,
- Oxygen reduction reaction
1. [1]
  
  (1) Ma, Y.; Wang, R.; Wang, H.; Key, J.; Ji, S. J. Power Sources 2015, 280, 526. doi: 10.1016/j.jpowsour.2015.01.139
2. [2]
  (2) Shrestha, S.; Asheghi, S.; Timbro, J.; Mustain, W. E. Appl. Catal. A 2013, 464-465, 233.
3. [3]
  (3) Balgis, R.; Anikumar, G. M.; Sa , S.; Ogi, T.; Okuyama, K. J. Power Sources 2013, 229, 58. doi: 10.1016/j.jpowsour. 2012.11.143
4. [4]
  (4) Dominguez, C.; Perez-Alonso, F. J.; Fuente, J. L. G.; Al-Thabaiti, S. A.; Basahel, S. N.; Alyoubi, A. O.; Alshehri, A. A.; Pena, M. A.; Rojas, S. J. Power Sources2014, 271, 87. doi: 10.1016/j.jpowsour.2014.07.173
5. [5]
  (5) El-Deeb, H.; Bron, M. Electrochim. Acta 2015, 164, 315. doi: 10.1016/j.electacta.2015.02.137
6. [6]
  (6) Andersen, N. I.; Serov, A.; Atanassov, P. Appl. Catal. B 2015, 163, 623. doi: 10.1016/j.apcatb.2014.08.033
7. [7]
  (7) Jukk, K.; Kozlova, J.; Ritslaid, P.; Sammelselg, V.; Alexeyeva, N.; Tammeveski, K. J. Electroanal. Chem. 2013, 708, 31. doi: 10.1016/j.jelechem.2013.09.009
8. [8]
  (8) Shao, Y.; Zhang, S.; Kou, R.; Wang, X.; Wang, C.; Dai, S.; Viswanathan, V.; Liu, J.; Wang, Y.; Lin, Y. J. Power Sources 2010, 195, 1805. doi: 10.1016/j.jpowsour.2009.10.036
9. [9]
  (9) Zhang, S.; Shao, Y.; Yin, G.; Lin, Y. J. Mater. Chem. 2009, 19, 7995. doi: 10.1039/b912104h
10. [10]
  (10) Zhao, B. Q.; Chen, W. M.; Zhu, Z. Y. Transitiona of Shenyang Li ng University 2014, 33 (4), 1. [赵博琪, 陈维民, 朱振玉. 沈阳理工大学学报, 2014, 33 (4), 1.]
11. [11]
  (11) Bragaru, A.; Vasile, E.; Obreja, C.; Kusko, M.; Danila, M.; Radoi, A. Mater. Chem. Phys. 2014, 146, 538. doi: 10.1016/j.matchemphys.2014.04.012
12. [12]
  (12) Zhu, H.; Yang, D.; Zhang, H. Mater. Lett. 2006, 60, 2686. doi: 10.1016/j.matlet.2006.01.065
13. [13]
  (13) Yang, H. N.; Lee, J. Y.; Na, Y.; Yi, S. C.; Kim, W. J. Microporous Mesoporous Mat. 2012, 152, 148. doi: 10.1016/j.micromeso.2011.11.042
14. [14]
  (14) Huang, X.; Li, Z.; Zhang, X.; He, X.; Lin, S. J. Colloid Interface Sci. 2013, 393, 300. doi: 10.1016/j.jcis.2012.10.058
15. [15]
  (15) Bard, A. J.; Faulkner, L. R. Electrochemical Methods, 2nd ed.; Wiley: New York, 2001.
16. [16]
  (16) Liu, H.; Li, J.; Xu, X.; Wang, F.; Liu, J.; Li, Z.; Ji, J. Electrochim. Acta 2013, 93, 25. doi: 10.1016/j.electacta. 2013.01.090
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Shiyang He , Dandan Chu , Zhixin Pang , Yuhang Du , Jiayi Wang , Yuhong Chen , Yumeng Su , Jianhua Qin , Xiangrong Pan , Zhan Zhou , Jingguo Li , Lufang Ma , Chaoliang Tan . Pt Single-Atom-Functionalized 2D Al-TCPP MOF Nanosheets for Enhanced Photodynamic Antimicrobial Therapy. Acta Physico-Chimica Sinica, 2025, 41(5): 100046-0. doi: 10.1016/j.actphy.2025.100046
3. [3]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
4. [4]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
5. [5]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
6. [6]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
7. [7]
  Xiaoyang Li , Xiaowei Huang , Yimeng Zhang , Huan Liu , Shao Jin , Junpeng Zhuang . Comprehensive Chemical Experiments on the Synthesis of 1,3-Dibromo-5,5-Dimethylhydantoin and Its Application as a Brominating Reagent. University Chemistry, 2025, 40(7): 286-293. doi: 10.12461/PKU.DXHX202408035
8. [8]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
9. [9]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 2408015-0. doi: 10.3866/PKU.WHXB202408015
10. [10]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
11. [11]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
12. [12]
  Tingbo Wang , Yao Luo , Bingyan Hu , Ruiyuan Liu , Jing Miao , Huizhe Lu . Quantitative Computational Study on the Claisen Rearrangement Reaction of Allyl Phenyl Ethers: An Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(11): 278-285. doi: 10.12461/PKU.DXHX202403082
13. [13]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
14. [14]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
15. [15]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
16. [16]
  Xiaoxuan Yu , Wukun Liu . Practice of Ideological and Political Education in Medicinal Chemistry for Pharmacy Administration Major: A Case Study on the Discovery of Cisplatin’s Anticancer Function. University Chemistry, 2025, 40(4): 408-414. doi: 10.12461/PKU.DXHX202405200
17. [17]
  Aiyi Xin , Jiawei Li , Xinyang Ran , Chuanjiang Fu , Zhiguo Wang . Collaborative Science and Education Based Experimental Design in Organic Chemistry: A Case Study of the Nucleophilic Substitution Reaction of 2-Hydroxymethyl-4,6-Di-Tert-Butylphenol. University Chemistry, 2025, 40(5): 366-375. doi: 10.12461/PKU.DXHX202407031
18. [18]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 2310029-0. doi: 10.3866/PKU.WHXB202310029
19. [19]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
20. [20]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005

Get Citation

PDF

XML

Metrics

PDF Downloads(226)
Abstract views(769)
HTML views(76)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142