Citation: SHANG Ming-Feng, DUAN Pei-Quan, ZHAO Tian-Tian, TANG Wen-Chao, LIN Rui, HUANG Yu-Ying, WANG Jian-Qiang. In Situ XAFS Methods for Characterizing Catalyst Structure in Proton Exchange Membrane Fuel Cell[J]. Acta Physico-Chimica Sinica, ;2015, 31(8): 1609-1614. doi: 10.3866/PKU.WHXB201505252 shu

In Situ XAFS Methods for Characterizing Catalyst Structure in Proton Exchange Membrane Fuel Cell

1.
1. Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, P. R. China;
2. School of Automotive Studies, Tongji University, Shanghai 201804, P. R. China

Received Date: 12 February 2015
Available Online: 25 May 2015
Fund Project: 国家重点基础研究发展规划项目(973) (2013CB933104) (973) (2013CB933104)国家自然科学基金(91127001, 11079005)资助 (91127001, 11079005)

We established and developed an in situ X-ray absorption fine structure (XAFS) experimental testing device for characterizing hydrogen-oxygen proton exchange membrane fuel cells (PEMFC) on XAFS beamline BL14W1 at the Shanghai Synchrotron Radiation Facility (SSRF). XAFS data were collected under the operating state of the fuel cell with Pt/C and Pd/C as the cathode and anode catalysts, respectively, while the cell current-voltage (J-V) Curve and power density curves were monitored. Changes in the oxidation states of the Pt/C catalyst were observed during the reaction process at different potentials. Strong Pt-O bonds on the surfaces of the Pt were found to be induced at high potential; this may hinder the performance of Pt and reduce its oxygen reduction reaction (ORR) activity. The study also verified the reliability and feasibility of the herein established experimental apparatus and technique.
- X-ray absorption fine structure,
- In situ,
- Proton exchange membrane fuel cell,
- Catalyst
1. [1]
  
  (1) Fu, X. C.; Sheng, W. X.; Yao, T. Y. Physical Chemistry, Volume II; Higher Education Press: Beijing, 2006; pp 141-143. [傅献彩, 沈文霞, 姚天杨. 物理化学. 下册. 北京: 高等教育出版社, 2006: 141-143.]
2. [2]
  (2) Ryan, O. H.; Whitney, C.; Fritz, B. P. Fuel Cell Fundamentals; translated by Wang, X. H.; Huang, H. Publishing House of Electronics Industry: Beijing, 2007; pp 6-7. [Ryan, O. H.; Whitney. C.; Fritz, B. P. 燃料电池基础. 王晓红, 黄宏, 译. 北京: 电子工业出版社, 2007: 6-7.]
3. [3]
  (3) Roth, C.; Martz, N.; Buhrmester, T.; Scherer, J.; Fuess, H. J. Phys. Chem. C 2002, 4 (15), 3555.
4. [4]
  (4) Stoupin, S.; Chung, E. H.; Chattopadhyay, S.; Segre, C. U.; Smotkin, E. S. J. Phys. Chem. B 2006, 110 (20), 9932. doi: 10.1021/jp057047x
5. [5]
  (5) Scott, F. J.; Roth, C.; Ramaker, D. E. J. Phys. Chem. C 2007, 111 (30), 11403. doi: 10.1021/jp072698+
6. [6]
  (6) Lin, R.; Cao, C. H.; Zhao, T. T.; Huang, Z.; Li, B. J. Power Sources 2013, 223, 190. doi: 10.1016/j.jpowsour.2012.09.073
7. [7]
  (7) Cao, C. H.; Lin, R; Zhao, T. T.; Huang, Z.; Ma, J. X. Acta Phys. -Chim. Sin. 2013, 29, 1. [曹春晖, 林瑞, 赵天天, 黄真, 马建新. 物理化学学报, 2013, 29, 1.] doi: 10.3866/PKU.WHXB 201209272
8. [8]
  (8) Shao, M. H.; Adzic, R. R. J. Phys. Chem. B 2005, 109, 16563. doi: 10.1021/jp053450s
9. [9]
  (9) Smith, M. C.; Gilbert, J. A.; Mawdsley, J. R.; Seifert, S.; Myers, D. J. J. Am. Chem. Soc. 2008, 130 (26), 8112. doi: 10.1021/ja801138t
10. [10]
  (10) Shao, M. H.; Liu, P.; Adzic, R. R. J. Am. Chem. Soc. 2006, 128, 7408. doi: 10.1021/ja061246s
11. [11]
  (11) Teliska, M.; O'Grady, W. E.; Ramaker, D. E. J. Phys. Chem. B 2005, 109 (16), 8076. doi: 10.1021/jp0502003
12. [12]
  (12) Maniguet, S.; Mathew, R. J.; Russell, A. E. J. Phys. Chem. B 2000, 104 (9), 1998. doi: 10.1021/jp992947x
13. [13]
  (13) Zhang, H. Y.; Cao, C. H.; Zhao, J.; Lin, R.; Ma, J. X. Chin. J. Catal. 2012, 33, 222. [张海艳, 曹春晖, 赵健, 林瑞, 马建新. 催化学报, 2012, 33, 222.]
14. [14]
  (14) Russell, A. E.; Maniguet, S.; Mathew, R. J.; Yao, J.; Roberts, M. A.; Thompsett, D. J. Power Sources 2001, 96 (1), 226. doi: 10.1016/S0378-7753(01)00573-0
15. [15]
  (15) Viswanathan, R.; Hou, G.; Liu, R.; Bare, S. R.; Modica, F.; Mickelson, G.; Segre, C. U.; Leyarovska, N.; Smotkin, E. S. J. Phys. Chem. B 2002, 106 (13), 3458. doi: 10.1021/jp0139787
16. [16]
  (16) Teliska, M.; Murthi, V. S.; Mukerjee, S.; Ramaker, D. E. J. Phys. Chem. C 2007, 111 (26), 9267. doi: 10.1021/jp071106k
17. [17]
  (17) Thomas, M. A.; Badri, S.; Jamie, S. L.; Nagappan, R.; David, E. B.; David, E. R.; Sanjeev, M. J. Phys. Chem. C 2010, 114 (2), 1028. doi: 10.1021/jp908082j
18. [18]
  (18) Fan, Q. B.; Pu, C.; Smotkin, E. S. J. Electrochem. Soc. 1996, 143 (10), 3053. doi: 10.1149/1.1837163
19. [19]
  (19) Viswanathan, R.; Liu, R.; Smotkin, E. S. Rev. Sci. Instrum. 2002, 73 (5), 2124. doi: 10.1063/1.1472469
20. [20]
  (20) Ian, K.; Dunesh, K.; Adam, Y.; Nicholas, D.; Smotkin, E. S. J. Am. Chem. Soc. 2010, 132, 17611. doi: 10.1021/ja1081487
21. [21]
  (21) Rice, C.; Tong, Y.; Oldfield, E.; Wieckowski, A.; Hahn, F.; Gloaguen, F.; Leger, J. M.; Lamy, C. J. Phys. Chem. C 2000, 104, 5803. doi: 10.1021/jp0007179
22. [22]
  (22) Sanicharane, S.; Bo, A.; Sompalli, B.; Gurau, B.; Smotkin, E. S. J. Electrochem. Soc. 2002, 149 (5), A554.
23. [23]
  (23) Vijayaraghavan, G.; Gao, L.; Korzeniewski, C. Langmuir 2003, 19, 2333. doi: 10.1021/la0207466
24. [24]
  (24) Tkach, I.; Panchenko, A.; Kaz, T.; gel, V.; Friedrich, K. A.; Roduner, E. Phys. Chem. Chem. Phys. 2004, 6 (23), 5419. doi: 10.1039/b411108g
25. [25]
  (25) Lebedeva, N. P.; Rodes, A.; Feliu, J. M.; Koper, M. T. M.; Santeen, R. A. V. J. Phys. Chem. B 2002, 106, 9863. doi: 10.1021/jp0203806
26. [26]
  (26) Kim, C. S.; Korzeniewski, C. Anal. Chem. 1997, 69 (13), 2349. doi: 10.1021/ac961306k
27. [27]
  (27) Shin, J.; Korzeniewski, C. J. Phys. Chem. 1995, 99 (11), 3419. doi: 10.1021/j100011a003
28. [28]
  (28) Milan, M. J.; Gianluigi, A. B.; Georgios, D. P.; Feihong, N.; Jelena, M. J. J. Phys. Chem. C 2014, 118, 8723. doi: 10.1021/jp412292w
29. [29]
  (29) Zawodzinski, T. A.; Derouin, C.; Radzinski, S.; Sherman, R. J.; Smith, V. T.; Springer, T. E.; ttesfeld, S. J. Electrochem. Soc. 1993, 140 (4), 1041. doi: 10.1149/1.2056194
30. [30]
  (30) Giorgia, G.; Agnieszka, W.; Marco, M.; Luca, O.; Emiliano, P.; Sonia, D.; Arianna, M.; Roberto, M.; Andrea, D. C. J. Phys. Chem. C 2012, 116, 12791. doi: 10.1021/jp2099569
31. [31]
  (31) Bridgid, N. W.; Bin, F.; Shan, S. Y.; Valeri, P.; Zhu, P. Y.; Rameshwori, L.; Chen, Y. S.; Jin, L.; Jun, Y.; Yang, L. F.; Shao, M. H.; Zhong, C. J. Chem. Mater. 2012, 24, 4283. doi: 10.1021/cm301613j
32. [32]
  (32) Shin-ichi, N.; Takashi, A.; Masakuni, Y.; Takuya, O.; Hiroyuki, O.; Takayuki, I.; Hajime, K.; Tomoya, U.; Mizuki, T.; Yasuhiro, I. J. Phys. Chem. C 2013, 117, 13094. doi: 10.1021/jp402438e
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