Citation: XU Zhen, CHEN Yu, ZHANG Zhao, ZHANG Jian-Qing. Progress of Research on Underpotential Deposition—— I. Theory of Underpotential Deposition[J]. Acta Physico-Chimica Sinica, ;2015, 31(7): 1219-1230. doi: 10.3866/PKU.WHXB201505071 shu

Progress of Research on Underpotential Deposition—— I. Theory of Underpotential Deposition

1.
1 Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China;
2 Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China

Received Date: 23 March 2015
Available Online: 7 May 2015
Fund Project: 国家自然科学基金(21273199, 21073162) (21273199, 21073162)教育部博士点基金(20130101110047)项目资助 (20130101110047)

Underpotential deposition (upd) has been a hotspot in the field of electrochemical research throughout the years owing to its significant theoretical and applied research value. Theoretical research on upd primarily centers around the relations and rules of interaction among deposition substrates, deposition species, and anions (or other organic additives) during upd process. In this paper, the developments in theoretical research in recent years on upd on both the local and international levels are systematically summarized mainly from two viewpoints, namely, thermodynamics and kinetics. With regard to the thermodynamics of upd process, introductory comments and mathematical formulas are summarized from four aspects, i.e., underpotential shift (ΔE_upd), electrosorption valency (γ), influence of temperature, and electrochemical adsorption isotherms. The applications and analyses of those related mathematical formulas are also presented in detail. In terms of the kinetics of upd process, nucleation and growth phenomena are mainly presented. We summarize the relevant mathematical models, and additionally introduce research studies on the characteristics of upd kinetics based on these mathematical models. Furthermore, this paper presents an outline of computational chemistry methods and application achievements concerning upd research. Finally, the theoretical research status of upd is presented, giving an overall view of the development trend.
- Electrochemistry,
- Underpotential deposition,
- Thermodynamics,
- Kinetics,
- Computational chemistry
1. [1]
  
  (1) Pangarov, N. Electrochim. Acta 1983, 28 (6), 763. doi: 10.1016/0013-4686(83)85145-7
2. [2]
  (2) Huang, M. H.; Henry, J. B.; Fortgang, P.; Henig, J.; Plumeré, N.; Bandarenka, A. S. RSC Adv. 2012, 2 (29), 10994. doi: 10.1039/c2ra21558f
3. [3]
  (3) Hevesy, G. V. Physik. Z. 1912, 13, 715.
4. [4]
  (4) Xing, X. K.; Bae, I. T.; Scherson, D. A. Electrochim. Acta 1995, 40 (1), 29. doi: 10.1016/0013-4686(94)00251-U
5. [5]
  (5) Zhu, W.; Yang, J. Y.; Zhou, D. X.; Bao, S. Q.; Fan, X. A.; Duan, X. K. Electrochim. Acta 2007, 52 (11), 3660. doi: 10.1016/j.electacta.2006.10.028
6. [6]
  (6) Kondo, T.; Takakusagi, S.; Uosaki, K. Electrochem. Commun. 2009, 11 (4), 804. doi: 10.1016/j.elecom.2009.01.036
7. [7]
  (7) Kirowa-Eisner, E.; Bonfil, Y.; Tzur, D.; Gileadi, E. J. Electroanal. Chem. 2003, 552, 171. doi: 10.1016/S0022-0728 (03)00181-5
8. [8]
  (8) Paddon, C. A.; Compton, R. G. J. Phys. Chem. C 2007, 111 (26), 9016. doi: 10.1021/jp073304h
9. [9]
  (9) Fu, Y. C.; Yan, J.W.; Wang, Y.; Tian, J. H.; Zhang, H. M.; Xie, Z. X.; Mao, B.W. J. Phys. Chem. C 2007, 111 (28), 10467. doi: 10.1021/jp0711621
10. [10]
  (10) Gasparotto, L. H. S.; Borisenko, N.; Bocchi, N.; El Abedin, S. Z.; Endres, F. Phys. Chem. Chem. Phys. 2009, 11 (47), 11140. doi: 10.1039/b916809e
11. [11]
  (11) Rosário, A. V.; Santos, M. C.; Mascaro, L. H.; Bulhões, L. O. S.; Pereira, E. C. Thin Solid Films 2010, 518 (10), 2669. doi: 10.1016/j.tsf.2009.08.035
12. [12]
  (12) Bouamrane, F.; Tadjeddine, A.; Tenne, R.; Butler, J. E.; Kalish, R.; Levy-Clement, C. J. Phys. Chem. B 1998, 102 (1), 134. doi: 10.1021/jp971516g
13. [13]
  (13) Su, X.; Zhan, X.; Hinds, B. J. J. Mater. Chem. 2012, 22 (16), 7979. doi: 10.1039/c2jm15395e
14. [14]
  (14) Lastraioli, E.; Loglio, F.; Innocenti, M.; Carlà, F.; Foresti, M. L. ECS Trans. 2010, 25 (34), 17. doi: 10.1149/1.3335488
15. [15]
  (15) Zhang, X.; Shi, X. Z.; Ye, W. C.; Ma, C. L.; Wang, C. M. Appl. Phys. A: Mater. Sci. Process. 2009, 94 (2), 381. doi: 10.1007/s00339-008-4815-5
16. [16]
  (16) Biçer, M.; Ayd1n, A. O.; ?i?man, ?. Electrochim. Acta 2010, 55 (11), 3749. doi: 10.1016/j.electacta.2010.02.015
17. [17]
  (17) Loglio, F.; Innocenti, M.; Jarek, A.; Caporali, S.; Pasquini, I.; Foresti, M. L. J. Electroanal. Chem. 2010, 638 (1), 15. doi: 10.1016/j.jelechem.2009.10.027
18. [18]
  (18) Alanyal?o?lu, M.; Bayrakçeken, F.; Demir, Ü. Electrochim. Acta 2009, 54 (26), 6554. doi: 10.1016/j.electacta.2009.06.056
19. [19]
  (19) Gao, L. X.; Wang, L. N.; Qi, T.; Yu, J. Acta Phys. -Chim. Sin. 2012, 28 (1), 111. [高丽霞, 王丽娜, 齐涛, 余江. 物理化学学报, 2012, 28 (1), 111.] doi: 10.3866/PKU.WHXB201228111
20. [20]
  (20) Li, M.; Sun, T. T.; Liu, B.; Han, W.; Sun, Y.; Zhang, M. L. Acta Phys. -Chim. Sin. 2015, 31 (2), 309. [李梅, 孙婷婷, 刘斌, 韩伟, 孙杨, 张密林. 物理化学学报, 2015, 31 (2), 309.] doi: 10.3866/PKU.WHXB201412182
21. [21]
  (21) Xue, Y.; Zhou, Z. P.; Yan, Y. D.; Zhang, M. L.; Li, X.; Ji, D. B.; Han, W.; Zhang, M. Acta Phys. -Chim. Sin. 2014, 30 (9), 1674. [薛云, 周志萍, 颜永得, 张密林, 李星, 纪德彬, 韩伟, 张萌. 物理化学学报, 2014, 30 (9), 1674.] doi: 10.3866/PKU.WHXB201407022
22. [22]
  (22) Nicic, I.; Liang, J.; Cammarata, V.; Alanyalioglu, M.; Demir, U.; Shannon, C. J. Phys. Chem. B 2002, 106 (47), 12247. doi: 10.1021/jp026625w
23. [23]
  (23) Hölzle, M. H.; Retter, U.; Kolb, D. M. J. Electroanal. Chem. 1994, 371 (1-2), 101. doi: 10.1016/0022-0728(93)03235-H
24. [24]
  (24) Sibert, E.; Wang, L.; De Santis, M.; Soldo-Olivier, Y. Electrochim. Acta 2014, 135, 594. doi: 10.1016/j.electacta.2014.04.168
25. [25]
  (25) Lamy-Pitara, E.; Elouazzani-Benhima, L.; Barbier, J.; Cahoreau, M.; Caisso, J. J. Electroanal. Chem. 1994, 372 (1-2), 233. doi: 10.1016/0022-0728(93)03256-O
26. [26]
  (26) Garcia, S. G.; Salinas, D. R.; Staikov, G. Surf. Sci. 2005, 576 (1-3), 9. doi: 10.1016/j.susc.2004.11.037
27. [27]
  (27) Hepel, M.; Kanige, K.; Bruckenstein, S. Langmuir 1990, 6 (6), 1063. doi: 10.1021/la00096a006
28. [28]
  (28) Sackmann, J.; Bunk, A.; Pötzschke, R. T.; Staikov, G.; Lorenz, W. J. Electrochim. Acta 1998, 43 (19-20), 2863. doi: 10.1016/S0013-4686(98)00027-9
29. [29]
  (29) Mendoza-Huizar, L. H.; Robles, J.; Palomar - Pardavé, M. J. Electroanal. Chem. 2002, 521 (1-2), 95. doi: 10.1016/S0022-0728(02)00659-9
30. [30]
  (30) Mendoza-Huizar, L. H.; Robles, J.; Palomar - Pardavé, M. J. Electroanal. Chem. 2003, 545, 39. doi: 10.1016/S0022-0728(03)00087-1
31. [31]
  (31) Staikov, G.; García, S. G.; Salinas, D. R. ECS Trans. 2010, 25 (34), 3. doi: 10.1149/1.3335487
32. [32]
  (32) Popov, B. N.; Zheng, G.; White, R. E. Corrosion Sci. 1994, 36 (12), 2139. doi: 10.1016/0010-938X(94)90012-4
33. [33]
  (33) Zheng, G.; Popov, B. N.; White, R. E. J. Electrochem. Soc. 1994, 141 (5), 1220. doi: 10.1149/1.2054899
34. [34]
  (34) Kazemi, R.; Kiani, A. Int. J. Hydrog. Energy 2012, 37 (5), 4098. doi: 10.1016/j.ijhydene.2011.11.147
35. [35]
  (35) Kuttiyiel, K. A.; Sasaki, K.; Choi, Y.; Su, D.; Liu, P.; Adzic, R. R. Energy Environ. Sci. 2012, 5 (1), 5297. doi: 10.1039/c1ee02067f
36. [36]
  (36) Liu, J. P.; Zhou, H. H.; Huang, J. T.; Huang, Z. Y.; Zeng, F. Y.; Kuang, Y. F. Int. J. Hydrog. Energy 2012, 37 (22), 16764. doi: 10.1016/j.ijhydene.2012.08.130
37. [37]
  (37) Ni?anc?, F. B.; Öznülüer, T.; Demir, Ü. Electrochim. Acta 2013, 108, 281. doi: 10.1016/j.eleetacta.2013.06.135
38. [38]
  (38) Köse, H.; Biçer, M.; Tütüno?lu, Ç.; Ayd?n, A. O.; ?i?man, ?. Electrochim. Acta 2009, 54 (6), 1680. doi: 10.1016/j.electacta.2008.09.059
39. [39]
  (39) ?i?man, ?.; Demir, Ü. J. Electroanal. Chem. 2011, 651 (2), 222. doi: 10.1016/j.jelechem.2010.12.005
40. [40]
  (40) Herzog, G.; Arrigan, D.W. M. Electroanalysis 2003, 15 (15-16), 1302. doi: 10.1002/elan.200302812
41. [41]
  (41) Herzog, G.; Arrigan, D.W. M. TrAC, Trends Anal. Chem. 2005, 24 (3), 208. doi: 10.1016/j.trac.2004.11.014
42. [42]
  (42) Orozco, J.; Fernández - Sánchez, C.; Jiménez - Jorquera, C. Environ. Sci. Technol. 2008, 42 (13), 4877. doi: 10.1021/es8005964
43. [43]
  (43) Huang, J. F. Talanta 2009, 77 (5), 1694. doi: 10.1016/j.talanta.2008.10.005
44. [44]
  (44) Sivasubramanian, R.; Sangaranarayanan, M. V. Talanta 2011, 85 (4), 2142. doi: 10.1016/j.talanta.2011.07.057
45. [45]
  (45) Oyamatsu, D.; Kanemoto, H.; Kuwabata, S.; Yoneyama, H. J. Electroanal. Chem. 2001, 497 (1-2), 97. doi: 10.1016/S0022-0728(00)00459-9
46. [46]
  (46) Lin, S. Y.; Tsai, T. K.; Lin, C. M.; Chen, C. H.; Chan, Y. C.; Chen, H.W. Langmuir 2002, 18 (14), 5473. doi: 10.1021/la0157364
47. [47]
  (47) Gebregziabiher, D. K.; Kim, Y. G.; Thambidurai, C.; Ivanova, V.; Haumesser, P. H.; Stickney, J. L. J. Cryst. Growth 2010, 312 (8), 1271. doi: 10.1016/j.jcrysgro.2009.11.038
48. [48]
  (48) Lin, S. X.; Shi, X. Z.; Zhang, X.; Kou, H. H.; Wang, C. M. Appl. Surf. Sci. 2010, 256 (13), 4365. doi: 10.1016/j.apsusc.2010.02.032
49. [49]
  (49) Innocenti, M.; Bellandi, S.; Lastraioli, E.; Loglio, F.; Foresti, M. Langmuir 2011, 27 (18), 11704. doi: 10.1021/la202174j
50. [50]
  (50) Innocenti, M.; Zangari, G.; Zafferoni, C.; Bencistà, I.; Becucci, L.; Lavacchi, A.; Di Benedetto, F.; Bellandi, S.; Vizza, F.; Foresti, M. L. J. Power Sources 2013, 241, 80. doi: 10.1016/j.jpowsour.2013.04.111
51. [51]
  (51) Wang, M. Y.; Wang, Z.; Guo, Z. C. Acta Phys.-Chim. Sin. 2009, 25 (5), 883. [王明涌, 王志, 郭占成. 物理化学学报, 2009, 25 (5), 883.] doi: 10.3866/PKU.WHXB20090511
52. [52]
  (52) Herrero, E.; Buller, L. J.; Abruna, H. D. Chem. Rev. 2001, 101 (1), 1897. doi: 10.1021/cr9600363
53. [53]
  (53) Anjos, D. M.; Rigsby, M. A.; Wieckowski, A. J. Electroanal. Chem. 2010, 639 (1-2), 8. doi: 10.1016/j.jelechem.2009.10.003
54. [54]
  (54) Sudha, V.; Sangaranarayanan, M. V. J. Phys. Chem. B 2002, 106 (10), 2699. doi: 10.1021/jp013544b
55. [55]
  (55) Sudha, V.; Sangaranarayanan, M. V. J. Phys. Chem. B 2003, 107 (16), 3907. doi: 10.1021/jp027818m
56. [56]
  (56) Sudha, V.; Sangaranarayanan, M. V. J. Chem. Sci. 2005, 117 (3), 207. doi: 10.1007/BF02709289
57. [57]
  (57) Kolb, D. M.; Przasnyski, M.; Gerischer, H. J. Electroanal. Chem. Interfacial Electrochem. 1974, 54 (1), 25. doi: 10.1016/0368-1874(74)85093-8
58. [58]
  (58) Campbell, F.W.; Compton, R. G. Int. J. Electrochem. Sci 2010, 5 (3), 407.
59. [59]
  (59) Campbell, F.W.; Zhou, Y. G.; Compton, R. G. New J. Chem. 2010, 34 (2), 187. doi: 10.1039/b9nj00669a
60. [60]
  (60) Zhou, Y. G.; Rees, N. V.; Compton, R. G. ChemPhysChem 2011, 12 (11), 2085. doi: 10.1002/cphc.201100282
61. [61]
  (61) Schultze, J.W.; Vetter, K. J. J. Electroanal. Chem. Interfacial Electrochem. 1973, 44 (1), 63.
62. [62]
  (62) Swathirajan, S.; Bruckenstein, S. J. Electrochem. Soc. 1982, 129 (6), 1202. doi: 10.1149/1.2124087
63. [63]
  (63) Swathirajan, S.; Bruckenstein, S. Electrochim. Acta 1983, 28 (7), 865. doi: 10.1016/0013-4686(83)85162-7
64. [64]
  (64) Swathirajan, S.; Bruckenstein, S. J. Electroanal. Chem. Interfacial Electrochem. 1983, 146 (1), 137. doi: 10.1016/S0022-0728(83)80117-X
65. [65]
  (65) Szabó, S. Int. Rev. Phys. Chem. 1991, 10 (2), 207. doi: 10.1080/01442359109353258
66. [66]
  (66) Ad?i?, R. R.; Minevski, L. V. Electrochim. Acta 1987, 32 (1), 125. doi: 10.1016/0013-4686(87)87020-2
67. [67]
  (67) Salie, G.; Bartels, K. Electrochim. Acta 1994, 39 (8-9), 1057. doi: 10.1016/0013-4686(94)E0020-Z
68. [68]
  (68) Santos, M. C.; Mascaro, L. H.; Machado, S. A. S. Electrochim. Acta 1998, 43 (16-17), 2263. doi: 10.1016/S0013-4686(97)10171-2
69. [69]
  (69) de Levie, R. J. Electroanal. Chem. 2004, 562 (2), 273. doi: 10.1016/j.jelechem.2003.08.027
70. [70]
  (70) Zolfaghari, A.; Jerkiewicz, G. J. Electroanal. Chem. 1999, 467 (1-2), 177. doi: 10.1016/S0022-0728(99)00084-4
71. [71]
  (71) Radovic-Hrapovic, Z.; Jerkiewicz, G. J. Electroanal. Chem. 2001, 499 (1), 61. doi: 10.1016/S0022-0728(00)00478-2
72. [72]
  (72) Zolfaghari, A.; Jerkiewicz, G. J. Electroanal. Chem. 1997, 422 (1-2), 1. doi: 10.1016/S0022-0728(97)00001-6
73. [73]
  (73) Abaci, S.; Zhang, L. S.; Shannon, C. J. Electroanal. Chem. 2004, 571 (2), 169. doi: 10.1016/j.jelechem.2004.05.006
74. [74]
  (74) Vra?ar, L.; Krstaji?, N.; Neophytides, S. G.; Jakši?, J. Int. J. Hydrog. Energy 2004, 29 (8), 835. doi: 10.1016/S0360-3199(03)00154-X
75. [75]
  (75) Blais, S.; Jerkiewicz, G.; Herrero, E.; Feliu, J. M. J. Electroanal. Chem. 2002, 519 (1-2), 111. doi: 10.1016/S0022-0728(01)00735-5
76. [76]
  (76) Jerkiewicz, G.; Perreault, F.; Radovic-Hrapovic, Z. J. Phys. Chem. C 2009, 113 (28), 12309. doi: 10.1021/jp900478u
77. [77]
  (77) Etzel, K. D.; Bickel, K. R.; Schuster, R. Rev. Sci. Instrum. 2010, 81 (3), 034101. doi: 10.1063/1.3309785
78. [78]
  (78) Schuster, R.; Rösch, R.; Timm, A. E. Z. Phys. Chem. 2007, 221 (11-12), 1479. doi: 10.1524/zpch.2007.221.11-12.1479
79. [79]
  (79) Etzel, K. D.; Bickel, K. R.; Schuster, R. ChemPhysChem 2010, 11 (7), 1416. doi: 10.1002/cphc.200900981
80. [80]
  (80) Swathirajan, S.; Mizota, H.; Bruckenstein, S. J. Phys. Chem. 1982, 86 (13), 2480. doi: 10.1021/j100210a048
81. [81]
  (81) Lasia, A. J. Electroanal. Chem. 2004, 562 (1), 23. doi: 10.1016/j.jelechem.2003.07.033
82. [82]
  (82) Chun, J. H.; Ra, K. H.; Kim, N. Y. Int. J. Hydrog. Energy 2001, 26 (9), 941. doi: 10.1016/S0360-3199(01)00028-3
83. [83]
  (83) Markovic, N. M.; Grgur, B. N.; Ross, P. N. J. Phys. Chem. B 1997, 101 (27), 5405. doi: 10.1021/jp970930d
84. [84]
  (84) Chang, B. Y.; Ahn, E.; Park, S. M. J. Phys. Chem. C 2008, 112 (43), 16902. doi: 10.1021/jp805960j
85. [85]
  (85) Zolfaghari, A.; Jerkiewicz, G.; Chrzanowski, W.; Wieckowski, A. J. Electrochem. Soc. 1999, 146 (11), 4158. doi: 10.1149/1.1392607
86. [86]
  (86) Zinola, C. F.; Rodríguez, J. J. Solid State Electrochem. 2002, 6 (6), 412. doi: 10.1007/s100080100242
87. [87]
  (87) Quaiyyum, M. D.; Aramata, A.; Moniwa, S.; Taguchi, S.; Enyo, M. J. Electroanal. Chem. 1994, 373 (1-2), 61. doi: 10.1016/0022-0728(94)03268-8
88. [88]
  (88) Palomar - Pardavé, M.; nzález, I.; Batina, N. J. Phys. Chem. B 2000, 104 (15), 3545. doi: 10.1021/jp9931861
89. [89]
  (89) Arbib, M.; Zhang, B.; Lazarov, V.; Stoychev, D.; Milchev, A.; Buess-Herman, C. J. Electroanal. Chem. 2001, 510 (1-2), 67. doi: 10.1016/S0022-0728(01)00545-9
90. [90]
  (90) Palomar-Pardavé, M.; Garfias-García, E.; Romero-Romo, M.; Ramírez-Silva, M. T.; Batina, N. Electrochim. Acta 2011, 56 (27), 10083. doi: 10.1016/j.electacta.2011.08.105
91. [91]
  (91) Quayum, M. E.; Ye, S.; Uosaki, K. J. Electroanal. Chem. 2002, 520 (1-2), 126. doi: 10.1016/S0022-0728(02)00643-5
92. [92]
  (92) Palomar-Pardavé, M.; nzález, I.; Soto, A. B.; Arce, E. M. J. Electroanal. Chem. 1998, 443 (1), 125. doi: 10.1016/S0022-0728(97)00496-8
93. [93]
  (93) Armstrong, R. D.; Harrison, J. A. J. Electrochem. Soc. 1969, 116 (3), 328. doi: 10.1149/1.2411839
94. [94]
  (94) Guo, L.; Hu, K.; Li, W. P.; Zhang, S. T. Chin. J. Appl. Chem. 2013, 30 (2), 214. [郭雷, 胡舸, 李文坡, 张胜涛. 应用化学, 2013, 30 (2), 214.] doi: 10.3724/SP.J.1095.2013.20090
95. [95]
  (95) Alanyal?o?lu, M.; Çakal, H.; Öztürk, A. E.; Demir, Ü. J. Phys. Chem. B 2001, 105 (43), 10588. doi: 10.1021/jp004227s
96. [96]
  (96) Hölzle, M. H.; Zwing, V.; Kolb, D. M. Electrochim. Acta 1995, 40 (10), 1237. doi: 10.1016/0013-4686(95)00055-J
97. [97]
  (97) Martínez-Ruíz, A.; Palomar-Pardavé, M.; Valenzuela-Benavides, J.; Farías, M. H.; Batina, N. J. Phys. Chem. B 2003, 107 (42), 11660. doi: 10.1021/jp027197x
98. [98]
  (98) Mendoza-Huizar, L. H.; Rios-Reyes, C. H. J. Solid State Electrochem. 2011, 15 (4), 737. doi: 10.1007/s10008-010-1146-1
99. [99]
  (99) Leiva, E. Electrochim. Acta 1996, 41 (14), 2185. doi: 10.1016/0013-4686(96)00050-3
100. [100]
  (100) Sanchez, C. G.; Del Popolo, M. G.; Leiva, E. P. M. Surf. Sci. 1999, 421 (1-2), 59. doi: 10.1016/S0039-6028(98)00818-8
101. [101]
  (101) Sanchez, C. G.; Leiva, E. P. M.; Kohanoff, J. Langmuir 2001, 17 (7), 2219. doi: 10.1021/la001639j
102. [102]
  (102) Oviedo, O. A.; Leiva, E. P. M.; Rojas, M.I. Electrochim. Acta 2006, 51 (17), 3526. doi: 10.1016/j.electacta.2005.10.008
103. [103]
  (103) Guo, L.; Tan, J. H.; Li, W. P.; Hu, K.; Zhang, S. T. Prog. Chem. 2013, 25 (11), 1842. [郭雷, 谭建红, 李文坡, 胡舸, 张胜涛. 化学进展, 2013, 25 (11), 1842.] doi: 10.7536/PC130148
104. [104]
  (104) Újfalussy, B.; Szunyogh, L.; Bruno, P.; Weinberger, P. Phys. Rev. lett. 1996, 77 (9), 1805. doi: 10.1103/PhysRevLett.77.1805
105. [105]
  (105) Oviedo, O. A.; Leiva, E. P. M.; Mariscal, M. M. Phys. Chem. Chem. Phys. 2008, 10 (24), 3561. doi: 10.1039/b801838c
106. [106]
  (106) Oviedo, O. A.; Mariscal, M. M.; Leiva, E. P. M. Electrochim. Acta 2010, 55 (27), 8244. doi: 10.1016/j.electacta.2010.03.059
107. [107]
  (107) Mariscal, M. M.; Oviedo, O. A.; Leiva, E. P. M. J. Mater. Res. 2012, 27 (14), 1777. doi: 10.1557/jmr.2012.132
108. [108]
  (108) Oviedo, O. A.; Negre, C. F. A.; Mariscal, M. M.; Sánchez, C. G.; Leiva, E. P. M. Electrochem. Commun. 2012, 16 (1), 1. doi: 10.1016/j.elecom.2011.12.013
109. [109]
  (109) Oviedo, O. A.; Reinaudi, L.; Leiva, E. P. M. Electrochem. Commun. 2012, 21, 14. doi: 10.1016/j.elecom.2012.05.001
110. [110]
  (110) Oviedo, O. A.; Reinaudi, L.; Mariscal, M. M.; Leiva, E. P. M. Electrochim. Acta 2012, 76, 424. doi: 10.1016/j.electacta.2012.05.055
1. [1]
  Mahmoud Sayed , Han Li , Chuanbiao Bie . Challenges and prospects of photocatalytic H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(9): 100117-0. doi: 10.1016/j.actphy.2025.100117
2. [2]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
3. [3]
  Tongqi Ye , Yanqing Wang , Qi Wang , Huaiping Cong , Xianghua Kong , Yuewen Ye . Reform of Classical Thermodynamics Curriculum from the Perspective of Computational Chemistry. University Chemistry, 2025, 40(7): 387-392. doi: 10.12461/PKU.DXHX202409128
4. [4]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
5. [5]
  Chunguang Rong , Miaojun Xu , Xingde Xiang , Song Liu . 化学热力学熵变计算的教学探讨. University Chemistry, 2025, 40(8): 323-329. doi: 10.12461/PKU.DXHX202409146
6. [6]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
7. [7]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
8. [8]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
9. [9]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
10. [10]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
11. [11]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
12. [12]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
13. [13]
  Yongjian Zhang , Fangling Gao , Hong Yan , Keyin Ye . Electrochemical Transformation of Organosulfur Compounds. University Chemistry, 2025, 40(5): 311-317. doi: 10.12461/PKU.DXHX202407035
14. [14]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
15. [15]
  Yanan Jiang , Yuchen Ma . Brief Discussion on the Electronic Exchange Interaction in Quantum Chemistry Computations. University Chemistry, 2025, 40(3): 10-15. doi: 10.12461/PKU.DXHX202402058
16. [16]
  Hongting Yan , Aili Feng , Rongxiu Zhu , Lei Liu , Dongju Zhang . Reexamination of the Iodine-Catalyzed Chlorination Reaction of Chlorobenzene Using Computational Chemistry Methods. University Chemistry, 2025, 40(3): 16-22. doi: 10.12461/PKU.DXHX202403010
17. [17]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
18. [18]
  Xu Li , Qinglan Li , Qingji Wang . Research and Practice of Computational Chemistry in Inorganic Chemistry Education. University Chemistry, 2025, 40(7): 345-351. doi: 10.12461/PKU.DXHX202408114
19. [19]
  Zhiwen HU , Ping LI , Yulong YANG , Weixia DONG , Qifu BAO . Morphology effects on the piezocatalytic performance of BaTiO₃. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 339-348. doi: 10.11862/CJIC.20240172
20. [20]
  Shuhui Li , Rongxiuyuan Huang , Yingming Pan . Electrochemical Synthesis of 2,5-Diphenyl-1,3,4-Oxadiazole: A Recommended Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 357-365. doi: 10.12461/PKU.DXHX202407028

Get Citation

PDF

XML

Metrics

PDF Downloads(607)
Abstract views(1096)
HTML views(145)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142