Citation:
CHENG Qing-Li, ZHANG Wei-Hua, TAO Bin. Investigation of the Electrochemical Corrosion of Copper under a Micrometric Electrolyte Droplet Using a Three-Electrode System[J]. Acta Physico-Chimica Sinica,
;2015, 31(7): 1345-1350.
doi:
10.3866/PKU.WHXB201504271
-
Owing to its high impedance, studying atmospheric corrosion using a traditional reference electrode (RE) is difficult. To obtain more accurate information on the electrochemical processes involved in atmospheric corrosion, it is necessary to improve the traditional RE. In this paper, the corrosion behavior of copper under an electrolyte droplet containing (NH4)2SO4 was investigated by electrochemical impedance spectroscopy (EIS) and polarization measurements using a three-electrode system with a modified RE. The average corrosion rate increased with decreasing electrolyte volumes (from 1 to 20 μL) and with decreasing heights of the droplet at heights below 850 μm. The EIS and polarization results were in agreement, thereby demonstrating that the modified RE could be effectively used to study atmospheric corrosion under an electrolyte droplet.
-
-
-
[1]
(1) Azmat, N. S.; Ralston, K. D.; Muddle, B. S.; Cole, I. S. Corrosion Sci. 2011, 53, 1604. doi: 10.1016/j.corsci.2011.01.044
-
[2]
(2) Liao, X. N.; Cao, F. H.; Zheng, L. Y.; Liu, W. J.; Chen, A.; Zhang, J. Q.; Cao, C. N. Corrosion Sci. 2011, 53, 3289.
-
[3]
(3) Su, Y. Y.; Shemenski, R. M. Surf. Interface Anal. 2008, 40, 1183. doi: 10.1002/sia.v40:8
-
[4]
(4) Hastuty, S.; Nishikata, A.; Tsuru, T. Corrosion Sci. 2010, 52, 2035.
-
[5]
(5) Chen, J.; Wang, J.; Han, E.; Ke, W. Corrosion Sci. 2007, 49, 1634.
-
[6]
(6) Tran, T.; Fiaud, C.; Sutter, E.; Villanova, A. Corrosion Sci. 2003, 45, 2802.
-
[7]
(7) Wadsak, M.; Aastrup, T.; Wallinder, I. O.; Leygraf, C.; Schreiner, M. Corrosion Sci. 2002, 44, 791.
-
[8]
(8) Chen, Y. Y.; Tzeng, H. J.; Wei, L. I.; Shih, H. C. Mater. Sci. Eng. A 2005, 47, 398.
-
[9]
(9) Sun, F. J.; Wang, J. Acta Phys. -Chim. Sin. 2012, 28, 615. [孙凤娟, 王佳. 物理化学学报, 2012, 28, 615.] doi: 10.3866/PKU.WHXB201201101
-
[10]
(10) Wang, J.; Tsuru, T. J. Chin. Soc. Corros. Prot. 1995, 15, 180. [王佳, 水流彻. 中国腐蚀与防护学报, 1995, 15, 180.]
-
[11]
(11) Nishikata, A.; Ichihara, Y. Corrosion Sci. 1995, 37, 897. doi: 10.1016/0010-938X(95)00002-2
-
[12]
(12) El-Mahdy, G. A.; Nishikata, A.; Tsuru, T. Corrosion Sci. 2000, 42, 1509.
-
[13]
(13) Venkatraman, M.; Cole, I. S.; Gunasegaram, D. R.; Emmanuel, B. Mater. Sci. Forum. 2010, 654-656, 1650.
-
[14]
(14) Cheng, Q. L.; Song, S. H.; Song, L. Y.; Hou, B. R. J. Electrochem. Soc. 2013, 160, C380.
-
[15]
(15) Nazarov, A.; Thierry, D. Electrochim. Acta 2004, 49, 2717. doi: 10.1016/j.electacta.2004.01.066
-
[16]
(16) King, P. C.; Cole, I. S.; Corrigan, P. A.; Hughes, A. E.; Muster, T. H. Corrosion Sci. 2011, 53, 1086.
-
[17]
(17) Williams, G.; McMurray, H. N. J. Electrochem. Soc. 2001, 148, B377.
-
[18]
(18) Williams, G.; McMurray, H. N. Electrochem. Commun. 2003, 5, 871. doi: 10.1016/j.elecom.2003.08.008
-
[19]
(19) Ehahoun, H.; Stratmann, M. Electrochim. Acta 2005, 50, 2667. doi: 10.1016/j.electacta.2004.11.011
-
[20]
(20) Bakker, E.; Diaz, M. T. Anal. Chem. 2002, 74, 2781. doi: 10.1021/ac0202278
-
[21]
(21) Chen, S.; Kucernak, A. Electrochem. Commun. 2002, 4, 80. doi: 10.1016/S1388-2481(01)00278-8
-
[22]
(22) Nakajima, K.; Yamagiwa, T.; Hirano, A.; Sugawara, M. Anal. Sci. 2003, 19, 55.
-
[23]
(23) Fushimi, K.; Seo, M. Electrochim. Acta 2001, 47, 121. doi: 10.1016/S0013-4686(01)00557-6
-
[24]
(24) Katemann, B. B.; Inchauspe, C. G.; Castro, P. A.; Schultze, A.; Calvo, E. J.; Schuhmann, W. Electrochim. Acta 2003, 48, 1115. doi: 10.1016/S0013-4686(02)00822-8
-
[25]
(25) Gabrielli, C.; Joiret, S.; Keddam, M.; Perrot, H.; Portail, N.; Rousseau, P.; Vivier, V. Electrochim. Acta 2007, 52, 7706. doi: 10.1016/j.electacta.2007.03.008
-
[26]
(26) Keddam, M.; Portail, N.; Trinh, D.; Vivier, V. ChemPhysChem 2009, 10, 3175.
-
[27]
(27) Isaacs, H. S. J. Electrochem. Soc. 1991, 138, 722. doi: 10.1149/1.2085665
-
[28]
(28) Sanchez, M.; Gamby, J.; Perrot, H.; Rose, D.; Vivier, V. Electrochem. Commun. 2010, 12, 1230. doi: 10.1016/j.elecom.2010.06.026
-
[29]
(29) Stulik, K.; Amatore, C.; Holub, K.; Marecek, V.; Kutner, W. Pure. Appl. Chem. 2000, 72, 1483.
-
[30]
(30) Vogel, A.; Schultze, J.W. Electrochim. Acta 1999, 44, 3751. doi: 10.1016/S0013-4686(99)00080-8
-
[31]
(31) Vignal, V.; Krawiec, H.; Heintz, O.; Oltra, R. Electrochim. Acta 2007, 52, 4994. doi: 10.1016/j.electacta.2007.01.079
-
[32]
(32) Murer, N.; Oltra, R.; Vuillemin, B.; Néel, O. Corrosion Sci. 2010, 52, 130.
-
[33]
(33) Krawiec, H.; Vignal, V.; Akid, R. Electrochim. Acta 2008, 54, 5252.
-
[34]
(34) Dubuisson, E.; Lavie, P.; Dalard, F.; Caire, J. P.; Szunerits, S. Corrosion Sci. 2007, 49, 910.
-
[35]
(35) Kitade, T.; Kitamura, K.; Takegami, S.; Miyata, Y. Japn. Soc. Anal. Chem. 2005, 21, 907.
-
[36]
(36) Nam, J.; Jeon, D. Electrochim. Acta 2006, 51, 3446. doi: 10.1016/j.electacta.2005.09.041
-
[37]
(37) Ni, M.; Leung, M. K. H.; Leung, D. Y. C. J. Power Sources 2007, 168, 369. doi: 10.1016/j.jpowsour.2007.03.005
-
[38]
(38) Tsuru, T.; Nishikata, A.; Wang, J. Mater. Sci. Eng. A 1995, 198, 161. doi: 10.1016/0921-5093(95)80071-2
-
[39]
(39) Ga, J. J.; Ga, J.W.; Lua, Y. H.; Hua, J. Z. Electrochim. Acta 2009, 54, 1426. doi: 10.1016/j.electacta.2008.09.017
-
[40]
(40) Nishikata, A.; Ichihara, Y.; Hayashi, Y.; Tsuru, T. J. Electrochem. Soc. 1997, 144, 1244. doi: 10.1149/1.1837578
-
[41]
(41) Huang, H. L.; Dong, Z. H.; Chen, Z. Y.; Guo, X. P. Corrosion Sci. 2011, 53, 1230.
-
[1]
-
-
-
[1]
Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . In Situ Electrochemical Impedance Spectroscopy Monitoring of the High-Temperature Double-Discharge Mechanism of Nb12WO33 Cathode Material for Long-Life Thermal Batteries. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-0. doi: 10.1016/j.actphy.2024.100040
-
[2]
Xudong Lv , Tao Shao , Junyan Liu , Meng Ye , Shengwei Liu . Paired Electrochemical CO2 Reduction and HCHO Oxidation for the Cost-Effective Production of Value-Added Chemicals. Acta Physico-Chimica Sinica, 2024, 40(5): 2305028-0. doi: 10.3866/PKU.WHXB202305028
-
[3]
Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
-
[4]
Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . Electrochemical CO2 Reduction to C2+ Products with Ampere-Level Current on Carbon-Modified Copper Catalysts. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-0. doi: 10.3866/PKU.WHXB202404012
-
[5]
Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
-
[6]
Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
-
[7]
Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO2 Reduction to C2 Products and Superior Rechargeable Zn-CO2 Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
-
[8]
Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi2MoO6 Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
-
[9]
Yue-Zhou Zhu , Kun Wang , Shi-Sheng Zheng , Hong-Jia Wang , Jin-Chao Dong , Jian-Feng Li . Application and Development of Electrochemical Spectroscopy Methods. Acta Physico-Chimica Sinica, 2024, 40(3): 2304040-0. doi: 10.3866/PKU.WHXB202304040
-
[10]
Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell. Acta Physico-Chimica Sinica, 2025, 41(1): 100005-0. doi: 10.3866/PKU.WHXB202309037
-
[11]
Yingtong FAN , Yujin YAO , Shouhao WAN , Yihang SHEN , Xiang GAO , Cuie ZHAO . Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043
-
[12]
Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
-
[13]
Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
-
[14]
Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
-
[15]
Lijun Dong , Pengcheng Du , Guangnong Lu , Wei Wang . Exploration and Practice of Independent Design Experiments in Inorganic and Analytical Chemistry: A Case Study of “Preparation and Composition Analysis of Tetraammine Copper(II) Sulfate”. University Chemistry, 2024, 39(4): 361-366. doi: 10.3866/PKU.DXHX202310041
-
[16]
Meiyu Lin , Yuxin Fang , Songzhang Shen , Yaqian Duan , Wenyi Liang , Chi Zhang , Juan Su . Exploration and Implementation of a Dual-Pathway Blended Teaching Model in General Chemistry Experiment Course: A Case Study of Copper Glycine Synthesis and Its Thermal Analysis. University Chemistry, 2024, 39(8): 48-53. doi: 10.3866/PKU.DXHX202312042
-
[17]
Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
-
[18]
Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
-
[19]
Yujing Chen , Hongqun Ouyang , Dan Zhao , Yanyan Chu , Zhengping Qiao . Recommendations for the Content and Instruction of the Physical Chemistry Experiment “Construction of Ternary Liquid-Liquid Phase Diagrams”. University Chemistry, 2025, 40(7): 359-366. doi: 10.12461/PKU.DXHX202409120
-
[20]
Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 2309036-0. doi: 10.3866/PKU.WHXB202309036
-
[1]
Metrics
- PDF Downloads(288)
- Abstract views(658)
- HTML views(8)