Citation: CHEN Yang, ZHANG Zi-Lan, SUI Zhi-Jun, LIU Zhi-Ting, ZHOU Jing-Hong, ZHOU Xing-Gui. Preparation and Electrochemical Performance of Ni(OH)₂ Nanowires/ Three-Dimensional Graphene Composite Materials[J]. Acta Physico-Chimica Sinica, ;2015, 31(6): 1105-1112. doi: 10.3866/PKU.WHXB201504081 shu

Preparation and Electrochemical Performance of Ni(OH)₂ Nanowires/ Three-Dimensional Graphene Composite Materials

1.
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China

Received Date: 9 February 2015
Available Online: 8 April 2015
Fund Project: 国家重点基础研究发展规划项目(973) (2014CB239702) (973) (2014CB239702)中央高校基本科研业务费专项基金(WA1514011)资助 (WA1514011)

We synthesized Ni(OH)₂ nanowires/three-dimensional graphene composites using a hydrothermal method, and compared their properties with those of three-dimensional graphene, Ni(OH)₂ nanowires, reduced graphene oxide, and Ni(OH)₂ nanowires/reduced graphene oxide. The samples were characterized using Xray diffraction, scanning electron microscopy, thermogravimetric analysis, and N₂ physisorption measurements. The electrochemical performances were investigated using cyclic voltammetry and galvanostatic chargedischarge methods. The results showed that Ni(OH)₂ nanowires of width 20-30 nm were closely combined with graphene and crosslinked to one another to form a three-dimensional structure with a high specific surface area (136 m²·g^-1) and mesoporosity (pore diameter 20-50 nm). The mass fraction of Ni(OH)₂ nanowires in the Ni(OH)₂ nanowires/three-dimensional graphene composite was 88%. The maximum specific capacitance of the Ni(OH)₂ nanowires/three-dimensional graphene composite was 1664 F·g^-1 in 6 mol·L^-1 KOH electrolyte at 1 A·g^-1. The specific capacitance decreased by only 7% after 3000 cycles at 1 A·g^-1. A comparative study of the specific capacitances and cycling performances of Ni(OH)₂ nanowires, Ni(OH)₂ nanowires/reduced graphene oxide, three-dimensional graphene, reduced graphene oxide, and Ni(OH)₂ nanowires/three-dimensional graphene indicated that three-dimensional graphene with three-dimensional porosity and a larger specific surface area than conventional reduced graphene oxide enabled improved use of the active material and significantly enhanced the electrochemical performance of Ni(OH)₂ nanowires.
- Graphene gel,
- Three-dimensional porosity,
- Specific capacitance,
- Hydrothermal method,
- Capacitance retention
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沈阳化工大学材料科学与工程学院沈阳 110142

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Preparation and Electrochemical Performance of Ni(OH)₂ Nanowires/ Three-Dimensional Graphene Composite Materials