Citation: XU Hai-Ying, KAN Cai-Xia, WANG Chang-Shun, NI Yuan, LIU Jin-Sheng, XU Wei, KE Jun-Hua. Ultrafine Au Nanowires Synthesized via One-Step Wet Chemical Method[J]. Acta Physico-Chimica Sinica, ;2015, 31(6): 1186-1190. doi: 10.3866/PKU.WHXB201504012 shu

Ultrafine Au Nanowires Synthesized via One-Step Wet Chemical Method

1.
1 Department of Applied Physics, College of Science, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, P. R. China;
2 Department of Mathematics and Physics, Nanjing Institute of Technology, Nanjing 211167, P. R. China

Received Date: 19 January 2015
Available Online: 1 April 2015
Fund Project: 国家自然科学基金(11274173) (11274173) 中央高校基本科研专项资金(NZ2015101, NJ20140005) (NZ2015101, NJ20140005) 江苏省研究生培养创新工程(KYZZ_0091) (KYZZ_0091)

Ultrafine Au nanowires (AuNWs) were synthesized in high yields by a one-step wet chemical method using oleylamine as the solvent, surfactant, and reductant. The obtained AuNWs were of high purity and had a high aspect ratio, with diameters of ~2 nm and lengths of tens of micrometers. AuNWs of diameter ~9 nm were also obtained in the presence of oleic acid, at an oleic acid:oleylamine volume ratio of 1:1. The formation of AuNWs was studied by changing the reaction temperature and the volume of oleylamine. It is proposed that the growth mechanism of the Au nanostructures involves strong aurophilic interactions from oleylamine-AuCl complexes; the reduced Au atoms agglomerate and attach to preformed particles, and the oleylamine molecular layer acts as a soft template, leading to one-dimensional growth of Au atoms into AuNWs.
- Quasi-one-dimension,
- Ultrafine,
- Au nanowire,
- Wet chemical method,
- Growth mechanism
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