Citation: XU Jing, YANG De-Zhi, LIAO Xiao-Zhen, HE Yu-Shi, MA Zi-Feng. Electrochemical Performances of Reduced Graphene Oxide/Titanium Dioxide Composites for Sodium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2015, 31(5): 913-919. doi: 10.3866/PKU.WHXB201503162 shu

Electrochemical Performances of Reduced Graphene Oxide/Titanium Dioxide Composites for Sodium-Ion Batteries

1.
Shanghai Electrochemical Energy Devices Research Center, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China

Received Date: 27 November 2014
Available Online: 16 March 2015
Fund Project: 上海市自然科学基金(15ZR1422300) (15ZR1422300) 国家自然科学基金(21336003, 21073120, 21006063) (21336003, 21073120, 21006063)国家重点基础研究发展计划(973)(2014CB239700) 资助项目 (973)(2014CB239700)

Anatase TiO₂ shows excellent long-term cycling stability as an anode for sodium-ion batteries. However, the low specific capacity and poor rate capability resulting from its intrinsic low electrical conductivity limit its applications. In this work, TiO₂ nanoparticles were coated with reduced graphene oxide (R ) using a combination of spray-drying and heat treatment. Electrochemical tests showed that the obtained R /TiO₂ composites had improved electrochemical performances. The reversible capacities of the R /TiO₂ [4.0% (w)] composites were 183.7 mAh·g^-1 (20 mA·g^-1), 153.7 mAh·g^-1 (100 mA·g^-1), and 114.4 mAh·g^-1 (600 mA·g^-1). Bare TiO₂ showed low capacities of 93.6mAh·g^-1 (20mA·g^-1), 69.6mAh·g^-1 (100mA·g^-1), and 26.5mAh·g^-1 (600 mA·g^-1). The 4.0%(w) TiO₂/R composites exhibited od cycling stability with a charge capacity of 146.7 mAh·g^-1 at a current density of 100 mA·g^-1 after 350 cycles, compared with 68.8 mAh·g^-1 for bare TiO₂. R modification is a promising method for improving the electrochemical performances of the sodium energystorage materials.
- Titanium dioxide,
- Reduced graphene oxide,
- Anode material,
- Sodium ion battery
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