通过3He(d, p)4He核反应研究He在Ti3SiC2中的扩散行为

引用本文: 戚强, HUANG Mengbing, 张海斌, 施立群. 通过³He(d, p)⁴He核反应研究He在Ti₃SiC₂中的扩散行为[J]. 物理化学学报, 2015, 31(S1): 54-58. doi: 10.3866/PKU.WHXB2014Ac15 shu

Citation: QI Qiang, HUANG Mengbing, ZHANG Hai-Bin, SHI Li-Qun. Investigation of Helium Diffusion Behavior in Ti₃SiC₂ by ³He (d, p) ⁴He Nuclear Reaction[J]. Acta Physico-Chimica Sinica, 2015, 31(S1): 54-58. doi: 10.3866/PKU.WHXB2014Ac15 shu

通过³He(d, p)⁴He核反应研究He在Ti₃SiC₂中的扩散行为

1.
1 复旦大学现代物理研究所, 应用离子束教育部重点实验室, 上海200433;
2.
2 纽约州立大学奥尔巴尼分校, 纳米科学与工程学院离子束实验室, 奥尔巴尼12203, 纽约, 美国;
3.
3 中国工程物理研究院核物理与化学研究所, 四川绵阳610003;
4.
4 中国科学院等离子体物理研究所, 合肥230031

通讯作者: 施立群

摘要: 对于未来聚变和裂变能源装置, 第一壁/包层的结构材料处于严酷的使用环境. 其中嬗变产物氢氦对结构材料的作用是所关心的重要问题之一. Ti₃SiC₂是一种新型的高性能综合性陶瓷材料——金属陶瓷材料, 具有十分优异的耐高温抗辐照特性. 本文通过³He (d, p) ⁴He核反应方法获得了400 至1100 ℃ He在Ti₃SiC₂中的扩散系数以及氦在材料中的深度分布, 并对氦的扩散行为进行了讨论. 发现氦在材料中的演化和内应力的共同作用导致了氦分布的变化.

关键词:

English

Investigation of Helium Diffusion Behavior in Ti₃SiC₂ by ³He (d, p) ⁴He Nuclear Reaction

1.
1 Applied Ion Beam Physics Laboratory, Institute of Modern Physics, Fudan University, Shanghai 200433, P. R. China;
2.
2 Ion Beam Laboratory, State University of New York (SUNY) at Albany & SUNY College of Nanoscale Science and Engineering, Albany 12203, New York, U. S. A.;
3.
3 Institute of Nuclear Physics and Chemistry, Chinese Academy of Engineering Physics, Mianyang 610003, Sichuan Province, P. R. China;
4.
4 Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, P. R. China

Corresponding author: 施立群

Abstract: In fusion and fission energy devices, the first wall/cladding structure materials are in a harsh environment. The effect of hydrogen and helium produced by transmutation on the structural materials is one of the critical problems for future nuclear reactors. Ti₃SiC₂ is a high performance ceramic material that combines the advantages of ceramics and metals, and it has excellent resistance to irradiation damage. In this work, the helium diffusion constants and concentration profiles in Ti₃SiC₂ from 400 to 1100 ℃ were obtained using the resonant ³He (d, p) ⁴He nuclear reaction, and the helium diffusion behavior is also discussed. The concentration profiles were found to change because of the interaction between helium evolution and stress in the material.

Key words:

1. [1]
  (1) Oo, Z.; Low, I. M.; O'Connor, B. H. Physica B 2006, 385-386, 499.(1) Oo, Z.; Low, I. M.; O'Connor, B. H. Physica B 2006, 385-386, 499.
2. [2]
  (2) Barsoum, M.W. Prog. Solid State Chem. 2000, 28, 201. doi: 10.1016/S0079-6786(00)00006-6(2) Barsoum, M.W. Prog. Solid State Chem. 2000, 28, 201. doi: 10.1016/S0079-6786(00)00006-6
3. [3]
  (3) Gilbert, C. J.; Bloyer, D. R.; Barsoum, M.W.; El-Raghy, T.; Tomsia, A. P.; Ritchie, R. O. Scripta Mater. 2000, 42, 761. doi: 10.1016/S1359-6462(99)00427-3(3) Gilbert, C. J.; Bloyer, D. R.; Barsoum, M.W.; El-Raghy, T.; Tomsia, A. P.; Ritchie, R. O. Scripta Mater. 2000, 42, 761. doi: 10.1016/S1359-6462(99)00427-3
4. [4]
  (4) Barsoum, M.W.; El-Raghy, T.; Rawn, C. J.; Porter, W. D.; Wang, H.; Payzant, E. A.; Hubbard, C. R. J. Phys. Chem. Solids 1999, 60, 429. doi: 10.1016/S0022-3697(98)00313-8(4) Barsoum, M.W.; El-Raghy, T.; Rawn, C. J.; Porter, W. D.; Wang, H.; Payzant, E. A.; Hubbard, C. R. J. Phys. Chem. Solids 1999, 60, 429. doi: 10.1016/S0022-3697(98)00313-8
5. [5]
  (5) Gao, N. F.; Miyamoto, Y.; Zhang, D. Mater. Lett. 2002, 55, 61. doi: 10.1016/S0167-577X(01)00620-6(5) Gao, N. F.; Miyamoto, Y.; Zhang, D. Mater. Lett. 2002, 55, 61. doi: 10.1016/S0167-577X(01)00620-6
6. [6]
  (6) El-Raghy, T.; Barsoum, M.W.; Zavaliangos, A.; Kalidindi, S. R. J. Am. Ceram. Soc. 1999, 82, 2855.(6) El-Raghy, T.; Barsoum, M.W.; Zavaliangos, A.; Kalidindi, S. R. J. Am. Ceram. Soc. 1999, 82, 2855.
7. [7]
  (7) Whittle, K. R.; Blackford, M. G.; Aughterson, R. D.; Moricca, S.; Lumpkin, G. R.; Riley, D. P.; Zaluzec, N. J. Acta Mater. 2010, 58, 4362. doi: 10.1016/j.actamat.2010.04.029(7) Whittle, K. R.; Blackford, M. G.; Aughterson, R. D.; Moricca, S.; Lumpkin, G. R.; Riley, D. P.; Zaluzec, N. J. Acta Mater. 2010, 58, 4362. doi: 10.1016/j.actamat.2010.04.029
8. [8]
  (8) Barsoum, M.W.; El-Raghy T. Am. Sci. 2001, 89, 334. doi: 10.1511/2001.28.736(8) Barsoum, M.W.; El-Raghy T. Am. Sci. 2001, 89, 334. doi: 10.1511/2001.28.736
9. [9]
  (9) Kooi, B. J.; Poppen, R. J.; Carvalho, N. J. M.; De Hosson, J. T. M.; Barsoum, M.W. Acta Mater. 2003, 51, 2859.(9) Kooi, B. J.; Poppen, R. J.; Carvalho, N. J. M.; De Hosson, J. T. M.; Barsoum, M.W. Acta Mater. 2003, 51, 2859.
10. [10]
  (10) Costantini, J. M.; Trocellier, P.; Haussy, J.; Grob, J. J. Nucl. Instrum. Meth. B 2002, 195, 400. doi: 10.1016/S0168-583X(02)01137-0(10) Costantini, J. M.; Trocellier, P.; Haussy, J.; Grob, J. J. Nucl. Instrum. Meth. B 2002, 195, 400. doi: 10.1016/S0168-583X(02)01137-0
11. [11]
  (11) Costantini, J. M.; Grob, J. J.; Haussy, J.; Trocellier, P.; Trouslard, P. J. Nucl. Mater. 2003, 321, 281. doi: 10.1016/S0022-3115(03)00280-0(11) Costantini, J. M.; Grob, J. J.; Haussy, J.; Trocellier, P.; Trouslard, P. J. Nucl. Mater. 2003, 321, 281. doi: 10.1016/S0022-3115(03)00280-0
12. [12]
  (12) Zielinski, F.; Costantini, J. M.; Haussy, J.; Durbin, F. J. Nucl. Mater. 2003, 312, 141. doi: 10.1016/S0022-3115(02)01589-1(12) Zielinski, F.; Costantini, J. M.; Haussy, J.; Durbin, F. J. Nucl. Mater. 2003, 312, 141. doi: 10.1016/S0022-3115(02)01589-1
13. [13]
  (13) Dominique, G.; Patrick, T.; Yves, S. J. Nucl. Mater. 2002, 303, 115. doi: 10.1016/S0022-3115(02)00822-X(13) Dominique, G.; Patrick, T.; Yves, S. J. Nucl. Mater. 2002, 303, 115. doi: 10.1016/S0022-3115(02)00822-X
14. [14]
  (14) Paszti, F. Nucl. Instrum. Meth. B 1992, 66, 83. doi: 10.1016/0168-583X(92)96143-M(14) Paszti, F. Nucl. Instrum. Meth. B 1992, 66, 83. doi: 10.1016/0168-583X(92)96143-M
15. [15]
  (15) Qi, Q.; Cheng, G. J.; Shi, L. Q.; O'Connor, D. J.; King, B. V.; Kisi, E. H. Acta Mater. 2014, 66, 317. doi: 10.1016/j.actamat.2013.11.019(15) Qi, Q.; Cheng, G. J.; Shi, L. Q.; O'Connor, D. J.; King, B. V.; Kisi, E. H. Acta Mater. 2014, 66, 317. doi: 10.1016/j.actamat.2013.11.019
16. [16]
  (16) Ziegler, J. F.; Biersack, J. P. The Stopping and Range of Ions in Matter (SRIM), SRIM 2010; http://www.srim.org.(16) Ziegler, J. F.; Biersack, J. P. The Stopping and Range of Ions in Matter (SRIM), SRIM 2010; http://www.srim.org.
17. [17]
  (17) Mayer, J.W.; Rimini, E. Ion Beam Handbook for Material Analysis; Academic: New York, 1977.(17) Mayer, J.W.; Rimini, E. Ion Beam Handbook for Material Analysis; Academic: New York, 1977.
18. [18]
  (18) Biersack, J. P.; Haggmark, L. G. Nucl. Instrum. Meth. B 1980, 174, 257. doi: 10.1016/0029-554X(80)90440-1(18) Biersack, J. P.; Haggmark, L. G. Nucl. Instrum. Meth. B 1980, 174, 257. doi: 10.1016/0029-554X(80)90440-1
19. [19]
  (19) Ryssel, H.; Ruge, I. Ion Implantation;Wiley: Chichester, 1986.(19) Ryssel, H.; Ruge, I. Ion Implantation;Wiley: Chichester, 1986.
20. [20]
  (20) Philibert, J. Diffusion and Matter Transport in Solids; Philibert, J. Ed.; de Physique: Paris, 1985.(20) Philibert, J. Diffusion and Matter Transport in Solids; Philibert, J. Ed.; de Physique: Paris, 1985.
21. [21]
  (21) Reed, D. J. Radiat. Effects 1977, 31, 129.(21) Reed, D. J. Radiat. Effects 1977, 31, 129.
22. [22]
  (22) Lewis, M. B.; Farell, K. Nucl. Instrum. Meth. B 1986, 16, 163. doi: 10.1016/0168-583X(86)90008-X(22) Lewis, M. B.; Farell, K. Nucl. Instrum. Meth. B 1986, 16, 163. doi: 10.1016/0168-583X(86)90008-X
23. [23]
  (23) Donnelly, S. E.; Evans, J. H. Eds. Fundamentals of Inert Gases in Solids; Plenum: New York, 1991.(23) Donnelly, S. E.; Evans, J. H. Eds. Fundamentals of Inert Gases in Solids; Plenum: New York, 1991.
24. [24]
  (24) Vassen, R.; Trinkaus, H.; Jung, P. Phys. Rev. B 1991, 44, 4206. doi: 10.1103/PhysRevB.44.4206(24) Vassen, R.; Trinkaus, H.; Jung, P. Phys. Rev. B 1991, 44, 4206. doi: 10.1103/PhysRevB.44.4206
25. [25]
  (25) Jia, L. X.; Wang, Y. X.; Ou, X. D.; Shi, L.Q.; Ding, W. Mater. Lett. 2012, 83, 23. doi: 10.1016/j.matlet.2012.05.093(25) Jia, L. X.; Wang, Y. X.; Ou, X. D.; Shi, L.Q.; Ding, W. Mater. Lett. 2012, 83, 23. doi: 10.1016/j.matlet.2012.05.093
26. [26]
  (26) Middleburgh, S. C.; Lumpkin, G. R.; Riley, D. P. J. Am. Ceram. Soc. 2013, 96, 3196.(26) Middleburgh, S. C.; Lumpkin, G. R.; Riley, D. P. J. Am. Ceram. Soc. 2013, 96, 3196.

扫一扫看文章

计量

PDF下载量: 261
文章访问数: 1225
HTML全文浏览量: 34

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

通过³He(d, p)⁴He核反应研究He在Ti₃SiC₂中的扩散行为

通讯作者: 施立群

English

Investigation of Helium Diffusion Behavior in Ti₃SiC₂ by ³He (d, p) ⁴He Nuclear Reaction

Corresponding author: 施立群

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处