Citation: YUE Ling, HE Zi-Meng, WANG Yu-Qin, SHANG Ya-Zhuo, LIU Hong-Lai. Effect of the Surfactant C₁₂mimBr on the Aggregation Behavior of Gemini12-2-12 at an Air/Water Interface, Investigated Using an Interfacial Dilational Rheology Method[J]. Acta Physico-Chimica Sinica, ;2014, 30(12): 2291-2299. doi: 10.3866/PKU.WHXB201410222 shu

Effect of the Surfactant C₁₂mimBr on the Aggregation Behavior of Gemini12-2-12 at an Air/Water Interface, Investigated Using an Interfacial Dilational Rheology Method

1.
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China

Received Date: 29 September 2014
Available Online: 22 October 2014
Fund Project: 国家自然科学基金(21173079, 91334203, 21476072)资助项目 (21173079, 91334203, 21476072)

The dynamic interfacial tension, dilational rheological properties, and interfacial relaxation processes of quaternary ammonium Gemini surfactant C₁₂-(CH₂)₂-C₁₂·2Br (Gemini12-2-12) solutions and Gemini12-2-12/ ionic liquid surfactant C₁₂mimBr mixed systems at an air/water interface were investigated using an interfacial dilational rheology method at low frequencies (0.02-0.50 Hz). The effect of the C₁₂mimBr on the interfacial properties of the Gemini12-2-12/C₁₂mimBr mixed systems, and the mechanism responsible for the influence of C₁₂mimBr on the aggregation behavior of the Gemini12-2-12 at the air/water interface, are discussed here. The experimental results showed that with increasing the amount of C₁₂mimBr, the time required to achieve interfacial adsorption equilibrium for the mixed systems was reduced, the dilational moduli and phase angle in the mixed systems decreased, and the interfacial adsorption films were inclined to become elastic. Simultaneously, the relaxation processes at the interface or near the interface changed significantly, the slow relaxation process disappeared, and a fast relaxation process dominated the properties of the interfacial films. Moreover, the contribution of the fast relaxation process increased with increasing the concentration of C₁₂mimBr. The abovementioned changes in the interfacial properties were mainly attributed to the participation of the C₁₂mimBr in the formation of the interface, and the competitive adsorption of the two surfactants at the air/water interface. At lower concentrations of C₁₂mimBr, the C₁₂mimBr molecules filled the vacancies between the Gemini12-2-12 molecules when the Gemini12-2-12 molecules were loosely arranged at the interface, and mixedadsorption films formed from C₁₂mimBr and Gemini12-2-12 spread on the air/water interface. With increasing the concentration of C₁₂mimBr, the alkyl chains of the Gemini12-2-12 molecules that were wrapped around each other at the air/water interface untangled, and the Gemini12-2-12 molecules underwent desorption from the interface. At the same time, C₁₂mimBr molecules replaced Gemini12-2-12 molecules, because of their low steric hindrance and strong hydrophobic effects; ultimately, C₁₂mimBr molecules almost entirely occupied the air/water interface.
- Ionic liquid surfactant,
- Gemini surfactant,
- Competitive adsorption,
- Interface behavior,
- Dilational rheological property
1. [1]
  
  (1) Wu, S. S. Chemical World 1990, 1, 44. [吴树森. 化学世界, 1990, 1, 44.]
2. [2]
  (2) Li, H. Z. The Chinese Journal of Process Engineering 2006, 6 (6), 991. [李洪钟. 过程工程学报, 2006, 6 (6), 991.]
3. [3]
  (3) Richardson, R. M.; Pelton, R.; Cosgrove, T.; Zhang, J. Macromolecules 2000, 33, 6269. doi: 10.1021/ma000095p
4. [4]
  (4) Noskov, B. A.; Alexandrov, D. A.; Loglio, G.; Miller, R. Colloids Surf. A 1999, 156, 307. doi: 10.1016/S0927-7757(99)00082-5
5. [5]
  (5) Bonfillon, A.; Langevin, D. Langmuir 1993, 9, 2172. doi: 10.1021/la00032a045
6. [6]
  (6) Bonfillon, A.; Langevin, D. Langmuir 1994, 10, 2965. doi: 10.1021/la00021a020
7. [7]
  (7) Regismond, T. A.; Gracie, K. D.;Winnik, F. M.; ddard, E. D. Langmuir 1997, 13, 5558. doi: 10.1021/la9702289
8. [8]
  (8) Babak, V. G.; Merkovich, E. A.; Galbraikh, L. S. Mendeleev Commun. 2000, 94.
9. [9]
  (9) Babak, V. G.; Lukina, I.; Vikhoreva, G. A.; Desbrieres, J.; Rinaudo, M. Colloids Surf. A 1999, 147, 139. doi: 10.1016/S0927-7757(98)00752-3
10. [10]
  (10) Babak, V. G.; Desbrieres, J. Colloid Polym. Sci. 2006, 284, 745. doi: 10.1007/s00396-005-1427-x
11. [11]
  (11) Babak, V. G.; Baros, F.; Boury, F.; Desbrieres, J.; Vikhoreva, G. A. Mendeleev Commun. 2008, 18, 35. doi: 10.1016/j.mencom.2008.01.014
12. [12]
  (12) Babak, V. G.; Auzely, R.; Rinaudo, M. J. Phys. Chem. B 2007, 111, 9519. doi: 10.1021/jp0718653
13. [13]
  (13) Noskov, B. A.; Loglio, G.; Miller, R. J. Phys. Chem. B 2004, 108, 18615. doi: 10.1021/jp046560s
14. [14]
  (14) Noskov, B. A.; Lin, S. Y.; Loglio, G.; Rubio, R. G.; Miller, R. Langmuir 2006, 22, 2647. doi: 10.1021/la052662d
15. [15]
  (15) Fainerman, V. B.; Petkov, J. T.; Miller, R. Langmuir 2008, 24, 6447. doi: 10.1021/la704058y
16. [16]
  (16) Noskov, B. A.; Gri riev, D. O.; Latnikova, A. V.; Lin, S. Y.; Loglio, G.; Miller, R. J. Phys. Chem. B 2009, 113, 13398. doi: 10.1021/jp905413q
17. [17]
  (17) Fainerman, V. B.; Aksenenko, E. V.; Zholob, S. A.; Petkov, J. T.; Yorke, J.; Miller, R. Langmuir 2010, 26, 1796. doi: 10.1021/la9024926
18. [18]
  (18) Fang, H. B.; Zong, H.; Mao, L. T.; Zhang, L.; Cui, G. Z.; Zhao, S.; Yu, J. Y. J. Dis. Sci. Technol. 2010, 31, 1652.
19. [19]
  (19) Zhou, Z. H.; Zhang, L.; Xu, Z. C.; Zhao, S.; Yu, J. Y. J. Dis. Sci. Technol. 2011, 32, 95.
20. [20]
  (20) Wang, Z. L.; Li, Z. Q.; Zhang, L.; Huang, H. Y.; Zhang, L.; Zhao, S.; Yu, J. Y. J. Chem. Eng. Data 2011, 56, 2393. doi: 10.1021/je1013312
21. [21]
  (21) Zhang, J. C.; Zhang, L.;Wang, X. C.; Zhang, L.; Zhao, S.; Yu, J. Y. J. Dis. Sci. Technol. 2011, 32, 372. doi: 10.1080/01932691003662381
22. [22]
  (22) Song, X.W.; Zhang, L.;Wang, X. C.; Zhang, L.; Zhao, S.; Yu, J. Y. J. Dis. Sci. Technol. 2011, 32, 247. doi: 10.1080/01932691003657001
23. [23]
  (23) Cui, X. H.; Zhang, L.; Luo, L.; Zhang, L.; Zhao, S.; Yu, J. Y. Colloids Surf. A 2010, 369, 106. doi: 10.1016/j.colsurfa.2010.08.012
24. [24]
  (24) Sun, H. Q.; Zhang, L.; Zhao, S.; Yu, J. Y. J. Dis. Sci. Technol. 2011, 32, 389. doi: 10.1080/01932691003662407
25. [25]
  (25) Ma, B. D.; Zhang, L.; Gao, B. Y.; Zhao, S.; Yu, J. Y. Colloid Polym. Sci. 2011, 289, 911. doi: 10.1007/s00396-011-2415-y
26. [26]
  (26) He, F.; Xu, G. Y.; Pang, J. Y.; Ao, M. Q.; Han, T. T.; ng, H. J. Langmuir 2011, 27, 538. doi: 10.1021/la103478c
27. [27]
  (27) Zhu, Y. Y.; Xu, G. Y.; Xin, X.; Zhang, H. X.; Shi, X. F. J. Chem. Eng. Data 2009, 54, 989. doi: 10.1021/je800788f
28. [28]
  (28) Che, Y. J.; Cao, J.; ng, H. J.; Xu, G. Y.; Tan, Y. B. J. Dis. Sci. Technol. 2011, 32, 174. doi: 10.1080/01932691003656698
29. [29]
  (29) Pei, X. M.; You, Y.; Zhao, J. X.; Deng, Y. S.; Li, E. J.; Li, Z. X. J. Colloid Interface Sci. 2010, 351, 457. doi: 10.1016/j.jcis.2010.07.076
30. [30]
  (30) You, Y.; Zhong, B. X.; Zhao, J. X. Colloid Polym. Sci. 2010, 288, 1359. doi: 10.1007/s00396-010-2265-z
31. [31]
  (31) Zhao, J. X.; Deng, Y. S.; Pei, X. M. Colloids Surf. A 2010, 369, 34. doi: 10.1016/j.colsurfa.2010.07.027
32. [32]
  (32) Wu, X. N.; Zhao, J. X.; Li, E. J.; Zou,W. S. Colloid Polym. Sci. 2011, 289, 1025. doi: 10.1007/s00396-011-2425-9
33. [33]
  (33) Angle, C.W.; Hua, Y. J. Energy Fuels 2012, 26, 6228. doi: 10.1021/ef300846z
34. [34]
  (34) Angle, C.W.; Hua, Y. J. Energy Fuels 2013, 27, 3613. doi: 10.1021/ef4003928
35. [35]
  (35) Reichert, M. D.;Walker, L. M. Langmuir 2013, 29, 1857. doi: 10.1021/la4000395
36. [36]
  (36) Takajo, Y.; Yamanaka, M.; Rubio, R. G.; Takiue, T.; Matsubara, H.; Aratono, M. J. Phys. Chem. C 2013, 117, 1097. doi: 10.1021/jp311283a
37. [37]
  (37) Zana, R.; Benrraou, M.; Rueff, R. Langmuir 1991, 7, 1072. doi: 10.1021/la00054a008
38. [38]
  (38) Lucassen, J.; Van Den Tempel, M. Chemical Engineering Science 1972, 27, 1283. doi: 10.1016/0009-2509(72)80104-0
39. [39]
  (39) Lucassen-Reynders, E. H. Anionic Surfactants; MercelDekker: Inc.: New York, 1981, p 173.
40. [40]
  (40) van den Tempel, M.; Lucassen-Reynders, E. H. Advances in Colloid and Interface Science 1983, 18, 281. doi: 10.1016/0001-8686(83)87004-3
41. [41]
  (41) Wu, D.; Feng, Y. J.; Xu, G. Y.; Chen, Y. J.; Cao, X. R.; Li, Y. M. Colloids Surf. A 2007, 299, 117. doi: 10.1016/j.colsurfa.2006.11.031
42. [42]
  (42) Zhang, L.;Wang, X. C.; Yan, F.; Luo, L.; Zhang, L.; Zhao, S.; Yu, J. Y. Colloid Polym. Sci. 2008, 286, 1291. doi: 10.1007/s00396-008-1894-y
43. [43]
  (43) Cao, C.; Huang, T.; Zhang, L.; Du, F. P. Colloids Surf. A 2013, 436, 557. doi: 10.1016/j.colsurfa.2013.07.013
44. [44]
  (44) Zhang, L.;Wang, X. C.; Yan, F. Colloid Polym. Sci. 2008, 286, 1291. doi: 10.1007/s00396-008-1894-y
45. [45]
  (45) Dou, L. X.; Cheng, J. B. Chemical Journal of Chinese Universities 2010, 31 (2), 361 [窦立霞, 程建波. 高等学校化学学报, 2010, 31 (2), 361.]
46. [46]
  (46) Zhang, C. R.; Li, Z. Q.; Luo, L.; Zhang, L.; Song, X.W.; Cao, X. L.; Zhao, S.; Yu, J. Y. Acta Phys. -Chim. Sin. 2007, 23 (2), 247. [张春荣, 李振泉, 罗澜, 张路, 宋新旺, 曹绪龙, 赵濉, 俞稼镛. 物理化学学报, 2007, 23 (2), 247.] doi: 10.3866/PKU.WHXB20070221
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Effect of the Surfactant C12mimBr on the Aggregation Behavior of Gemini12-2-12 at an Air/Water Interface, Investigated Using an Interfacial Dilational Rheology Method

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通讯作者: 陈斌, bchen63@163.com

Effect of the Surfactant C₁₂mimBr on the Aggregation Behavior of Gemini12-2-12 at an Air/Water Interface, Investigated Using an Interfacial Dilational Rheology Method