Citation: WANG Jian-De, PENG Tong-Jiang, SUN Hong-Juan, HOU Yun-Dan. Effect of the Hydrothermal Reaction Temperature on Three-Dimensional Reduced Graphene Oxide's Appearance, Structure and Super Capacitor Performance[J]. Acta Physico-Chimica Sinica, ;2014, 30(11): 2077-2084. doi: 10.3866/PKU.WHXB201409152 shu

Effect of the Hydrothermal Reaction Temperature on Three-Dimensional Reduced Graphene Oxide's Appearance, Structure and Super Capacitor Performance

1.
1. School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, Sichuan Province, P. R. China;
2. Center of Forecasting and Analysis, Southwest University of Science and Technology, Mianyang 621010, Sichuan Province, P. R. China;
3. Institute of Mineral Materials & Application, Southwest University of Science and Technology, Mianyang 621010, Sichuan Province, P. R. China

Received Date: 28 July 2014
Available Online: 15 September 2014
Fund Project: 国家自然科学基金(41272051) (41272051) 西南科技大学博士基金(11ZX7135) (11ZX7135)西南科技大学研究生创新基金(14ycx003)资助项目 (14ycx003)

Three-dimensional reduction of graphene oxide with a series of different degrees of reduction was performed by the hydrothermal method in the temperature range from 120 to 220 ℃, with graphene oxide sols as the precursor and prepared by graphite oxide gels. The effect of the temperature of the hydrothermal reaction on the materials appearance, structure, and super capacitor performance was investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and electrochemical measurements. The results show that the prepared three dimensional reduction of graphene oxide was porous and reticulated, and its volume and inner mesh aperture gradually decreased with increasing temperature, while its degree of reduction and order increased at the same time, and its structure gradually transformed to the graphite oxide structure. However, thematerials' specific capacitance and energy density showed the tendency of first increasing and then decreasing, with the electric double-layer capacitor mainly remaining. The three-dimensional reduction of graphene oxide materials at 180 ℃ resulted in the best super capacitor performance, with a specific capacitance of 315 F·g^-1 when the current density was 0.5 A·g^-1 and 212 F·g^-1 when the current density was 10 A·g^-1. Its energy density was 40.5 Wh·kg^-1 and its specific capacitance was 86% after 5000 cycles, with all these properties indicating its od super capacitor performance.
- Graphite oxide gel,
- Hydrothermal method,
- Porous and reticulated,
- Supercapacitor,
- Specific capacitance
1. [1]
  
  (1) Sarangapani, S.; Tilak, B. V.; Chen, C. P. J. Electrochem. Soc. 1996, 143 (11), 3791. doi: 10.1149/1.1837291
2. [2]
  (2) Arbizzani, C.; Mastra stino, M.; Soavi, F. J. Power Sources 2001, 100 (1), 164.
3. [3]
  (3) Zheng, J. P.; Jow, T. R. J. Power Sources 1996, 62 (2), 155. doi: 10.1016/S0378-7753(96)02424-X
4. [4]
  (4) Zheng, J. P.; Jow, T. R. J. Electrochem. Soc. 1995, 142 (1), L6.
5. [5]
  (5) Frackowiak, E. Phys. Chem. Chem. Phys. 2007, 9 (15), 1774.
6. [6]
  (6) Zhu, Y.; Murali, S.; Stoller, M. D.; Ganesh, K. J.; Cai,W.; Ferreira, P. J.; Ruoff, R. S. Science 2011, 332 (6037), 1537. doi: 10.1126/science.1200770
7. [7]
  (7) Liu, D.; Shen, J.; Li, Y. J.; Liu, N. P.; Liu, B. Acta Phys. -Chim. Sin. 2012, 28 (4), 843. [刘冬, 沈军, 李亚捷, 刘念平, 刘斌. 物理化学学报, 2012, 28 (4), 843.] doi: 10.3866/PKU.WHXB201202172
8. [8]
  (8) Lei, Y.; Li, J.;Wang, Y.; Gu, L.; Chang, Y.; Yuan, H.; Xiao, D. ACS Appl. Mat. Interfaces 2014, 6 (3), 1773. doi: 10.1021/am404765y
9. [9]
  (9) Chen, L.; Li, B.; Qi, Z.; Guo, H.; Zhou, J.; Li, L. J. Electron. Mater. 2013, 42 (10), 2933.
10. [10]
  (10) Jin, Y.; Chen, H. Y.; Chen, M. H.; Liu, N.; Li, Q.W. Acta Phys. -Chim. Sin. 2012, 28 (3), 609. [靳瑜, 陈宏源, 陈名海, 刘宁, 李清文. 物理化学学报, 2012, 28 (3), 609.] doi: 10.3866/PKU.WHXB201201162
11. [11]
  (11) Ma, J.; Liu, Y.; Hu, Z.; Xu, Z. Solid State Ionics 2013, 19 (10), 1405.
12. [12]
  (12) Mao, L.; Zhang, K.; Chan, H. S. O.;Wu, J. J. Mater. Chem. 2012, 22 (5), 1845. doi: 10.1039/c1jm14503g
13. [13]
  (13) Sun, X. Z.; Zhang, X.; Zhang, D. C.; Ma, Y.W. Acta Phys. -Chim. Sin. 2012, 28 (2), 367. [孙现众, 张熊, 张大成, 马衍伟. 物理化学学报, 2012, 28 (2), 367.] doi: 10.3866/PKU.WHXB201112131
14. [14]
  (14) Che, Q.; Zhang, F.; Zhang, X. G.; Lu, X. J.; Ding, B.; Zhu, J. J. Acta Phys. -Chim. Sin. 2012, 28 (4), 837. [车倩, 张方, 张校刚, 卢向军, 丁兵, 朱佳佳. 物理化学学报, 2012, 28 (4), 837.] doi: 10.3866/PKU.WHXB201202074
15. [15]
  (15) Niu, Z. Q.; Liu, L. L.; Zhang, L.; Shao, Q.; Zhou,W. Y.; Chen, X. D.; Xie, S. S. Adv. Mater. 2014, 26 (22), 3681. doi: 10.1002/adma.v26.22
16. [16]
  (16) Novoselo, V. K. S.; Geim, A. K.; Morozo, V. S. V. Science 2004, 306, 666. doi: 10.1126/science.1102896
17. [17]
  (17) Kane, C. L. Nature 2005, 438 (7065), 168. doi: 10.1038/438168a
18. [18]
  (18) Stoller, M. D.; Park, S. J.; Zhu, Y.; An, J.; Ruoff, R. S. Nano Lett. 2008, 8 (10), 3498. doi: 10.1021/nl802558y
19. [19]
  (19) Vivekchand, S. R. C.; Rout, C. S.; Subrahmanyam, K. S.; vindaraj, A.; Rao, C. N. R. Chem. Sci. 2008, 120 (1), 9. doi: 10.1007/s12039-008-0002-7
20. [20]
  (20) Wang, Y.; Shi, Z.; Huang, Y.; Ma, Y.;Wang, C.; Chen, M.; Chen, Y. J. Phys. Chem. C 2009, 113 (30), 13103. doi: 10.1021/jp902214f
21. [21]
  (21) Ye, J.; Zhang, H. Y.; Chen, Y. M.; Cheng, Z. D.; Hu, L.; Ran, Q. Y. J. Power Sources 2012, 212, 105. doi: 10.1016/j.jpowsour.2012.03.101
22. [22]
  (22) Lv,W.; Tang, D. M.; He, Y. B.; You, C. H.; Shi, Z. Q.; Chen, X. C. ACS Nano 2009, 3 (11), 3730. doi: 10.1021/nn900933u
23. [23]
  (23) Shen, B.; Lu, D.; Zhai,W.; Zheng,W. J. Phys. Chem. C 2013, 1 (1), 50.
24. [24]
  (24) Xu, Y.; Lin, Z.; Huang, X.;Wang, Y.; Huang, Y.; Duan, X. Adv. Mater. 2013, 25 (40), 5779. doi: 10.1002/adma.v25.40
25. [25]
  (25) Bi, H.; Yin, K.; Xie, X.; Zhou, Y.;Wan, N.; Xu, F.; Banhart, F.; Sun, L.; Ruoff, R. S. Adv. Mater. 2012, 24, 5124. doi: 10.1002/adma.201201519
26. [26]
  (26) Xu, Y.; Shi, G. J. Mater. Chem. 2011, 21 (10), 3311.
27. [27]
  (27) Dreyer, D. R.; Park, S.; Bielawski, C.W.; Ruoff, R. S. Chem. Soc. Rev. 2010, 39 (1), 228. doi: 10.1039/b917103g
28. [28]
  (28) Thomsen, C.; Reich, S. Phys. Rev. Lett. 2000, 85, 5214. doi: 10.1103/PhysRevLett.85.5214
29. [29]
  (29) Yang, Y. H.; Sun, H. J.; Peng, T. J.; Huang, Q. Acta Phys. -Chim. Sin. 2011, 27 (3), 736. [杨勇辉, 孙红娟, 彭同江, 黄桥. 物理化学学报, 2011, 27 (3), 736.] doi: 10.3866/PKU.WHXB20110320
30. [30]
  (30) Du, Q.; Zheng, M.; Zhang, L.;Wang, Y.; Chen, J.; Xue, L.; Cao, J. Electrochim. Acta 2010, 55 (12), 3897. doi: 10.1016/j.electacta.2010.01.089
31. [31]
  (31) Chen, S.; Zhu, J.;Wu, X.; Han, Q.;Wang, X. ACS Nano 2010, 4 (5), 2822. doi: 10.1021/nn901311t
32. [32]
  (32) Mao, Lu.; Zhang, K.; Chan, H. S. O.;Wu, J. S. J. Mater. Chem. 2012, 22, 1845. doi: 10.1039/c1jm14503g
33. [33]
  (33) Simon, P.; tsi, Y. Nat. Mater. 2008, 7 (11), 845.
34. [34]
  (34) Wu, X. L.;Wang,W.; Guo, Y. G.;Wan, L. J.; Nanosci, J. Nano Technol. 2011, 11 (3), 1897.
35. [35]
  (35) Polat, E. O.; Kocabas, C. Nano Lett. 2013, 13 (12), 5851. doi: 10.1021/nl402616t
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