Citation: ZHENG Jie-Yun, WANG Rui, LI Hong. Fabrication and Electrochemical Behavior of a Pure-Phase Li₂MnO₃ Thin Film for Cathode Material of Li-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2014, 30(10): 1855-1860. doi: 10.3866/PKU.WHXB201407151 shu

Fabrication and Electrochemical Behavior of a Pure-Phase Li₂MnO₃ Thin Film for Cathode Material of Li-Ion Batteries

1.
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 17 March 2014
Available Online: 15 July 2014
Fund Project:

Li₂MnO₃ materials were synthesized by solid state reactions. A series of Li₂MnO₃ thin films were fabricated at different temperatures under O₂ by pulsed laser deposition (PLD) using a home-made Li₂MnO₃ target. The structure and morphology of the as- prepared Li₂MnO₃ thin films were characterized by X- ray diffraction (XRD), Raman spectroscopy, and scanning electron microscopy (SEM). Their electrochemical performance was also investigated. The results show that the crystallinity of the thin films increased with an increase in deposition temperature, and the thin film electrode prepared at lower than 25 ℃ did not work well. The highest electrochemical activity was achieved by the thin film deposited at 400 ℃, and this result is consistent with our previous report on powder materials. The Li₂MnO₃ thin film electrodes deposited at 400 and 600 ℃ exhibited lower discharge voltage decay upon cycling compared with the powder electrode.
- Li₂MnO₃ thin film,
- Cathode material,
- Pulsed laser deposition,
- Potential decay,
- Li-ion battery
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沈阳化工大学材料科学与工程学院沈阳 110142

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Fabrication and Electrochemical Behavior of a Pure-Phase Li₂MnO₃ Thin Film for Cathode Material of Li-Ion Batteries