Citation: XIAO Bo, LIU Shou-Qing. Photocatalytic Oxidation of Ammonia via an Activated Carbon-Nickel Ferrite Hybrid Catalyst under Visible Light Irradiation[J]. Acta Physico-Chimica Sinica, ;2014, 30(9): 1697-1705. doi: 10.3866/PKU.WHXB201407111 shu

Photocatalytic Oxidation of Ammonia via an Activated Carbon-Nickel Ferrite Hybrid Catalyst under Visible Light Irradiation

XIAO Bo ,
LIU Shou-Qing

1.
Jiangsu Key Laboratory of Environmental Functional Materials, School of Chemistry, Biology and Material Engineering, Suzhou University of Science and Technology, Suzhou 215009, Jiangsu Province, P. R. China

Received Date: 18 April 2014
Available Online: 11 July 2014
Fund Project:

The nickel atoms in a metal ferrite lattice inhibit photocatalytic activity with hydrogen peroxide. However, activated carbon bonded on nickel ferrite (AC-NiFe₂O₄) induces photocatalytic activity of nickel ferrite with hydrogen peroxide, enabling photo-Fenton catalytic oxidation of ammonia under visible-light irradiation in the presence of hydrogen peroxide. The AC-NiFe₂O₄ catalyst was characterized using X-ray diffraction, transmission electron microscopy, Fourier-transform infrared spectroscopy, and a vibrating sample magnetometer at room temperature. The photocatalytic tests showed that the ammonia degradation efficiency approached 91.0% in the presence of the AC-NiFe₂O₄ catalyst, whereas the efficiency was only 24.0% without the catalyst under similar conditions over 10 h. Another test showed that the single NiFe₂O₄ catalyst achieved a degradation efficiency of only 30.0% under similar conditions, indicating that activated carbon can accelerate the rate of ammonia oxidation. Exploration of the oxidation mechanism showed that the oxidation pathway involves an HONH₂ intermediate, forming nitrite ions. Kinetic studies showed that the oxidation of ammonia follows a pseudo-first order kinetic law, with a rate constant of 3.538×10^-3 min^-1. The catalyst was used in eight runs, and shown to be stable, recoverable, separable, and reusable, suggesting that it has potential applications in the disposal of ammonia.
- Nickel ferrite,
- Activated carbon,
- Hybrid,
- Photo-Fenton catalyst,
- Ammonia oxidation
1. [1]
  
  (1) Costa, R. C. C.; Lelis, M. F. F.; Oliveira, L. C. A.; Fabris, J. D.; Ardisson, J. D.; Rios, R. R. V. A.; Silva, C. N.; La , R. M. J. Hazard. Mater. B 2006, 129, 171. doi: 10.1016/j.jhazmat.2005.08.028
2. [2]
  (2) Liu, S. Q.; Feng, L. R.; Xu, N.; Chen, Z. G.;Wang, X. M. Chem. Eng. J. 2012, 203, 432. doi: 10.1016/j.cej.2012.07.071
3. [3]
  (3) Fu, Y. S.; Chen, H. Q.; Sun, X. Q.;Wang, X. AIChE J. 2012, 58, 3298. doi: 10.1002/aic.13716
4. [4]
  (4) Pan, X.; Fu, Y.;Wang, L.;Wang, X. Chem. Eng. J. 2012, 149, 195.
5. [5]
  (5) Nguyen, T. D.; Phan, N. H.; Do, M. H.; N , K. T. J. Hazard. Mater. 2011, 185, 653. doi: 10.1016/j.jhazmat.2010.09.068
6. [6]
  (6) Xu, X.;Wang, X. J.; Hu, Z. H.; Liu, Y .F.;Wang, C. C.; Zhao, G. H. Acta Phys. -Chim. Sin. 2010, 26, 79. [徐鑫, 王晓静,胡中华, 刘亚菲, 王晨晨, 赵国华. 物理化学学报, 2010, 26, 79.] doi: 10.3866/PKU.WHXB20100131
7. [7]
  (7) Yang, H. P.; Zhang, Y. C.; Fu, X. F.; Song, S. S.;Wu, J. M. Acta Phys. -Chim. Sin. 2013, 29, 1327. [杨汉培, 张颖超, 傅小飞, 宋双双, 吴俊明. 物理化学学报, 2013, 29, 1327.] doi: 10.3866/PKU.WHXB201303212
8. [8]
  (8) Long, M.; Cong, Y.; Li, X. K.; Cui, Z.W.; Dong, Z. J.; Yuan, G. M. Acta Phys. -Chim. Sin. 2013, 29, 1344. [龙梅, 丛野, 李轩科, 崔正威, 董志军, 袁观明. 物理化学学报, 2013, 29, 1344.] doi: 10.3866/PKU.WHXB201303263
9. [9]
  (9) Xing,W. N.; Ni, L.; Yan, X. S.; Liu, X. L.; Luo, Y. Y.; Lu, Z. Y.; Yan, Y. S.; Huo, P.W. Acta Phys. -Chim. Sin. 2014, 30, 141. [邢伟男, 倪良, 颜学升, 刘馨琳, 罗莹莹, 逯子扬, 闫永胜, 霍鹏伟. 物理化学学报, 2014, 30, 141.] doi: 10.3866/PKU.WHXB201311211
10. [10]
  (10) Ou, H. H.; Hoffmann, M. R.; Liao, C. H.; Hong, J. H.; Lo, S. L. Appl. Catal. B 2010, 99, 74. doi: 10.1016/j.apcatb.2010.06.002
11. [11]
  (11) Bonsen, E. M.; Schroeter, S.; Jacobs, H.; Broekaert, J. A. C. Chemosphere 1997, 35, 1431. doi: 10.1016/S0045-6535(97)00216-6
12. [12]
  (12) Altomare, M.; Chiarello, G. L.; Costa, A.; Guarino, M.; Selli, E.; Chem. Eng. J. 2012, 191, 394. doi: 10.1016/j.cej.2012.03.037
13. [13]
  (13) Kominami, H.; Nishimune, H.; Ohta, Y.; Arakawa, Y.; Inaba, T. Appl. Catal. B 2012, 111, 297.
14. [14]
  (14) Kolinko, P. A.; Kozlov, D. V. Appl. Catal. B 2009, 90, 126. doi: 10.1016/j.apcatb.2009.03.001
15. [15]
  (15) Boulinguiez, B.; Bouzaza, A.; Merabet, S.;Wolbert, D. J. Photochem. Photobiol. A 2008, 200, 254. doi: 10.1016/j.jphotochem.2008.08.005
16. [16]
  (16) Zhu, X.; Nanny, M. A.; Butler, E. C. Water Res. 2008, 42, 2736. doi: 10.1016/j.watres.2008.02.003
17. [17]
  (17) Shavisi, Y.; Sharifnia, S.; Hosseini, S. N.; Khadivi, M. A. J. Ind. Eng. Chem. 2014, 20, 278. doi: 10.1016/j.jiec.2013.03.037
18. [18]
  (18) Dong, Y.; Bai, Z.; Liu, R.; Zhu, T. Atmos. Environ. 2007, 41, 3182. doi: 10.1016/j.atmosenv.2006.08.056
19. [19]
  (19) Geng, Q.; Guo, Q.; Cao, C.; Zhang, Y.;Wang, L. Ind. Eng. Chem. Res. 2008, 47, 4363. doi: 10.1021/ie800274g
20. [20]
  (20) u, H. H.; Liao, C. H.; Liou, Y. H.; Hong, J. H.; Lo, S. L. Environ. Sci. Technol. 2008, 42, 4507. doi: 10.1021/es703211u
21. [21]
  (21) Altomare, M.; Selli, E. Catalysis Today 2013, 209, 127. doi: 10.1016/j.cattod.2012.12.001
22. [22]
  (22) Niedzielski, P.; Kurzyca, I.; Siepak, J. Anal. Chim. Acta 2006, 577, 220. doi: 10.1016/j.aca.2006.06.057
23. [23]
  (23) Lazarevic, Z. ?.; Jovalekic, C.; Recnik, A.; Ivanovski, V. N.; Milutinovic, A.; Romcevic, M.; Pavlovic, M. B.; Cekic, B.; Romcevic, N. ?. Mater. Res. Bull. 2013, 48, 404. doi: 10.1016/j.materresbull.2012.10.061
24. [24]
  (24) Klug, H. P.; Alexander, L. E. X-Ray Diffraction Procedures for Polycrystalline and Amorphous Materials, 2nd ed.;Wiley: New York, 1974.
25. [25]
  (25) Mouallem-Bahout, M.; Bertrand, S.; PeHa, O. J. Solid State Chem. 2005, 178, 1080. doi: 10.1016/j.jssc.2005.01.009
26. [26]
  (26) Hoigne, J.; Bader, H. Environ. Sci. Technol. 1978, 12, 79. doi: 10.1021/es60137a005
27. [27]
  (27) Liao, Q.; Sun, J.; Gao, L. Colloids Surf. A 2009, 345, 95. doi: 10.1016/j.colsurfa.2009.04.037
28. [28]
  (28) Romero, A.; Santos, A.; Vicente, F. J. Hazard. Mater. 2009, 162, 785. doi: 10.1016/j.jhazmat.2008.05.123
29. [29]
  (29) Ramirez, J. H.; Maldonado-Hódar, F. J.; Pérez-Cadenas, A. F.; Moreno-Castilla, C.; Costa, C. A.; Madeira, L. M. Appl. Catal. B 2007, 75, 312. doi: 10.1016/j.apcatb.2007.05.003
30. [30]
  (30) Lam, S.W.; Chiang, K.; Lim, T. M.; Amal, R.; Low, G. K. C. J. Catal. 2005, 234, 292. doi: 10.1016/j.jcat.2005.06.014
31. [31]
  (31) Bacardit, J.; Sto1tzner, J.; Chamarro, E. Eng. Chem. Res. 2007, 46, 7615. doi: 10.1021/ie070154o
32. [32]
  (32) Machulek, A., Jr.; Moraes, J. E. F.; Carolina, Vautier-Gion .; Silverio, C. A.; Friedrich, L. C.; Nascimento, C. A. O.; nzalez, M. C.; Quina, F. H. Environ. Sci. Technol. 2007, 41, 8459. doi: 10.1021/es071884q
33. [33]
  (33) Li, M.; Feng, C.; Zhang, Z.; Zhao, R.; Lei, X.; Chen, R.; Sugiura, N. Electrochim. Acta 2009, 55, 159. doi: 10.1016/j.electacta.2009.08.027
34. [34]
  (34) Zhu, X.; Castleberry, S. R.; Nanny, M. A.; Butler, E. C. Environ. Sci. Technol. 2005, 39, 3784. doi: 10.1021/es0485715
35. [35]
  (35) Lee, J.; Park, H.; Choi,W. Environ. Sci. Technol. 2002, 36, 5462. doi: 10.1021/es025930s
36. [36]
  (36) Velasco, L. F.; Fonseca, I. M.; Parra, J. B.; Lima, J.; Ania, C. O. Carbon 2012, 50, 249. doi: 10.1016/j.carbon.2011.08.042
37. [37]
  (37) Leary, R.;Westwood, A. Carbon 2011, 49, 741. doi: 10.1016/j.carbon.2010.10.010
38. [38]
  (38) Liu, S. Q.; Xiao, B.; Feng, L. R.; Zhou, S. S.; Chen, Z. G.; Liu, C. B.; Chen, F.;Wu, Z. Y.; Xu N.; Oh,W. C.; Meng, Z. D. Carbon 2013, 64, 197. doi: 10.1016/j.carbon.2013.07.052
39. [39]
  (39) Guo, S.; Zhang, G. K.; Guo, Y. D.; Yu, J. C. Carbon 2013, 60, 437. doi: 10.1016/j.carbon.2013.04.058
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