Citation: XIA Da-Hai, YANG Li-Xia. AMechanistic Study on Semiconductivity Conversion of Passive Films under Varying Sulfate to Chloride Concentration Ratios[J]. Acta Physico-Chimica Sinica, ;2014, 30(8): 1465-1473. doi: 10.3866/PKU.WHXB201405211 shu

AMechanistic Study on Semiconductivity Conversion of Passive Films under Varying Sulfate to Chloride Concentration Ratios

XIA Da-Hai ^1,2,3, ,
YANG Li-Xia ^3,4,

1.
1. School of Materials Science and Engineering, Tianjin University, Tianjin 300072, P. R. China;
2. Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, P. R. China;
3. Department of Chemical and Materials Engineering, University of Alberta, Edmonton T6G 2V4, Alberta, Canada;
4. Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, P. R. China

Received Date: 16 April 2014
Available Online: 21 May 2014
Fund Project:

Alloy 800 is an important steamgenerator material used in nuclear power plants, and so there is significant interest in the properties of passive films of this alloy under service conditions. In this work, the semiconductivity of Alloy 800 in sulfate and chloride solutions was investigated using Mott-Schottky analysis, electrochemistry impedance spectroscopy (EIS), scanning electron microscopy (SEM), and scanning electrochemical microscopy (SECM). The Mott-Schottky results show that the semiconductivity is affected by the sulfate to chloride concentration ratio; p-type semiconductivity is exhibited at high concentration ratios but transitions to n-type when the concentration ratio is low. EIS, SEM, and SECM results indicate that the degradation formof the passive filmchanges fromtranspassive dissolution to pitting as the concentration ratio decreases while the film's surface reactivity increases, an effect that is related to the semiconductivity conversion. The observed variation in semiconductivity results fromthe competitive adsorption of sulfate and chloride, a process that modifies the potential drop at the film/solution interface, changes the vacancy types and ultimately determines the semiconductivity.
- Passive film,
- Alloy 800,
- Semiconductivity,
- Sulfate ion,
- Chloride ion
1. [1]
  
  (1) Xia, D. H.; Song, S. Z.; Zhu, R. K.; Behnamian, Y.; Shen, C.; Wang, J. H.; Luo, J. L.; Lu, Y. C.; Klimas, S. Electrochimica Acta 2013, 111, 510. doi: 10.1016/j.electacta.2013.08.030
2. [2]
  (2) Xia, D. H.; Zhu, R. K.; Behnamian, Y.; Shen, C.; Luo, J. L.; Lu, Y. C.; Klimas, S. Journal of the Electrochemical Society 2014, 161, C201.
3. [3]
  (3) Zhu, R. K.; Lu, B. T.; Luo, J. L.; Lu, Y. C. Applied Surface Science 2013, 270, 755. doi: 10.1016/j.apsusc.2013.01.150
4. [4]
  (4) Lu, B. T.; Luo, J. L.; Lu, Y. C. Journal of the Electrochemical Society 2007, 154, C379.
5. [5]
  (5) Lu, B. T.; Luo, J. L.; Lu, Y. C. Electrochimica Acta 2008, 53, 4122. doi: 10.1016/j.electacta.2007.12.070
6. [6]
  (6) Lu, Y. AECL Nuclear Review 2012, 1, 13.
7. [7]
  (7) Luo, B.; Xia, D. H. Acta Physico-Chimica Sinica 2014, 30, 59. [罗兵,夏大海.物理化学学报, 2014, 30, 59.] doi: 10.3866/PKU.WHXB201311221
8. [8]
  (8) Montemor, M. F.; Ferreira, M. G. S.; Walls, M.; Rondot, B.; Belo, M. C. Corrosion 2003, 59, 11. doi: 10.5006/1.3277531
9. [9]
  (9) Huang, J.; Wu, X.; Han, E. H. Corrosion Science 2009, 51, 2976. doi: 10.1016/j.corsci.2009.08.002
10. [10]
  (10) Huang, J.; Wu, X.; Han, E. H. Corrosion Science 2010, 52, 3444. doi: 10.1016/j.corsci.2010.06.016
11. [11]
  (11) Kim, H.; MacDonald, D. D. Corrosion Science 2010, 52, 1139. doi: 10.1016/j.corsci.2009.12.006
12. [12]
  (12) Meng, F.; Han, E. H.; Wang, J.; Zhang, Z.; Ke, W. Electrochimica Acta 2011, 56, 1781 doi: 10.1016/j.electacta.2010.08.028
13. [13]
  (13) Sato, N. Journal of the Electrochemical Society 1982, 129, 255. doi: 10.1149/1.2123808
14. [14]
  (14) Lu, B. T.; Luo, J. L.; Lu, Y. C. Electrochimica Acta 2013, 87, 824. doi: 10.1016/j.electacta.2012.10.006
15. [15]
  (15) Lu, B. T.; Tian, L. P.; Zhu, R. K.; Luo, J. L.; Lu, Y. C. Electrochimica Acta 2011, 56, 1848. doi: 10.1016/j.electacta.2010.09.104
16. [16]
  (16) Yang, M. Z.; Luo, J. L.; Yang, Q.; Qiao, L. J.; Qin, Z. Q.; Norton, P. R. Journal of the Electrochemical Society 1999, 146, 2107. doi: 10.1149/1.1391899
17. [17]
  (17) Li, J.; Xu, Z. Y.; Li, J. Y.; Jiao, D. Acta Physico-Chimica Sinica 2010, 26, 2638. [李进, 许兆义, 李久义,焦迪.物理化学学报, 2010, 26, 2638.] doi: 10.3866/PKU.WHXB20100927
18. [18]
  (18) Yu, J. G.; Luo, J. L. Langmuir 2002, 18, 6637. doi: 10.1021/la025580n
19. [19]
  (19) Maurice, V.; Marcus, P. Electrochimica Acta 2012, 84, 129. doi: 10.1016/j.electacta.2012.03.158
20. [20]
  (20) Massoud, T.; Maurice, V.; Klein, L. H.; Wiame, F.; Marcus, P. Corrosion Science 2013, 69, 245. doi: 10.1016/j.corsci.2012.12.010
21. [21]
  (21) Massoud, T.; Maurice, V.; Klein, L. H.; Marcus, P. Journal of the Electrochemical Society 2013, 160, C232.
22. [22]
  (22) Tian, H. W.; Li, W. H.; Wang, D. P.; Hou, B. R. Acta Physico-Chimica Sinica 2012, 28, 137. [田惠文, 李伟华,王大鹏, 侯保荣.物理化学学报, 2012, 28, 137.] doi: 10.3866/PKU.WHXB201228137
23. [23]
  (23) Xia, D.; Wang, J.; Jiang, Y.; Li, N.; Zhou, C. Journal of Tianjin University (Science and Technology) 2013, 46, 503.
24. [24]
  (24) Staehle, R. W.; rman, J. A. Corrosion 2004, 60, 115. doi: 10.5006/1.3287716
25. [25]
  (25) Xia, D. H.; Song, S. Z.; Wang, J. H.; Bi, H. C. CIESC Journal 2012, 63, 1797.
26. [26]
  (26) Xia, D. H.; Song, S. Z.; Wang, J. H.; Bi, H. C. Transactions of Tianjin University 2012, 18, 15.
27. [27]
  (27) Zheng, X.; Xia, D.; Wang, H.; Fu, C. Anti-Corrosion Methods and Materials 2013, 60, 153. doi: 10.1108/00035591311315382
28. [28]
  (28) Zhang, Y.; Urquidi-MacDonald, M.; Engelhardt, G. R.; MacDonald, D. D. Electrochimica Acta 2012, 69, 1. doi: 10.1016/j.electacta.2012.01.022
29. [29]
  (29) Zhang, Y.; Urquidi-MacDonald, M.; Engelhardt, G. R.; MacDonald, D. D. Electrochimica Acta 2012, 69, 12. doi: 10.1016/j.electacta.2012.01.023
30. [30]
  (30) Zhang, Y.; Urquidi-MacDonald, M.; Engelhardt, G. R.; MacDonald, D. D. Electrochimica Acta 2012, 69, 19. doi: 10.1016/j.electacta.2012.01.024
31. [31]
  (31) Mao, F.; Sharifi-Asl, S.; Yu, J.; MacDonald, D. D. Journal of the Electrochemical Society 2014, 161, C254.
32. [32]
  (32) Shao, H. B.; Wang, J. M.; He, W. C.; Zhang, J. Q.; Cao, C. N. Electrochemistry Communications 2005, 7, 1429. doi: 10.1016/j.elecom.2005.10.002
33. [33]
  (33) Shao, H. B.; Wang, J. M.; Wang, X. Y.; Zhang, J. Q.; Cao, C. N. Electrochemistry Communications 2004, 6, 6. doi: 10.1016/j.elecom.2003.10.007
34. [34]
  (34) Leistner, K.; Toulemonde, C.; Diawara, B.; Seyeux, A.; Marcus, P. Journal of the Electrochemical Society 2013, 160, C197.
35. [35]
  (35) Seyeux, A.; Maurice, V.; Marcus, P. Journal of the Electrochemical Society 2013, 160, C189.
36. [36]
  (36) Zhang, C. S.; Luo, J. L.; Munoz-Paniagua, D.; Norton, P. R. Thin Solid Films 2006, 503, 149. doi: 10.1016/j.tsf.2005.10.083
37. [37]
  (37) Zhu, R. K.; Nowierski, C.; Ding, Z. F.; Noel, J. J.; Shoesmith, D. W. Chemistry of Materials 2007, 19, 2533. doi: 10.1021/cm070023d
38. [38]
  (38) Zhu, R. K.; Qin, Z. Q.; Noel, J. J.; Shoesmith, D. W.; Ding, Z. F. Analytical Chemistry 2008, 80, 1437. doi: 10.1021/ac701796u
39. [39]
  (39) Sharifi-Asl, S.; Taylor, M. L.; Lu, Z.; Engelhardt, G. R.; Kursten, B.; MacDonald, D. D. Electrochimica Acta 2013, 102, 161. doi: 10.1016/j.electacta.2013.03.143
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