Citation: HU Jing-Xiu, ZHANG Jing, ZOU Jian-Feng, XIAO Qiang, ZHONG Yi-Jun, ZHU Wei-Dong. Nitrogen-Rich Microporous Carbon Derived from Melamine-Based Porous Polymer for Selective CO₂ Adsorption[J]. Acta Physico-Chimica Sinica, ;2014, 30(6): 1169-1174. doi: 10.3866/PKU.WHXB201404223 shu

Nitrogen-Rich Microporous Carbon Derived from Melamine-Based Porous Polymer for Selective CO₂ Adsorption

1.
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China

Received Date: 19 February 2014
Available Online: 22 April 2014
Fund Project:

Nitrogen-rich microporous carbon (NMC) was prepared by the carbonization of a melaminebased porous polymer (POP), which was synthesized via a Schiff base condensation using isophthalaldehyde and melamine as starting materials. N₂ adsorption-desorption and Fourier transform infrared (FTIR) spectroscopy were used to characterize the structural properties of POP and the derived NMC. NMC contains less functional groups and has a higher specific surface area and microporous volume compared to POP. NMC has a N content of up to 12.5% (w), as determined by elemental analysis. Single-component adsorption equilibrium isotherms of CO₂, CH₄, and N₂ on NMC were obtained using a volumetric method. NMC has a od CO₂ capture property and its CO₂ adsorption capacity was 2.34 mmol·g^-1 at 298 K and 100 kPa. Dual-site Langmuir (DSL) or single-site Langmuir (SSL) models appropriately describe the adsorption equilibrium behavior of CO₂, CH₄, and N₂ on NMC. Based on the combined fitting parameters, binary adsorption isotherms were predicted by ideal adsorbed solution theory (IAST). Very high adsorption selectivities of CO₂ over N₂ and CH₄ were obtained and the values were 144.9 and 12.8, respectively.
- Microporous carbon,
- CO₂ adsorption,
- Langmuir model,
- IAST,
- Selectivity
1. [1]
  
  (1) Tang, Z. Y.; Sun, Y. H.; Jiang, M. H. Scientia Sinica Chimica 2013, 43 (1), 116. [唐志永, 孙予罕, 江绵恒. 中国科学: 化学, 2013, 43 (1), 116.] doi: 10.1360/032012-402
2. [2]
  (2) Song, C. Catal. Today 2006, 115 (1-4), 2.
3. [3]
  (3) Rochelle, G. T. Science 2009, 325 (5948), 1652. doi: 10.1126/science.1176731
4. [4]
  (4) Bae, J. S.; Bhatia, S. K. Energy Fuels 2006, 20 (6), 2599. doi: 10.1021/ef060318y
5. [5]
  (5) Choi, S.; Drese, J. H.; Jones, C. W. ChemSusChem 2009, 2 (9), 796. doi: 10.1002/cssc.200900036
6. [6]
  (6) Ma, T. Y.; Liu, L.; Yuan, Z. Y. Chem. Soc. Rev. 2013, 42 (9), 3977. doi: 10.1039/c2cs35301f
7. [7]
  (7) Bae, Y. S.; Snurr, R. Q. Angew. Chem. Int. Edit. 2011, 50 (49), 11586. doi: 10.1002/anie.201101891
8. [8]
  (8) Harlick, P. J. E.; Tezel, F. H. Microporous Mesoporous Mat. 2004, 76 (1-3), 71.
9. [9]
  (9) He, Y. F.; Seaton, N. A. Langmuir 2006, 22 (3), 1150. doi: 10.1021/la052237k
10. [10]
  (10) Wang, D.; Ma, X.; Sentorun-Shalaby, C.; Song, C. Ind. Eng. Chem. Res. 2012, 51 (7), 3048. doi: 10.1021/ie2022543
11. [11]
  (11) Zhao, H. L.; Hu, J.; Wang, J. J.; Zhou, L. H.; Liu, H. L. Acta Phys. -Chim. Sin. 2007, 23 (6), 801. [赵会玲, 胡军, 汪建军, 周丽绘, 刘洪来. 物理化学学报, 2007, 23 (6), 801.] doi: 10.1016/S1872-1508(07)60046-1
12. [12]
  (12) Hao, S. Y.; Xiao, Q.; Zhong, Y. J.; Zhu, W. D.; Yang, H. Chin. J. Inorg. Chem. 2010, 26 (1), 982. [郝仕油, 肖强, 钟依均, 朱伟东, 杨辉. 无机化学学报, 2010, 26 (1), 982.]
13. [13]
  (13) Herm, Z. R.; Swisher, J. A.; Smit, B.; Krishna, R.; Long, J. R. J. Am. Chem. Soc. 2011, 133 (15), 5664. doi: 10.1021/ja111411q
14. [14]
  (14) Li, J. R.; KuppleR, R. J.; Zhou, H. C. Chem. Soc. Rev. 2009, 38 (5), 1477. doi: 10.1039/b802426j
15. [15]
  (15) Millward, A. R.; Yaghi, O. M. J. Am. Chem. Soc. 2005, 127 (51), 17998. doi: 10.1021/ja0570032
16. [16]
  (16) Ding, S. Y.; Wang, W. Chem. Soc. Rev. 2013, 42 (2), 548. doi: 10.1039/c2cs35072f
17. [17]
  (17) Xiang, Z.; Cao, D. J. Mater. Chem. A 2013, 1 (8), 2691. doi: 10.1039/c2ta00063f
18. [18]
  (18) Ben, T.; Pei, C.; Zhang, D.; Xu, J.; Deng, F.; Jing, X.; Qiu, S. Energy Environ. Sci. 2011, 4 (10), 3991. doi: 10.1039/c1ee01222c
19. [19]
  (19) Liu, L.; Li, P.; Zhu, L.; Zou, R.; Zhao, Y. Polymer 2013, 54 (2), 596. doi: 10.1016/j.polymer.2012.12.015
20. [20]
  (20) Pei, C.; Ben, T.; Guo, H.; Xu, J.; Deng, F.; Xiang, Z.; Cao, D.; Qiu, S. Phil. Trans. R .Soc. A 2013, 371 No. 2000. doi: 10.1098/rsta.2012.0312
21. [21]
  (21) Vishnyakov, A.; Ravikovitch, P. I.; Neimark, A. V. Langmuir 1999, 15 (25), 8736. doi: 10.1021/la990726c
22. [22]
  (22) Plaza, M. G.; Rubiera, F.; Pis, J. J.; Pevida, C. Appl. Surf. Sci. 2010, 256 (22), 6843. doi: 10.1016/j.apsusc.2010.04.099
23. [23]
  (23) Hao, G. P.; Li, W. C.; Qian, D.; Lu, A. H. Adv. Mater. 2010, 22 (7), 853. doi: 10.1002/adma.200903765
24. [24]
  (24) Hao, G. P.; Li, W. C.; Qian, D.; Wang, G. H.; Zhang, W. P.; Zhang, T.; Wang, A. Q.; Schueth, F.; Bongard, H. J.; Lu, A. H. J. Am. Chem. Soc. 2011, 133 (29), 11378. doi: 10.1021/ja203857g
25. [25]
  (25) Liu, L.; Deng, Q, F.; Hou, X, X.; Yuan, Z. Y. J. Mater. Chem. 2012, 22 (31), 15540. doi: 10.1039/c2jm31441j
26. [26]
  (26) Schwab, M. G.; Fassbender, B.; Spiess, H. W.; Thomas, A.; Feng, X.; Mullen, K. J. Am. Chem. Soc. 2009, 131 (21), 7216. doi: 10.1021/ja902116f
27. [27]
  (27) Lu, W. G.; Sculley, J. P.; Yuan, D. Q.; Krishna, R.; Zhou, H. C. J. Phys. Chem. C 2013, 117 (30), 4057.
28. [28]
  (28) Cao, D. V.; Mohr, R. J.; Rao, M. B.; Sircar, S. J. Phys. Chem. B 2000, 104 (45), 10498.
29. [29]
  (29) Myers, A. L.; Prausnitz, J. M. AIChE. J. 1965, 11 (1), 121. doi: 10.1002/aic.690110125
30. [30]
  (30) Patel, H. A.; Je, S. H.; Park, J.; Chen, D. P.; Jung, Y.; Yavuz, C. T.; Coskun, A. Nat. Commun. 2013, 4, 1357. doi: 10.1038/ncomms2359
1. [1]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-0. doi: 10.1016/j.actphy.2025.100074
2. [2]
  Xianghai Song , Xiaoying Liu , Zhixiang Ren , Xiang Liu , Mei Wang , Yuanfeng Wu , Weiqiang Zhou , Zhi Zhu , Pengwei Huo . Insights into the greatly improved catalytic performance of N-doped BiOBr for CO₂ photoreduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-0. doi: 10.1016/j.actphy.2025.100055
3. [3]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
4. [4]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
5. [5]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
6. [6]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
7. [7]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
8. [8]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
9. [9]
  Zhi Chai , Huashan Huang , Xukai Shi , Yujing Lan , Zhentao Yuan , Hong Yan . Wittig反应的立体选择性. University Chemistry, 2025, 40(8): 192-201. doi: 10.12461/PKU.DXHX202410046
10. [10]
  Wenlong Wang , Wentao Hao , Lang He , Jia Qiao , Ning Li , Chaoqiu Chen , Yong Qin . Bandgap and adsorption engineering of carbon dots/TiO₂ S-scheme heterojunctions for enhanced photocatalytic CO₂ methanation. Acta Physico-Chimica Sinica, 2025, 41(9): 100116-0. doi: 10.1016/j.actphy.2025.100116
11. [11]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
12. [12]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
13. [13]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081
14. [14]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
15. [15]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
16. [16]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . Surface Sulfur Species Influence Hydrogenation Performance of Palladium-Sulfur Nanosheets. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-0. doi: 10.3866/PKU.WHXB202309043
17. [17]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
18. [18]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
19. [19]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
20. [20]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106

Get Citation

PDF

XML

Metrics

PDF Downloads(582)
Abstract views(957)
HTML views(56)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Nitrogen-Rich Microporous Carbon Derived from Melamine-Based Porous Polymer for Selective CO2 Adsorption

Metrics

通讯作者: 陈斌, bchen63@163.com

Nitrogen-Rich Microporous Carbon Derived from Melamine-Based Porous Polymer for Selective CO₂ Adsorption