Citation: YU Zai-Lu, XIE Peng-Fei, TANG Xing-Fu, YUE Ying-Hong, HUA Wei-Ming, GAO Zi. Selective Catalytic Reduction of NO with NH₃ over MnO_x-CeO₂-WO₃-ZrO₂：Effect of Calcination Temperature[J]. Acta Physico-Chimica Sinica, ;2014, 30(6): 1175-1179. doi: 10.3866/PKU.WHXB201404171 shu

Selective Catalytic Reduction of NO with NH₃ over MnO_x-CeO₂-WO₃-ZrO₂：Effect of Calcination Temperature

1.
1 Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China;
2 Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, P. R. China

Received Date: 10 March 2014
Available Online: 17 April 2014
Fund Project:

MnO_x-CeO₂-WO₃-ZrO₂ catalysts were prepared by co-precipitation and calcined at various temperatures (500, 600, 700, and 800 ℃). The effect of calcination temperature on their performance in the selective catalytic reduction (SCR) of NO with ammonia in the presence of O₂ and H₂O was investigated. The structural and physicochemical characterization of the catalysts were performed by N₂ adsorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), NH₃ temperature-programmed desorption (NH₃-TPD), and CO pulse reaction. The results show that the low temperature activity decreased with an increase in the calcination temperature, which is due to a decrease in the amount of surface chemisorbed oxygen and acid sites. As the calcination temperature increased the high temperature activity first increased and then decreased, which is contrary to the variation found for the most readily releasable oxygen on the catalyst surface. The catalyst calcined at 700 ℃ exhibited od low temperature activity and had the widest reaction temperature window. The light-off temperature (50% NO conversion) was 189 ℃ for this catalyst and the NO conversion was 80%-100% between 218 and 431 ℃ at a space velocity of 90000 h^-1.
- Nitrogen oxide,
- Selective catalytic reduction,
- Manganese oxide,
- Cerium oxide,
- WO₃-ZrO₂,
- Co-precipitation method
1. [1]
  
  (1) Liu, Z. M.;Woo, S. I. Catal. Rev. Sci. Eng. 2006, 48, 43. doi: 10.1080/01614940500439891
2. [2]
  (2) Baidya, T.; Bernhard, A.; Elsener, M.; Kröcher, O. Top. Catal. 2013, 56, 23. doi: 10.1007/s11244-013-9923-6
3. [3]
  (3) Zheng, H. H.; Keith, J. M. Catal. Today 2004, 98, 403. doi: 10.1016/j.cattod.2004.08.008
4. [4]
  (4) Chapman, D. M. Appl. Catal. A-Gen. 2011, 392, 143.
5. [5]
  (5) Kapteijn, F.; Sin redjo, L.; Andreini, A.; Moulijn, J. A. Appl. Catal. B-Environ. 1994, 3, 173. doi: 10.1016/0926-3373(93)E0034-9
6. [6]
  (6) Li, J. H.; Chen, J. J.; Ke, R.; Luo, C. K.; Hao, J. M. Catal. Commun. 2007, 8, 1896. doi: 10.1016/j.catcom.2007.03.007
7. [7]
  (7) Lin, T.; Zhang, Q. L.; Li,W.; ng, M. C.; Xing, Y. X.; Chen, Y. Q. Acta Phys. -Chim. Sin. 2008, 24, 1127. [林涛, 张秋林, 李伟, 龚茂初, 幸怡汛, 陈耀强. 物理化学学报, 2008, 24, 1127.] doi: 10.1016/S1872-1508(08)60046-7
8. [8]
  (8) Dai, Y.; Li, J. H.; Peng, Y.; Tang, X. F. Acta Phys. -Chim. Sin. 2012, 28, 1771. [戴韵, 李俊华, 彭悦, 唐幸福. 物理化学学报, 2012, 28, 1771.] doi: 10.3866/PKU.WHXB201204175
9. [9]
  (9) Gu, T. T.; Jin, R. B.; Liu, Y.; Liu, H. F.;Weng, X. L.;Wu, Z. B. Appl. Catal. B-Environ. 2013, 129, 30.
10. [10]
  (10) Qi, G. S.; Yang, R. T. Chem. Commun. 2003, 848.
11. [11]
  (11) Chen, X. R.; Chen, C. L.; Xu, N. P.; Mou, C. Y. Catal. Today 2004, 93-95, 129.
12. [12]
  (12) Lukinskas, P.; Kuba, S.; Grasselli, R. K.; Knözinger, H. Top. Catal. 2007, 46, 87. doi: 10.1007/s11244-007-0318-4
13. [13]
  (13) Si, Z. C.;Weng, D.;Wu, X. D.; Li, J.; Li, G. J. Catal. 2010, 271, 43. doi: 10.1016/j.jcat.2010.01.025
14. [14]
  (14) Due-Hansen, J.; Kustov, A. L.; Rasmussen, S. B.; Fehrmann, R.; Christensen, C. H. Appl. Catal. B-Environ. 2006, 66, 161. doi: 10.1016/j.apcatb.2006.03.006
15. [15]
  (15) Xu, H. D.; Zhang, Q. L.; Qiu, C. T.; Lin, T.; ng, M. C.; Chen, Y. Q. Chem. Eng. Sci. 2012, 76, 120. doi: 10.1016/j.ces.2012.04.012
16. [16]
  (16) Santiesteban, J. G.; Vartuli, J. C.; Han, S.; Bastian, R. D.; Chang, C. D. J. Catal. 1997, 168, 431. doi: 10.1006/jcat.1997.1658
17. [17]
  (17) Si, Z. C.;Weng, D.;Wu, X. D.; Ma, Z. R.; Ma, J.; Ran, R. Catal. Today 2013, 201, 122. doi: 10.1016/j.cattod.2012.05.001
18. [18]
  (18) Zhang, X.; Ji, L. Y.; Zhang, S. C.; Yang,W. S. J. Power Sources 2007, 173, 1017. doi: 10.1016/j.jpowsour.2007.08.083
19. [19]
  (19) Wu, Z. B.; Jin, R. B.; Liu, Y.;Wang, H. Q. Catal. Commun. 2008, 9, 2217. doi: 10.1016/j.catcom.2008.05.001
20. [20]
  (20) Chen, L. S.; Yang, R. T.; Chen, N. J. Catal. 1996, 164, 70. doi: 10.1006/jcat.1996.0364
21. [21]
  (21) Ding, Z. Y.; Li, L. X.;Wade, D.; Gloyna, E. F. Ind. Eng. Chem. Res. 1998, 37, 1707. doi: 10.1021/ie9709345
22. [22]
  (22) Kang, M.; Park, E. D.; Kim, J. M.; Yie, J. E. Appl. Catal. A-Gen. 2007, 327, 261. doi: 10.1016/j.apcata.2007.05.024
23. [23]
  (23) Chang, H. Z.; Li, J. H.; Yuan, J.; Chen, L.; Dai, Y.; Arandiyuan, H.; Xu, J. Y.; Hao, J. M. Catal. Today 2013, 201, 139. doi: 10.1016/j.cattod.2012.03.027
24. [24]
  (24) Guan, B.; Lin, H.; Zhu, L.; Huang, Z. J. Phys. Chem. C 2011, 115, 12850. doi: 10.1021/jp112283g
25. [25]
  (25) Busca, G.; Lietti, L.; Ramis, G.; Berti, F. Appl. Catal. BEnviron. 1998, 18, 1. doi: 10.1016/S0926-3373(98)00040-X
26. [26]
  (26) Carja, G.; Kameshima, Y.; Okada, K.; Madhusoodana, C. D. Appl. Catal. B-Environ. 2007, 73, 60. doi: 10.1016/j.apcatb.2006.06.003
27. [27]
  (27) Choi, E. Y.; Nam, I. S.; Kim, Y. G. J. Catal. 1996, 161, 597. doi: 10.1006/jcat.1996.0222
28. [28]
  (28) Lietti, L.; Nova, I.; Ramis, G.; Dall′Acqua, L.; Busca, G.; Giamello, E.; Forzatti, P.; Bregani, F. J. Catal. 1999, 187, 419. doi: 10.1006/jcat.1999.2603
1. [1]
  Xudong Lv , Tao Shao , Junyan Liu , Meng Ye , Shengwei Liu . Paired Electrochemical CO₂ Reduction and HCHO Oxidation for the Cost-Effective Production of Value-Added Chemicals. Acta Physico-Chimica Sinica, 2024, 40(5): 2305028-0. doi: 10.3866/PKU.WHXB202305028
2. [2]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
3. [3]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
4. [4]
  Junjie TANG , Yunting ZHANG , Zhengjiang LIU , Jiani WU . Preparation of CeO₂ by starch template method for photo-Fenton degradation of methyl orange. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1617-1631. doi: 10.11862/CJIC.20240420
5. [5]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
6. [6]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
7. [7]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
8. [8]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
9. [9]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
10. [10]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 2404023-0. doi: 10.3866/PKU.WHXB202404023
11. [11]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
12. [12]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
13. [13]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005
14. [14]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell. Acta Physico-Chimica Sinica, 2025, 41(1): 100005-0. doi: 10.3866/PKU.WHXB202309037
15. [15]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
16. [16]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
17. [17]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
18. [18]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
19. [19]
  Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378
20. [20]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002

Get Citation

PDF

XML

Metrics

PDF Downloads(528)
Abstract views(684)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Selective Catalytic Reduction of NO with NH3 over MnOx-CeO2-WO3-ZrO2：Effect of Calcination Temperature

Metrics

通讯作者: 陈斌, bchen63@163.com

Selective Catalytic Reduction of NO with NH₃ over MnO_x-CeO₂-WO₃-ZrO₂：Effect of Calcination Temperature