Citation: LIN Xu-Feng, XI Yan-Yan, LIN De-Lian. Controllable Synthesis of Zn_xCd_1-xS Nanowires with Tunable Optical Properties[J]. Acta Physico-Chimica Sinica, ;2014, 30(3): 576-582. doi: 10.3866/PKU.WHXB201312232 shu

Controllable Synthesis of Zn_xCd_1-xS Nanowires with Tunable Optical Properties

LIN Xu-Feng ^1,2 ,
XI Yan-Yan ^1,3, ,
LIN De-Lian ^1,3

1.
1 State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao 266580, Shandong Province, P. R. China;
2 College of Science, China University of Petroleum (East China), Qingdao 266580, Shandong Province, P. R. China;
3 College of Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, Shandong Province, P. R. China

Received Date: 17 October 2013
Available Online: 23 December 2013
Fund Project: 国家自然科学基金(21306230，21003159) (21306230，21003159)山东省自然科学基金(ZR2012BQ020)资助项目 (ZR2012BQ020)

Zn_xCd_1-xS (0< x <1) nanowires with several different compositions were successfully synthesized on Si wafers by a simple vapor deposition method using Au as a catalyst. The morphology and composition of the nanowires were investigated by scanning electron microscopy, transmission electron microscopy, and energy dispersive X-ray spectroscopy. The results show that the Zn/Cd ratio is controllable by adjusting the relative amount of the starting materials and the deposition temperature. The X- ray diffraction patterns show that the nanowires are single crystals with the wurtzite structure. The morphology character of the nanowires suggests that the growth of the nanowires can be explained by the base-growth mechanism. The optical characteristics of the nanowires were studied by Raman and photoluminescence (PL) spectroscopy. Raman shifts of the longitudinal optical (LO) phonon mode were observed in the Zn_xCd_1-xS nanowires. The LO peak frequency changed smoothly with changing composition, which approximately shows a one-mode behavior pattern in the ZnxCd1- xS nanowires. In the PL spectra, both band-gap and defect emission were observed. The PL results indicate that the emission frequency originating from the band-gap transition of the Zn_xCd_1-xS nanowires can be tuned through modulating of the composition. The band-gap of the nanowires can be tuned from 2.41 eV (CdS) to 3.63 eV (ZnS).
- Zinc-cadmium-sulfur,
- Nanowire,
- Vapor deposition,
- Tunable composition,
- Tunable optical property
1. [1]
  
  (1) Huang, M. H.; Mao, S.; Feick, H.; Yan, H. Q.;Wu, Y. Y.; Kind, H.;Weber, E.; Russo, R.; Yang, P. D. Science 2001, 292, 1897. doi: 10.1126/science.1060367
2. [2]
  (2) Bando, K.; Sawabe, T.; Asaka, K.; Masumoto, Y. J. Lumin. 2004, 108, 385. doi: 10.1016/j.jlumin.2004.01.081
3. [3]
  (3) Hu, C.; Zeng, X. H.; Cui, J. Y.; Chen, H. T.; Lu, J. F. J. Phys. Chem. C 2013, 117, 20998. doi: 10.1021/jp407272u
4. [4]
  (4) Duan, X.; Hu, Y.; Agarwal, R.; Lieber, C. M. Nature 2003, 421, 24.
5. [5]
  (5) Kind, Y. H.; Messer, B.; Law, M.; Yang, P. D. Adv. Mater. 2002, 14, 158.
6. [6]
  (6) Brus, L. E. J. Chem. Phys. 1984, 80, 4403. doi: 10.1063/1.447218
7. [7]
  (7) Gudiksen, M. S.; Lieber, C. M. J. Am. Chem. Soc. 2000, 122, 8801. doi: 10.1021/ja002008e
8. [8]
  (8) Gudiksen, M. S.;Wang, J.; Lieber, C. M. J. Phys. Chem. B 2002, 106, 4036. doi: 10.1021/jp014392n
9. [9]
  (9) Ma, D. D. D.; Lee, C. S.; Au, F. C. K.; Tong, S. Y.; Lee, S. T. Science 2003, 299, 1874. doi: 10.1126/science.1080313
10. [10]
  (10) Peng, K. Q.;Wang, X.; Li, L.; Hu, Y.; Lee, S. T. Nano Today 2013, 8, 75. doi: 10.1016/j.nantod.2012.12.009
11. [11]
  (11) Shan, C. X.; Liu, Z.; Ng, C. M.; Hark, S. K. Appl. Phys. Lett. 2005, 87, 033108. doi: 10.1063/1.1997271
12. [12]
  (12) Zhang, X. T.; Liu, Z.; Liu, Q.; Hark, S. K. J. Phys. Chem. B 2005, 109, 17913. doi: 10.1021/jp0527406
13. [13]
  (13) Averin, S. V.; Kuznetsov, P. I.; Zhitov, V. A.; Alkeev, N. V.; Kotov, V. M.; Zakharov, L. Y.; Gladysheva, N. B. Tech. Phys. 2012, 82, 49.
14. [14]
  (14) Hou, J.W.; Song, B.; Zhang, Z. H.;Wang,W. J.;Wu, R.; Sun, Y. F.; Zheng, Y. F.; Ding, P.; Jian, J. K. Acta Physico-Chimica Sinica 2009, 25, 724. [侯军伟, 宋波, 张志华, 王文军, 吴荣, 孙言飞, 郑毓峰, 丁芃, 简基康. 物理化学学报, 2009, 25, 724.] doi: 10.3866/PKU.WHXB20090428
15. [15]
  (15) Liang, Y. Q.; Zhai, L.; Zhao, X. S.; Xu, D. S. J. Phys. Chem. B 2005, 109, 7120. doi: 10.1021/jp045566e
16. [16]
  (16) Liu, Y.; Zapien, J. A.; Shan, Y. Y.; Geng, C. Y.; Lee, C. S.; Lee, S. T. Adv. Mater. 2005, 17, 1372.
17. [17]
  (17) Venu pal, R.; Lin, P. I.; Chen, Y. T. J. Phys. Chem. B 2006, 110, 11691. doi: 10.1021/jp056892c
18. [18]
  (18) Wu, H.; Yao, Y.; Li,W.; Zhu, L.; Ni, N.; Zhang, X. J. Nanopart. Res. 2011, 13, 2225. doi: 10.1007/s11051-010-9981-7
19. [19]
  (19) Mahdi, M. A.; Hassan, J. J.; Hassan, Z.; Ng, S. S. Journal of Alloys and Compounds 2012, 541, 227. doi: 10.1016/j.jallcom.2012.05.123
20. [20]
  (20) Huang, Y.; Duan, X. F.; Lieber, C. M. Small 2005, 1, 142.
21. [21]
  (21) Mcalpine, C. M.; Friedman, R. S.; Lieber, C. M. Proc. IEEE 2005, 93, 1357. doi: 10.1109/JPROC.2005.850308
22. [22]
  (22) Sirbuly, D. J.; Law, M.; Yan, H. Q.; Yang, P. D. J. Phys. Chem. B 2005, 109, 15190. doi: 10.1021/jp051813i
23. [23]
  (23) Law, M.; Greene, L. E.; Johnson, J. C.; Saykally, R.; Yang, P. D. Nat. Mater. 2005, 4, 455. doi: 10.1038/nmat1387
24. [24]
  (24) Bailey, R. E.; Nie, S. J. Am. Chem. Soc. 2003, 125, 7100. doi: 10.1021/ja035000o
25. [25]
  (25) Wei, H.; Ren, X. L.; Han, Z. Y.; Li, T. T.; Su, Y. J.;Wei, L. M.; Cong, F. S.; Zhang, Y. F. Mater. Lett. 2013, 102, 94
26. [26]
  (26) Xi, Y. Y.; Cheung, T. L. Y.; Ng, D. H. L. Mater. Lett. 2008, 62, 128. doi: 10.1016/j.matlet.2007.04.094
27. [27]
  (27) Rincon, M. E.; Martinez, M.W.; Miranda-Hernandez, M. Solar Energy Materials & Solar Cells 2003, 77, 25. doi: 10.1016/S0927-0248(02)00242-8
28. [28]
  (28) Sainova, D. S.; Zen, A.; Nothofer, H. H.; Asawapirom, U.; Scherf, U.; Hagen, R.; Bieringer, T.; Kostromine, S.; Neher, D. Adv. Funct. Mater. 2002, 12, 49. doi: 10.1002/1616-3028(20020101)12:1<49::AID-ADFM49>3.0.CO;2-D
29. [29]
  (29) Ballentyne, D.W. G.; Ray, B. Physica 1961, 27, 337. doi: 10.1016/0031-8914(61)90106-9
30. [30]
  (30) Shimaoka, G.; Suzuki, Y. Appl. Surf. Sci. 1997, 113, 528.
31. [31]
  (31) Kar, S.; Satpati, B.; Satyam, P. V.; Chaudhuri, S. J. Phys. Chem. B 2005, 109, 19134. doi: 10.1021/jp052600w
32. [32]
  (32) Kim, H.W.; Shim, S. H. Chem. Phys. Lett. 2006, 422, 165. doi: 10.1016/j.cplett.2006.02.062
33. [33]
  (33) Duan, X.; Lieber, C. M. Adv. Mater. 2000, 12, 298.
34. [34]
  (34) Wu, Z. H.; Sun, M.; Mei, X. Y.; Ruda, H. E. Appl. Phys. Lett. 2004, 85, 657. doi: 10.1063/1.1775037
35. [35]
  (35) Fan, S. S.; Chapline, M. G.; Franklin, N. R.; Tombler, T.W.; Cassell, A. M.; Dai, H. Science 1999, 283, 512. doi: 10.1126/science.283.5401.512
36. [36]
  (36) Chan, I. F.; Mitra, S. S. Phys. Rev. 1968, 172, 924. doi: 10.1103/PhysRev.172.924
37. [37]
  (37) Lucovsky, G.; Lind, E.; Davis, E. A. Proceedings of the International Conference on the Physics of II-VI Semiconducting Compounds; Benjamin: New York, 1967; p 1150.
38. [38]
  (38) Ichimura, M.; Usami, A.;Wada, T.; Funato, M.; Ichino, K.; Fujita, S.; Fujita, S. Phys. Rev. B 1992, 46, 4273. doi: 10.1103/PhysRevB.46.4273
39. [39]
  (39) Lu, H. Y.; Chu, S. Y.; Chang, C. C. J. Crystal Growth 2005, 280, 173. doi: 10.1016/j.jcrysgro.2005.03.032
40. [40]
  (40) Qu, L. H.; Peng, X. G. J. Am. Chem. Soc. 2002, 124, 2049. doi: 10.1021/ja017002j
41. [41]
  (41) Murray, C. B.; Norris, D. J.; Bawendi, M. G. J. Am. Chem. Soc. 1993, 115, 8706. doi: 10.1021/ja00072a025
42. [42]
  (42) Hill, R. J. J. Phys. C: Solid State Phys. 1974, 7, 521. doi: 10.1088/0022-3719/7/3/009
43. [43]
  (43) Richardson, D.; Hill, R. J. Phys. C: Solid State Phys. 1972, 5, 821. doi: 10.1088/0022-3719/5/8/008
1. [1]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
2. [2]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 2310029-0. doi: 10.3866/PKU.WHXB202310029
3. [3]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
4. [4]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
5. [5]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H₂O₂ synthesis via melamine-foam supported S-scheme Cd_0.5Zn_0.5In₂S₄/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093
6. [6]
  Jianqiao ZHANG , Yang LIU , Yan HE , Yaling ZHOU , Fan YANG , Shihui CHENG , Bin XIA , Zhong WANG , Shijian CHEN . Ni-doped WP₂ nanowire self-standingelectrode: Preparation and alkaline electrocatalytic hydrogen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1610-1616. doi: 10.11862/CJIC.20240444
7. [7]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
8. [8]
  Yingtong FAN , Yujin YAO , Shouhao WAN , Yihang SHEN , Xiang GAO , Cuie ZHAO . Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043
9. [9]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . Surface Sulfur Species Influence Hydrogenation Performance of Palladium-Sulfur Nanosheets. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-0. doi: 10.3866/PKU.WHXB202309043
10. [10]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
11. [11]
  Dongheng WANG , Si LI , Shuangquan ZANG . Construction of chiral alkynyl silver chains and modulation of chiral optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 131-140. doi: 10.11862/CJIC.20240379
12. [12]
  Shu'e Song , Xiaokui Wang , Yongmei Liu , Wanchun Zhu , Hong Yuan , Fuping Tian , Yunshan Bai , Yunchao Li , Li Wang , Zhongyun Wu , Yuan Chun , Jianrong Zhang , Shuyong Zhang . Suggestions on Operating Specifications of Physical Chemistry Experiment: Measurement of Viscosity, Density and Optical Properties. University Chemistry, 2025, 40(5): 148-156. doi: 10.12461/PKU.DXHX202503026
13. [13]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
14. [14]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
15. [15]
  Yan'e LIU , Shengli JIA , Yifan JIANG , Qinghua ZHAO , Yi LI , Xinshu CHANG . MoO₃/cellulose derived carbon aerogel: Fabrication and performance as cathode for lithium-sulfur battery. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1565-1573. doi: 10.11862/CJIC.20250054
16. [16]
  Xue Xiao , Jiachun Li , Xiangtong Meng , Jieshan Qiu . Sulfur-Doped Carbon-Coated Fe_0.95S_1.05 Nanospheres as Anodes for High-Performance Sodium Storage. Acta Physico-Chimica Sinica, 2024, 40(6): 2307006-0. doi: 10.3866/PKU.WHXB202307006
17. [17]
  Qilin YU , Yifei XU , Pengjun ZHANG , Shuwei HAO , Chongqiang ZHU , Chunhui YANG . Effect of regulating K⁺/Na⁺ ratio on the structure and optical properties of double perovskite Cs₂NaBiCl₆: Mn²⁺. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1058-1067. doi: 10.11862/CJIC.20240418
18. [18]
  Ximeng CHI , Jianwei WEI , Yunyun WANG , Wenxin DENG , Jiayi DAI , Xu ZHOU . First-principles study of the electronic structure and optical properties of Au and I doped-inorganic lead-free double perovskite Cs₂NaBiCl₆. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1371-1379. doi: 10.11862/CJIC.20240401
19. [19]
  Xiaohang JIN , Qi LIU , Jianping LANG . Room‑temperature solid‑state synthesis, structure, and third‑order nonlinear optical properties of phosphine‑ligand‑protected silver thiolate clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1505-1512. doi: 10.11862/CJIC.20250125
20. [20]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382

Get Citation

PDF

XML

Metrics

PDF Downloads(543)
Abstract views(730)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Controllable Synthesis of ZnxCd1-xS Nanowires with Tunable Optical Properties

Metrics

通讯作者: 陈斌, bchen63@163.com

Controllable Synthesis of Zn_xCd_1-xS Nanowires with Tunable Optical Properties