Citation: YU Hui-Mei, PAN Xiu-Hong, ZHANG Ming-Hui, LIU Yan, YU Jian-Ding. Thermal and Mechanical Properties of Nd³⁺/Yb³⁺ Co-Doped Titanate Glass with Upconversion Emissions[J]. Acta Physico-Chimica Sinica, ;2014, 30(2): 227-231. doi: 10.3866/PKU.WHXB201312161 shu

Thermal and Mechanical Properties of Nd³⁺/Yb³⁺ Co-Doped Titanate Glass with Upconversion Emissions

1.
1 Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China;
2 Energy Institute, Pennsylvania State University, Pennsylvania 16802, USA

Received Date: 13 September 2013
Available Online: 16 December 2013
Fund Project: 国家自然科学基金(21005083)，中国科学院公派出国留学基金(201198)，中国科学院科研装备研制项目(YZ201142) (21005083)，中国科学院公派出国留学基金(201198)，中国科学院科研装备研制项目(YZ201142)中国科学院上海硅酸盐研究所科技创新项目(Y17ZC1160G)资助 (Y17ZC1160G)

In the present work, Nd³⁺/Yb³⁺ co-doped TiO₂-La₂O₃-ZrO₂ (TLZ) glasses which were previously prepared by the aerodynamic levitation method were characterized by thermal differential analysis (DTA) and micro-hardness tests. The DTA technique was used to study the thermal stability of the characteristic temperatures, the glass transition temperature (T_g), the crystallization onset temperature (T_c), and the crystallization peak temperature (T_p), of the rare earth doped titanate glasses. The thermal kinetic DTA-analysis of the Nd³⁺/Yb³⁺ co-doped TLZ glasses was studied at heating rates of 5, 10, 15, 20 K·min^-1. The activation energy (E_a) and the pre-exponential factor (A) were obtained by the Kissinger and Friedman methods. In addition, the Vickers hardness was higher than 7.50 GPa and fracture toughness was higher than 1.20 MPa· m^1/2 for all the investigated TLZ glasses by the micro- hardness test. Furthermore, the upconversion luminescence property was investigated at 808 nm laser excitation, and three intense upconversion emission bands were observed. The excellent upconversion fluorescence, od thermal stability, and high mechanical strength suggested that this class of materials has potential for practical application in frequency upconversion devices.
- Thermal stability,
- Mechanical property,
- Upconversion emission,
- Titanate glass,
- Levitation method
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Thermal and Mechanical Properties of Nd3+/Yb3+ Co-Doped Titanate Glass with Upconversion Emissions

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通讯作者: 陈斌, bchen63@163.com

Thermal and Mechanical Properties of Nd³⁺/Yb³⁺ Co-Doped Titanate Glass with Upconversion Emissions