Citation: PANG Rui-Zhi, LI Xin, LI Jian-Sheng, LU Zhuang-Yu, HUANG Cheng, SUN Xiu-Yun, WANG Lian-Jun. In situ Preparation and Antifouling Performance of ZrO₂/PVDF Hybrid Membrane[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2592-2598. doi: 10.3866/PKU.WHXB201310291 shu

In situ Preparation and Antifouling Performance of ZrO₂/PVDF Hybrid Membrane

1.
School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China

Received Date: 24 June 2013
Available Online: 29 October 2013
Fund Project: 国家自然科学基金(51278247)资助项目 (51278247)

Polymers used in porous membrane manufacture are highly susceptible to adsorption of organic foulants. In this study, a new method for in situ preparation of a poly(vinylidene fluoride) (PVDF) based hybrid membrane is reported. The strategy in this method is to combine an ion-exchange process with a traditional immersion precipitation process. A hydrous ZrO₂ sol was synthesized by the addition of anion-exchange resin to N,N-dimethylformamide (DMF) containing zirconyl chloride. A homogeneous ZrO₂/PVDF casting solution was then obtained by dissolving PVDF in the ZrO₂ sol. The presence and dispersion states of ZrO₂ nanoparticles in the resultant membrane matrix were determined using X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The results indicate that the ZrO₂ nanoparticles were well dispersed throughout the PVDF matrix, and the size of the formed nanoparticles was about 10-20 nm. The membrane formation mechanism was investigated based on the viscosity, precipitation kinetics, and membrane morphology. The results indicate that the introduction of ZrO₂ nanoparticles accelerates phase inversion of the casting solution. The membrane hydrophilicity was determined using contact angle measurements. The antifouling properties were examined using antifouling experiments. The results confirm that the presence of ZrO₂ nanoparticles improves the membrane hydrophilicity and reduces protein adsorption on the membrane. This method for in situ preparation of ZrO₂/PVDF hybrid membranes by combining an ion-exchange process with a traditional immersion precipitation process is valuable in the fabrication and applications of organic-inorganic hybrid membranes.
- PVDF membrane,
- In situ preparation,
- Ion-exchange,
- ZrO₂ sol,
- Sol-gel process
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

In situ Preparation and Antifouling Performance of ZrO2/PVDF Hybrid Membrane

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通讯作者: 陈斌, bchen63@163.com

In situ Preparation and Antifouling Performance of ZrO₂/PVDF Hybrid Membrane