Citation: ZHAO Xue-Ting, DONG Yong-Chun, CHENG Bo-Wen, KANG Wei-Min. Coordination Kinetics of Fe³⁺ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye[J]. Acta Physico-Chimica Sinica, ;2013, 29(12): 2513-2522. doi: 10.3866/PKU.WHXB201310233 shu

Coordination Kinetics of Fe³⁺ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye

1.
1 Division of Textile Chemistry & Ecology, School of Textiles, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
2 Key Laboratory of Advanced Textile Composites, Ministry of Education, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received Date: 12 August 2013
Available Online: 23 October 2013
Fund Project: 天津市应用基础与前沿技术重点研究计划(11JCZDJC24600, 11ZCKFGX03200) (11JCZDJC24600, 11ZCKFGX03200)国家自然科学基金(2020773093, 51102178)资助项目 (2020773093, 51102178)

Membranes produced from modified polyacrylonitrile (PAN) nanofibers with different diameters were prepared by electrospinning and amidoximation. They were then used as ligands to coordinate with Fe³⁺ for preparing modified PAN nano-fibrous membrane Fe complexes. The coordination kinetics of three modified PAN nano-fibrous membranes with Fe³⁺ were studied, and the effects of temperature and the Fe³⁺ initial concentration on the coordination kinetics were also examined. Finally, the catalytic activities of the three modified PAN nano- fibrous membrane Fe complexes were evaluated as heterogeneous Fenton catalysts in the degradation of an organic dye. The effect of fiber diameter on the catalytic activity of the complexes was investigated. The results indicated that within the observed temperature and concentration ranges, the equilibrium data for the coordination of Fe³⁺ with the modified PAN nano-fibrous membranes correlated with the Langmuir and Freundlich isotherm equations, but the coordination kinetics showed better agreement with the Lagergren second-order equation. Modified PAN nanofibrous membranes with small diameters showed higher Fe- coordinating capacities and reaction rate constants under the same conditions, indicating that they reacted with Fe³⁺ more easily than the others did. Better catalytic activities for dye degradation were found for the three modified PAN nanofibrous membrane Fe complexes in the dark, and these were further improved by light irradiation. The catalytic activities of the complexes were significantly affected by the nanofiber diameter. The complex prepared using a modified PAN nanofibrous membrane with fibers of an appropriate diameter exhibited the best catalytic activity.
- PAN nano-fibrous membrane,
- Fe³⁺,
- Coordination kinetics,
- Photocatalysis,
- Fenton reaction,
- Dye degradation
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通讯作者: 陈斌, bchen63@163.com

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Coordination Kinetics of Fe3+ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye

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通讯作者: 陈斌, bchen63@163.com

Coordination Kinetics of Fe³⁺ with Membranes Based on Modified PAN Nanofibers with Different Diameters, and Catalytic Effect of Their Complexes on Decomposition of Organic Dye