Citation: HU Zheng-Fa, MENG Tao, ZHANG Wei, CUI Yue-Peng, LUO Li, WANG Yin-Hai. Preparation and Luminescence Properties of Dy³⁺-Doped Full-Color Emitting Ca₉La(PO₄)₇ Phosphors[J]. Acta Physico-Chimica Sinica, ;2013, 29(10): 2271-2275. doi: 10.3866/PKU.WHXB201307162 shu

Preparation and Luminescence Properties of Dy³⁺-Doped Full-Color Emitting Ca₉La(PO₄)₇ Phosphors

1.
School of Physics and Optoelectronic Engineering, Guangdong University of Technology, Guangzhou 510006, P. R. China

Received Date: 9 May 2013
Available Online: 16 July 2013
Fund Project: 广东省重大科技专项(2011A080801015) (2011A080801015) 国家自然科学基金(21271048) (21271048)广东省佛山市南海绿色照明专项(A201107)资助 (A201107)

Dy³⁺-doped Ca₉La(PO₄)₇ phosphors were synthesized by a high-temperature solid-state reaction. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to determine the crystal structure and size of the prepared materials. Photoluminescence excitation and emission spectra of the Dy³⁺-doped Ca₉La(PO₄)₇:Dy³⁺ phosphors were measured. The samples exhibited a broad absorption band in the range of 300-460 nmand a series of individual absorption peaks of Dy³⁺. Blue (481 nm) and yellow (573 nm) emissions combined to generate the observable white-light emission of the Dy³⁺-doped Ca₉La(PO₄)₇:Dy³⁺ phosphors with suitable Commission Internationale de L'Eclairage (CIE) chromaticity coordinates around the colorless point (0.313, 0.329) when the phosphors were excited at 350 nm. Concentration quenching was clearly observed as the concentration of Dy³⁺ dopant was increased. The most intense emission corresponded to a optimummolar fraction of doped Dy³⁺ ions of 0.05. The mechanismof concentration quenching was dominated by electric dipole?dipole interactions.
- Ca₉La(PO₄)₇:Dy³⁺,
- Phosphors,
- High temperature solid state reaction,
- Luminescence property,
- concentration quenching
1. [1]
  
  (1) Zheng, T.; Li, P.; Xiao, S. C.; Wang, D.; Lü, J. W.; Meng, Z. W.Acta Phys. -Chim. Sin. 2011, 27, 2095. [郑涛,李攀,肖生春,王丹,吕景文,门志伟. 物理化学学报, 2011, 27, 2095.]doi: 10.3866/PKU.WHXB20110906
2. [2]
  (2) Li, P. L.; Yang, Z. P.; Wang, Z. J.; Xiong, Z. J.; Guo, Q. L. Acta Phys. -Chim. Sin. 2008, 24, 179. [李盼来,杨志平,王志军,熊志军, 郭庆林.物理化学学报, 2008, 24, 179.] doi: 10.3866/PKU.WHXB20080133
3. [3]
  (3) Nakamura, S.; Fasol, G. The Blue Laser Diode; Spring-Verlag:Berlin, 1997; p 1.
4. [4]
  (4) Wang, Z. J.; Yang, Z. P.; Guo, Q. L.; Li, P. L. Acta Phys. -Chim. Sin. 2010, 26, 3317. [王志军, 杨志平,郭庆林, 李盼来.物理化学学报, 2010, 26, 3317.] doi: 10.3866/PKU.WHXB20101226
5. [5]
  (5) Yang, Z. P.; Liu, P. F.; Song, Y. C.; Han, Y.; Zhao, Y. H.; Zhou,D. Z. J. Chin. Rare Earth Soc. 2012, 30 (5), 570. [杨志平, 刘鹏飞, 宋延春,韩月,赵引红, 周东站. 中国稀土学报, 2012,30 (5), 570.]
6. [6]
  (6) Liu, X. H.; Xiong, W. D.; Chen, F. M.; Hu, Z. F.; Zhang, W.Mater. Res. Bull. 2013, 48, 281. doi: 10.1016/j.materresbull.2012.10.050
7. [7]
  (7) Galceran, M.; Pujol, M. C.; Gluchowski, P.; Carvajal, J. J.;Mateos, X.; Aguiló, M.; Díaz, F. Opt. Mater. 2010, 32,1493. doi: 10.1016/j.optmat.2010.06.008
8. [8]
  (8) Zhong, J. P.; Liang, H. B.; Han, B.; Su, Q.; Yao, Y. Chem. Phys. Lett. 2008, 453, 192. doi: 10.1016/j.cplett.2008.01.032
9. [9]
  (9) Amami, J.; Hreniak, D.; Guyot, Y.; Pazik, R.; utaudier, C.;Boulon, G.; Ayadi, M.; Strek, W. J. Lumin. 2006, 119-120, 383.
10. [10]
  (10) Liu, X. H.; Xiong, W. D.; Chen, F. M.; Zhang, W.; Hu, Z. F.Mater. Res. Bull. 2012, 47, 3417. doi: 10.1016/j.materresbull.2012.07.012
11. [11]
  (11) Guo, C.; Yang, H. K.; Jeong, J. H. J. Lumin. 2010, 130,1390. doi: 10.1016/j.jlumin.2010.02.052
12. [12]
  (12) Chen, X. P.; Xiao, F.; Ye, S.; Huang, X. Y.; Dong, G. P.; Zhang,Q. Y. J. Alloy. Compd. 2011, 509, 1355. doi: 10.1016/j.jallcom.2010.10.061
13. [13]
  (13) Rao, B. V.; Jang, K. W.; Lee, H. S.; Yi, S. S.; Jeong, J. H.J. Alloy. Compd. 2010, 496, 251. doi: 10.1016/j.jallcom.2009.12.175
14. [14]
  (14) Bao, A.; Yang, H.; Tao, C. Y. Curr. Appl. Phys. 2009, 9,1252. doi: 10.1016/j.cap.2009.02.008
15. [15]
  (15) Ning, Q. Y.; Wang, B. Q.; Guo, F. F.; Qiao, C. J.; Wang, X. F.J. Funct. Mater. 2012, 43 (9), 1126. [宁青菊,王邦青, 郭芳芳, 乔畅君,王秀峰.功能材料, 2012, 43 (9), 1126.]
16. [16]
  (16) Liu, W. R.; Chiu, Y. C.; Yeh, Y. T.; Jang, S. M.; Chen, T. M.J. Electrochem. Soc. 2009, 156 (7), 165. doi: 10.1149/1.3121531
17. [17]
  (17) Zhou, G. X.; Zhao, W. R.; Song, E. H.; Dou, X. H.; Yi, C. Y.;Zhou, M. K. Spectroscopy and Spectral Analysis 2011, 31 (8),2058. [周国雄, 赵韦人,宋恩海, 豆喜华,易春雨, 周民康.光谱学与光谱分析, 2011, 31 (8), 2058.]
18. [18]
  (18) Yang, W. J.; Chen, T. M. Appl. Phys. Lett. 2006, 88 (10), 1903.
19. [19]
  (19) Huang, C. H.; Luo, L. Y.; Chen, T. M. J. Electrochem. Soc.2011, 158 (11), 341. doi: 10.1149/2.029111jes
20. [20]
  (20) Sun, J. Y.; Zhang, X. Y.; Xiao, Z. G.; Du, H. Y. Mater. Res. Bull.2011, 46, 2179. doi: 10.1016/j.materresbull.2011.07.033
21. [21]
  (21) Shinde, K. N.; Nagpure, I. M.; Dhoble, S. J.; dbole, S. V.;Bhide, M. K. Indian J. Phys. 2009, 83, 503. doi: 10.1007/s12648-009-0010-6
22. [22]
  (22) Fernandes, M.; Bermudez, Z. V.; Saferreira, R. A.; Carlos, L. D.;Silva, M. M.; Smith, M. J. Chem. Matter. 2007, 19, 3892. doi: 10.1021/cm062832n
23. [23]
  (23) Liang, C. H.; Qi, X. D.; Chang, Y. S. J. Electrochem. Soc. 2010,157, 169. doi: 10.1149/1.3336958
24. [24]
  (24) Blass, G. Philips Res. Rep. 1969, 24, 131.
25. [25]
  (25) Dexter, D. L. J. Chem. Phys. 1953, 21 (5), 836. doi: 10.1063/1.1699044
26. [26]
  (26) Dexter, D. L.; Schulman, J. H. J. Chem. Phys. 1954, 22 (6),1063. doi: 10.1063/1.1740265
1. [1]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
2. [2]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
3. [3]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
4. [4]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
5. [5]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
6. [6]
  Yingpeng ZHANG , Xingxing LI , Yunshang YANG , Zhidong TENG . A pyrazole-based turn-off fluorescent probe for visual detection of hydrazine. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1301-1308. doi: 10.11862/CJIC.20250064
7. [7]
  Xuyu WANG , Xinran XIE , Dengke CAO . Photoreaction characteristics and luminescence modulation in phosphine-anthracene-based Au(Ⅰ) and Ir(Ⅲ) complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1513-1522. doi: 10.11862/CJIC.20250113
8. [8]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
9. [9]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
10. [10]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
11. [11]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
12. [12]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
13. [13]
  Zehao Zhang , Zheng Wang , Haibo Li . Preparation of 2D V₂O₃@Pourous Carbon Nanosheets Derived from V₂CF_x MXene for Capacitive Desalination. Acta Physico-Chimica Sinica, 2024, 40(8): 2308020-0. doi: 10.3866/PKU.WHXB202308020
14. [14]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
15. [15]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
16. [16]
  Weicheng Feng , Jingcheng Yu , Yilan Yang , Yige Guo , Geng Zou , Xiaoju Liu , Zhou Chen , Kun Dong , Yuefeng Song , Guoxiong Wang , Xinhe Bao . Regulating the High Entropy Component of Double Perovskite for High-Temperature Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2024, 40(6): 2306013-0. doi: 10.3866/PKU.WHXB202306013
17. [17]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
18. [18]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5−xMn_0.5V_1.5−xZr_x (PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023
19. [19]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
20. [20]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393

Get Citation

PDF

XML

Metrics

PDF Downloads(675)
Abstract views(808)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Luminescence Properties of Dy3+-Doped Full-Color Emitting Ca9La(PO4)7 Phosphors

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Luminescence Properties of Dy³⁺-Doped Full-Color Emitting Ca₉La(PO₄)₇ Phosphors