Citation: WANG Xiang, LI Ren-Gui, XU Qian, HAN Hong-Xian, LI Can. Roles of (001) and (101) Facets of Anatase TiO₂ in Photocatalytic Reactions[J]. Acta Physico-Chimica Sinica, ;2013, 29(07): 1566-1571. doi: 10.3866/PKU.WHXB201304284 shu

Roles of (001) and (101) Facets of Anatase TiO₂ in Photocatalytic Reactions

WANG Xiang ^1,2 ,
LI Ren-Gui ^1,2 ,
XU Qian ¹ ,
HAN Hong-Xian ¹ ,
LI Can ^1,

1.
1 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian 116023, Liaoning Province, P. R. China;
2 Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 3 April 2013
Available Online: 28 April 2013
Fund Project: 国家自然科学基金(21090341, 21061140361)资助项目 (21090341, 21061140361)

Single crystals of anatase TiO₂ with exposed (001) and (101) facets were synthesized by a hydrothermal method. We carried out photocatalytic reduction reactions to deposit noble metals (Au, Ag, and Pt) and photocatalytic oxidation reactions to deposit metal oxides (PbO₂ and MnO_x) on the surface of TiO₂. The deposited anatase TiO₂ samples were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS) to study the roles of the two facets of anatase TiO₂ in photocatalytic reactions. The noble metals were selectively deposited on the exposed (101) facet, while metal oxides were selectively deposited on the exposed (001) facet. This result indicated that photogenerated electrons and holes mainly accumulated on the (101) and (001) facets, and then took part in photocatalytic reduction and oxidation reactions, respectively. These results also suggested that the simultaneous exposure of the two facets could facilitate charge separation. Therefore, it was proposed that the simultaneous exposure of two facets with different functions will be a new strategy to effectively promote photocatalytic reaction.
- TiO₂,
- Anatase,
- Photocatalysis,
- Crystal facet,
- Charge separation
1. [1]
  
  (1) Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
2. [2]
  (2) Liu, G.; Zhao, Y.; Sun, C.; Li, F.; Lu, G. Q.; Cheng, H. M.Angew. Chem. Int. Edit. 2008, 47, 5277.
3. [3]
  (3) Zhang, J.; Xu, Q.; Feng, Z.; Li, M.; Li, C. Angew. Chem. Int. Edit. 2008, 47, 1766.
4. [4]
  (4) Dholam, R.; Patel, N.; Miotello, A. Int. J. Hydrog. Energy 2011,36, 6519. doi: 10.1016/j.ijhydene.2011.03.028
5. [5]
  (5) Liu, F. S.;Wang, S.; Liu, L. L.; Du, H. Renewable and Sustainable Energy II, Pts 1-4; Trans. Tech. Publications Ltd.:Switzerland, 2012; Vol. 512-515, pp 1677-1682.
6. [6]
  (6) Paracchino, A.; Laporte, V.; Sivula, K.; Gratzel, M.; Thimsen, E.Nat. Mater. 2011, 10, 456. doi: 10.1038/nmat3017
7. [7]
  (7) Higashimoto, S.; Ushiroda, Y.; Azuma, M. Top. Catal. 2008, 47,148. doi: 10.1007/s11244-007-9026-3
8. [8]
  (8) Chen, X. B.; Liu, L.; Yu, P. Y.; Mao, S. S. Science 2011, 331,746. doi: 10.1126/science.1200448
9. [9]
  (9) Akurati, K. K.; Vital, A.; Dellemann, J. P.; Michalow, K.;Graule, T.; Fetti, D.; Baiker, A. Appl. Catal. B-Environ. 2008,79, 53. doi: 10.1016/j.apcatb.2007.09.036
10. [10]
  (10) Zhang, X. Y.; Cui, X. L. Acta Phys. -Chim. Sin. 2009, 25, 1829.[张晓艳, 崔晓莉. 物理化学学报, 2009, 25, 1829.] doi: 10.3866/PKU.WHXB20090905
11. [11]
  (11) Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253. doi: 10.1039/b800489g
12. [12]
  (12) Wang, X.; Xu, Q.; Li, M. R.; Shen, S.;Wang, X. L.;Wang, Y.C.; Feng, Z. C.; Shi, J. Y.; Han, H. X.; Li, C. Angew. Chem. Int. Edit. 2012, 51, 13089. doi: 10.1002/anie.v51.52
13. [13]
  (13) Giocondi, J. L.; Rohrer, G. S. J. Am. Ceram. Soc. 2003, 86,1182. doi: 10.1111/jace.2003.86.issue-7
14. [14]
  (14) Yang, H. G.; Sun, C. H.; Qiao, S. Z.; Zou, J.; Liu, G.; Smith, S.C.; Cheng, H. M.; Lu, G. Q. Nature 2008, 453, 638. doi: 10.1038/nature06964
15. [15]
  (15) Liu, G.; Sun, C. H.; Yang, H. G.; Smith, S. C.;Wang, L. Z.; Lu,G. Q.; Cheng, H. M. Chem. Commun. 2010, 46, 755. doi: 10.1039/b919895d
16. [16]
  (16) Pan, J.; Liu, G.; Lu, G. M.; Cheng, H. M. Angew. Chem. Int. Edit. 2011, 50, 2133. doi: 10.1002/anie.v50.9
17. [17]
  (17) Liu, C.; Han, X. G.; Xie, S. F.; Kuang, Q.;Wang, X.; Jin, M. S.;Xie, Z. X.; Zheng, L. S. Chem. -Asian J. 2013, 8, 282. doi: 10.1002/asia.v8.1
18. [18]
  (18) Ohno, T.; Sarukawa, K.; Matsumura, M. New J. Chem. 2002,26, 1167. doi: 10.1039/b202140d
19. [19]
  (19) Taguchi, T.; Saito, Y.; Sarukawa, K.; Ohno, T.; Matsumura, M.New J. Chem. 2003, 27, 1304. doi: 10.1039/b304518h
20. [20]
  (20) Murakami, N.; Kurihara, Y.; Tsubota, T.; Ohno, T. J. Phys. Chem. C 2009, 113, 3062. doi: 10.1021/jp809104t
21. [21]
  (21) Farneth,W. E.; McLean, R. S.; Bolt, J. D.; Dokou, E.; Barteau,M. A. Langmuir 1999, 15, 8569. doi: 10.1021/la9908844
22. [22]
  (22) Farneth,W. E.; Hotsenpiller, P. A. M.; Bolt, J. D.; Lowekamp, J.B.; Rohrer, G. S. Orientation Dependence of PhotochemicalReactions on TiO2 Thin Film Surfaces. In Abstracts of Papers of the American Chemical Society, University ofWashington,USA, Aug 23, 1998; Amercan Chemical Sociality:WashingtonDC, 1998; Vol. 216, U747-U747.
23. [23]
  (23) Li, R.; Zhang, F.;Wang, D.; Yang, J.; Li, M.; Zhu, J.; Zhou, X.;Han, H.; Li, C. Nat. Commun. 2013, 4, 1432. doi: 10.1038/ncomms2401
24. [24]
  (24) Kato, H.; Asakura, K.; Kudo, A. J. Am. Chem. Soc. 2003, 125,3082. doi: 10.1021/ja027751g
25. [25]
  (25) Oku, M.; Hirokawa, K.; Ikeda, S. J. Electron. Spectrosc. 1975,7, 465. doi: 10.1016/0368-2048(75)85010-9
26. [26]
  (26) Dicastro, V.; Polzonetti, G. J. Electron. Spectrosc. 1989, 48,117. doi: 10.1016/0368-2048(89)80009-X
27. [27]
  (27) Foord, J. S.; Jackman, R. B.; Allen, G. C. Philos. Mag. A 1984,49, 657. doi: 10.1080/01418618408233293
28. [28]
  (28) Hengerer, R.; Kavan, L.; Krtil, P.; Grätzel, M. J. Electrochem. Soc. 2000, 147, 1467. doi: 10.1149/1.1393379
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Roles of (001) and (101) Facets of Anatase TiO2 in Photocatalytic Reactions

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通讯作者: 陈斌, bchen63@163.com

Roles of (001) and (101) Facets of Anatase TiO₂ in Photocatalytic Reactions