Citation: WU Hong-Bin, ZHANG Ying, YUAN Cong-Li, WEI Xiao-Pei, YIN Jin-Ling, WANG Gui-Ling, CAO Dian-Xue, ZHANG Yi-Ming, YANG Bao-Feng, SHE Pei-liang. Synthesis and Electrochemical Performance of Li₄Ti₅O₁₂/CMK-3 Nanocomposite Negative Electrode Materials for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2013, 29(06): 1247-1252. doi: 10.3866/PKU.WHXB201303211 shu

Synthesis and Electrochemical Performance of Li₄Ti₅O₁₂/CMK-3 Nanocomposite Negative Electrode Materials for Lithium-Ion Batteries

1.
1 Key Laboratory of Superlight Material and Surface Technology of Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, P. R. China;
2 Shuangdeng Institute of Science and Techonology, Nanjing, 211000, P. R. China

Received Date: 8 January 2013
Available Online: 21 March 2013
Fund Project: 哈尔滨优秀学术带头人科技创新基金(2012RFXXG103) (2012RFXXG103) 中央高校基础研究基金(HEUCFT1205) (HEUCFT1205)江苏省科技支撑计划(BE2012152)资助 (BE2012152)

The composite of ordered mesoporous carbon (CMK-3) and Li₄Ti₅O₁₂ (Li₄Ti₅O₁₂/CMK-3) was prepared by the wet impregnation of CMK-3 with LiNO₃ and Ti(OC₄H₉)₄ solution followed by calcination. Its morphology and structure were examined using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The content of Li₄Ti₅O₁₂ in the mesoporous nanocomposite was determined by thermogravimetric analysis. Its electrochemical performance as the negative electrode material of lithium-ion batteries was investigated by galvanostatic charge-discharge tests, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The results show that Li₄Ti₅O₁₂ is formed inside the mesopore channels of CMK-3 and some particles are located on the surface of CMK-3. The composite shows significantly greater high-rate performance than commercial Li₄Ti₅O₁₂. The specific capacity of Li₄Ti₅O₁₂ in the composite is higher than Li₄Ti₅O₁₂ without CMK-3 (117.8 mAh·g^-1 at 1C rate), and its stabilized specific capacity reached 160, 143, and 131 mAh·g^-1 at 0.5C, 1C, and 5C charge-discharge rates, respectively, with a columbic efficiency of nearly 100%. The capacity loss after 100 cycles at 5C rate was less than 0.62%. This result clearly indicates that CMK-3 improves the high rate performance of Li₄Ti₅O₁₂, likely by reducing the particle size of Li₄Ti₅O₁₂ and increasing its electronic conductivity owing to the unique structure and od electronic conduction nature of CMK-3.
- Ordered mesoporous carbon,
- Lithium titanate oxide,
- Composite,
- Lithium-ion battery,
- Negative electrode material
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通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Performance of Li₄Ti₅O₁₂/CMK-3 Nanocomposite Negative Electrode Materials for Lithium-Ion Batteries