Citation: ZHU Yan-Yan, LIU Yan-Fang, LÜ Yan-Hui, WANG Hua, LING Qiang, ZHU Yong-Fa. Reflux Preparation and Photocatalytic Performance of Bismuth Phosphate Nanorods[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 576-584. doi: 10.3866/PKU.WHXB201301043 shu

Reflux Preparation and Photocatalytic Performance of Bismuth Phosphate Nanorods

1.
1 Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China;
2 Institute of Aeronautical Meteorology and Chemical Defence, Equipment Academy of Air Force, Beijing 100085, P. R. China

Received Date: 24 October 2012
Available Online: 4 January 2013
Fund Project: 国家自然科学基金(20925725, 50972070) (20925725, 50972070)

BiPO₄ nanorods were synthesized by reflux, and the effect of reaction time, reactant ratio and concentration, and pH value on BiPO₄ crystal structure and morphology was investigated. Nanorods were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), specific surface area analysis (BET), and UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS). The ability of BiPO₄ to photo-degrade methylene blue (MB) was investigated. The reaction time and reactant concentration influenced the product morphology. The reactant ratio and pH value had a large effect on the product crystal structure and morphology, and also on the photo-activity of BiPO₄. Highly UV active BiPO₄ nanorods of monoclinic monazite/hexa nal mixed crystal structure suitable for photocatalysis could be prepared by carefully controlling the above conditions.
- Refluxing method,
- Controllable synthesis,
- Bismuth phosphate,
- Mixed crystal structure,
- Photocatalysis
1. [1]
  
  (1) Vincenzo, B.; Alberto, C.; Margherita, V. ChemSusChem 2008,1 (1-2), 26.
2. [2]
  (2) Chen, X. B.; Shen, S. H.; Guo, L. J.; Mao, S. S. Chem. Rev.2010, 110 (11), 6503. doi: 10.1021/cr1001645
3. [3]
  (3) Matsumoto, Y. J.; Koinuma, H.; Ohsawa, T. J. Phys. Chem. C2007, 111 (28), 10523. doi: 10.1021/jp072365c
4. [4]
  (4) Nathaniel, L. H.; Jaewook, B. Chem. Mater. 2007, 19, 1883.doi: 10.1021/cm062934d
5. [5]
  (5) Yu, K.; Yang, S. G.; Liu, C.; Chen, H. Z.; Li, H.; Sun, C.;Stephen, A. B. Environ. Sci. Technol. 2012, 46 (13), 7318. doi: 10.1021/es3001954
6. [6]
  (6) Zhang, Q.; Li, X. J.; Li, F. B.; Chang, J. Acta Phys. -Chim. Sin.2004, 20 (5), 507. [张琦, 李新军, 李芳柏, 常杰. 物理化学学报, 2004, 20 (5), 507.] doi: 10.3866/PKU.WHXB20040513
7. [7]
  (7) Xing, J. C.; Bian, J. J.; Yang, J. H.; Huang, F. Q. Journal ofInorganic Materials 2007, 22 (5), 927. [邢精成, 卞建江, 杨建华, 黄富强. 无机材料学报, 2007, 22 (5), 927.]
8. [8]
  (8) Zou, Z. G.; Ye, J. H.; Kazuhiro, S.; Hironori, A. Nature 2001,414, 625. doi: 10.1038/414625a
9. [9]
  (9) Shi, R.;Wang, Y. J.; Li, D.; Xu, J.; Zhu, Y. F. Applied CatalysisB: Environmental 2010, 100, 173.
10. [10]
  (10) Li, D.; Shi, R.; Pan, C. S.; Zhu, Y. F.; Zhao, H. J.CrystEngComm 2011, 13, 4695.
11. [11]
  (11) Zhang, S. C.; Zhang, C.; Man, Y.; Zhu, Y. F. Journal of SolidState Chemistry 2006, 179 (1), 62. doi: 10.1016/j.jssc.2005.09.041
12. [12]
  (12) Fu, X. Z.;Walter, A. Z.; Yang, Q.; Marc, A. A. Joural ofCatalysis 1997, 168 (2), 482. doi: 10.1006/jcat.1997.1660
13. [13]
  (13) Su,W. Y.; Fu, X. Z.;Wei, K. M. Acta Phys. -Chim. Sin. 2001, 17 (1), 28. [苏文悦, 付贤智, 魏可镁. 物理化学学报, 2001, 17 (1), 28.] doi: 10.3866/PKU.WHXB20010106
14. [14]
  (14) La´szlo´, K.; Szilvia, P.; Imre, B.; Imre, D. Chem. Mater. 2007,19 (19), 4811.
15. [15]
  (15) Bi, Y. P.; Ouyang, S. X.; Naoto, U.; Cao, J. Y.; Ye, J. H. J. Am.Chem. Soc. 2011, 133 (17), 6490.
16. [16]
  (16) Ji, F.; Li, C. L.; Zhang, J. H. ACS Appl. Mater. Interfaces 2010,2 (6), 1674. doi: 10.1021/am100189m
17. [17]
  (17) Kudo, A.; Omori, K.; Kato, H. J. Am. Chem. Soc. 1999, 121,11459. doi: 10.1021/ja992541y
18. [18]
  (18) Lin, X. P.; Huang, T.; Huang, F. Q.;Wang,W. D.; Shi, J. L. J.Phys. Chem. B 2006, 110 (48), 24629.
19. [19]
  (19) Lin, X.; Lu, P.; Guan, Q. F.; Li, H. B.; Li, H. J.; Cai, J.; Zou, Y.Acta Phys. -Chim. Sin. 2012, 28 (8), 1978. [林雪, 吕鹏,关庆丰, 李海波, 李洪吉, 蔡杰, 邹阳. 物理化学学报,2012, 28 (8), 1978.] doi: 10.3866/PKU.WHXB201205172
20. [20]
  (20) Dunkle, S. S.; Suslick, K. S. J. Phys. Chem. C 2009, 113 (24),10341. doi: 10.1021/jp903163u
21. [21]
  (21) Fu, H. B.; Pan, C. S.; Zhang, L.W.; Zhu, Y. F. MaterialsResearch Bulletin 2007, 42 (4), 696. doi: 10.1016/j.materresbull.2006.07.017
22. [22]
  (22) Zhao, X.; Xu, T.; Yao,W.; Zhu, Y. F. Applied Surface Science2009, 255, 8036. doi: 10.1016/j.apsusc.2009.05.010
23. [23]
  (23) Shi, R.; Lin, J.;Wang, Y. J.; Xu, J.; Zhu, Y. F. J. Phys. Chem. C2010, 114, 6472.
24. [24]
  (24) Pan, C. S.; Zhu, Y. F. Environ. Sci. Technol. 2010, 44, 5570. doi: 10.1021/es101223n
25. [25]
  (25) Pan, C. S.; Zhu, Y. F. J. Mater. Chem. 2011, 21, 4235. doi: 10.1039/c0jm03655b
26. [26]
  (26) Liu, Y. F.; Ma, X. G.; Yi, X.; Zhu, Y. F. Acta Phys. -Chim. Sin.2012, 28 (3), 654. [刘艳芳,马新国, 易欣, 朱永法. 物理化学学报, 2012, 28 (3), 654.] doi: 10.3866/PKU.WHXB201112232
27. [27]
  (27) Lumetta, G. J.; Mcnamara, B. K.; Buck, E. C.; Fiskum, A. K.;Snow, L. A. Environ. Sci. Technol. 2009, 43 (20), 7843. doi: 10.1021/es9013745
28. [28]
  (28) Pan, C. S.; Xu, J.; Chen, Y.; Zhu, Y. F. Applied Catalysis B:Environmental 2012, 115-116, 314.
29. [29]
  (29) Pan, C. S.; Xu, J.;Wang, Y. J.; Li, D.; Zhu, Y. F. Adv. Funct.Mater. 2012, 22, 1518. doi: 10.1002/adfm.v22.7
30. [30]
  (30) Rose, C. L.; Mooney, S. Zeitschrift für Kristallographie, Bd.1962, 117, 371. doi: 10.1524/zkri.1962.117.5-6.371
31. [31]
  (31) Baltasar, R.; Sebastian, B.; Miguel, A. G. A.; Juan, E. I. Inorg.Chem. 1994, 33, 1869. doi: 10.1021/ic00087a023
32. [32]
  (32) Li, G. F.; Ding, Y.; Zhang, Y. F.; Lu, Z.; Sun, H. Z.; Chen, R.Journal of Colloid and Interface Science 2011, 363, 497. doi: 10.1016/j.jcis.2011.07.090
33. [33]
  (33) Geng, J.; Hou,W. H.; Lv, Y. N.; Zhu, J. J.; Chen, H. Y. Inorg.Chem. 2005, 44, 8503. doi: 10.1021/ic050674g
34. [34]
  (34) Pan, C. S.; Li, D.; Ma, X. G.; Chen, Y.; Zhu, Y. F. Catal. Sci.Technol. 2011, 1, 1399. doi: 10.1039/c1cy00261a
35. [35]
  (35) Zhang, D. B.;Wang, S. J.; Cheng, K.; Dai, S. X.; Hu, B. B.;Han, X.; Shi, Q.; Du, Z. L. ACS Appl. Mater. Interfaces 2012, 4,2969. doi: 10.1021/am3003473
36. [36]
  (36) Tsutomu, S.; Seiji,W.; Masanobu, I. Cryst. Growth Des. 2011,11, 5533. doi: 10.1021/cg2011106
37. [37]
  (37) Raj, K. J. A.; Viswanathan, B. India Journal of Chemistry 2009,48, 1378.
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