Citation: HU Sheng-Zhi, XIE Zhao-Xiong, PALENIK G. J.. Bond Valence Parameters for Sn(II)―X and Sn(IV)―X (X=O, S, N, C, P, As, Se, Te, F, Cl, Br, I)[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 19-24. doi: 10.3866/PKU.WHXB20122819 shu

Bond Valence Parameters for Sn(II)―X and Sn(IV)―X (X=O, S, N, C, P, As, Se, Te, F, Cl, Br, I)

1.
1. Department of Chemistry, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2. State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
3. Chemistry Department, The University of Floride, P. O. Box 117200, Gainesville, FL 32611-7200, USA

Received Date: 13 September 2011
Available Online: 9 November 2011

The bond valence parameters (R₀) for homoleptic Sn(II)―X and Sn(IV)―X complexes, where X=O, S, N, C, P, As, Se, Te, F, Cl, Br, and I, were determined using data retrieved from the Cambridge Structural Database with bond valence parameter B=0.037 nm. Some are the first reported experimental values for Sn(II)―X or Sn(IV)―X bonds. In the case of Sn(II)―O, R₀=0.1956 nm with B=0.037 nm can be used to assign the oxidation state of the central Sn(II) ion for almost all coordination numbers. In contrast, the reported parameter set of R₀=0.1859 nm with B=0.055 nm appears applicable mainly to complexes with a low coordination number. Our results suggest that further studies of bond valence parameters are required to better understand the factors that are important in bond valence sum (BVS) calculations.
- Tin compound,
- Bond valence parameter,
- Oxidation state,
- Secondary bond
1. [1]
  (1) Brown, I. D. The Chemical Bond in Inorganic Chemistry: The Valence Model. Oxford University Press: Oxford, 2002.
2. [2]
  (2) Brown, I. D. Chem. Rev. 2009, 109, 6858.
3. [3]
  (3) Palenik, G. J.; Hu, S. Z. Inorg. Chim. Acta 2009, 362, 4740.
4. [4]
  (4) Spek, A. L. Acta Crystallogr. D 2009, 65, 148.
5. [5]
  (5) Brown. I. D. 2011 http://www.iucr.org/resources/data/datasets/ bond-valence-parameters
6. [6]
  (6) Brese, N. E.; O'Keeffe, M. Acta Cryst. B 1991, 47, 192.
7. [7]
  (7) Sidey, V. Acta Crystallogr. B 2009, 56, 99.
8. [8]
  (8) Jensen,W. P.; Palenik, G. J.; Tiekink, E. R. T. Polyhedron 2001, 20, 2137.
9. [9]
  (9) Brown, I. D. Acta Crystallogr. B 2009, 56, 684.
10. [10]
  (10) Brown, I. D.; Altermatt, D. Acta Crystallogr. B 1985, 41, 244.
11. [11]
  (11) Chen, M. D.; Hu, S. Z. Acta Phys. -Chim. Sin. 2002, 18, 1104. [陈明旦, 胡盛志. 物理化学学报, 2002, 18, 1104.]
12. [12]
  (12) Ng, S.W.; Hu, S. Z. Acta Phys. -Chim. Sin. 2001, 17, 1040. [Ng, S.W., 胡盛志. 物理化学学报, 2001, 17, 1040.]
13. [13]
  (13) HU, S. Z.; Chen, M. D.; Robertson, B. E. Acta Phys.- Chim. Sin. 2005, 21, 646. [胡盛志, 陈明旦, Robertson, B. E. 物理化学学报, 2005, 21, 646.]
14. [14]
  (14) HU, S. Z.; Xie, Z. X.; Zhou, Z. H. Acta Phys. -Chim. Sin. 2010, 26, 1795. [胡盛志, 谢兆雄, 周朝晖. 物理化学学报, 2010, 26, 1795.]
15. [15]
  (15) von Trömel, M. Acta Crystallogr . B 1986, 42, 138.
16. [16]
  (16) Dai, J. C.;Wu, L. M.; Cui, C. P.; Fu, Z. Y.; Hu, S. M.; Du,W. X.; Zhang,W. J.;Wu, X. T. Inorg. Chem. Commun. 2001, 4, 643.
17. [17]
  (17) Brown, I. D. J. Appl. Cryst. 1996, 29, 479.
18. [18]
  (18) Sowa, H.; Druck, U.; Kutoglu, A. Z. Krist. 1981, 154, 333.
19. [19]
  (19) Dai, J. C. Private communication.
20. [20]
  (20) Kiselev, Y. M. Russ. J. Inorg. Chem. 1998, 43, 1875.
21. [21]
  (21) Shields, G. P.; Raithby, P. R.; Allen, F. H.; Motherwell,W. D. S. Acta Crystallogr . B 2000, 56, 455.
22. [22]
  (22) HU, S. Z. Acta Phys.-Chim. Sin. 2007, 23, 786. [胡盛志. 物理化学学报, 2007, 23, 786.]
23. [23]
  (23) HU, S. Z. unpublished results.
24. [24]
  (24) Palenik, G. J.; Hu, S. Z. Chin. J. Struct. Chem. accepted.
1. [1]
  Rui Li , Jiayu Zhang , Anyang Li . Two Levels of Understanding of Chemical Bonds: a Case of the Bonding Model of Hypervalent Molecules. University Chemistry, 2024, 39(2): 392-398. doi: 10.3866/PKU.DXHX202308051
2. [2]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
3. [3]
  Wenke ZHENG , Ce LIU , Wei CHEN , Hongshan KE , Fanlong ZENG , Yibo LEI , Anyang LI , Wenyuan WANG . Synthesis and bonding analysis of low-coordinate Fe and Cr complexes with ultra-bulky silylamino groups. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1285-1293. doi: 10.11862/CJIC.20250095
4. [4]
  Lili Jiang , Shaoyu Zheng , Xuejiao Liu , Xiaomin Xie . Copper-Catalyzed Oxidative Coupling Reactions for the Synthesis of Aryl Sulfones: A Fundamental and Exploratory Experiment for Undergraduate Teaching. University Chemistry, 2025, 40(7): 267-276. doi: 10.12461/PKU.DXHX202408004
5. [5]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
6. [6]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
7. [7]
  Linhan Tian , Changsheng Lu . Discussion on Sextuple Bonding in Diatomic Motifs of Chromium Family Elements. University Chemistry, 2024, 39(8): 395-402. doi: 10.3866/PKU.DXHX202401056
8. [8]
  Pengzi Wang , Wenjing Xiao , Jiarong Chen . Copper-Catalyzed C―O Bond Formation by Kharasch-Sosnovsky-Type Reaction. University Chemistry, 2025, 40(4): 239-244. doi: 10.12461/PKU.DXHX202406090
9. [9]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
10. [10]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
11. [11]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
12. [12]
  Lu Zhuoran , Li Shengkai , Lu Yuxuan , Wang Shuangyin , Zou Yuqin . Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2306003-0. doi: 10.3866/PKU.WHXB202306003
13. [13]
  Haiping Wang . A Streamlined Method for Drawing Lewis Structures Using the Valence State of Outer Atoms. University Chemistry, 2024, 39(8): 383-388. doi: 10.12461/PKU.DXHX202401073
14. [14]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
15. [15]
  Ying Xiong , Guangao Yu , Lin Wu , Qingwen Liu , Houjin Li , Shuanglian Cai , Zhanxiang Liu , Xingwen Sun , Yuan Zheng , Jie Han , Xin Du , Chengshan Yuan , Qihan Zhang , Jianrong Zhang , Shuyong Zhang . Basic Operations and Specification Suggestions for Determination of Physical Constants of Organic Compounds. University Chemistry, 2025, 40(5): 106-121. doi: 10.12461/PKU.DXHX202503079
16. [16]
  Yongjian Zhang , Fangling Gao , Hong Yan , Keyin Ye . Electrochemical Transformation of Organosulfur Compounds. University Chemistry, 2025, 40(5): 311-317. doi: 10.12461/PKU.DXHX202407035
17. [17]
  Nan Xiao , Fang Sun . 二芳基硫醚化合物的构建及应用. University Chemistry, 2025, 40(6): 360-363. doi: 10.12461/PKU.DXHX202407099
18. [18]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021
19. [19]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
20. [20]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093

Get Citation

PDF

XML

Metrics

PDF Downloads(936)
Abstract views(2468)
HTML views(92)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142