Citation: LI Feng-Li, GUO Li, XIAN Hui, MENG Ming, LI Zhi-Jun, BAO Jun, LI Xin-Gang. NO_x Storage Performance of Alkaline Earth-Doped Perovskite-Type BaFeO₃ Catalysts[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 605-611. doi: 10.3866/PKU.WHXB201212241 shu

NO_x Storage Performance of Alkaline Earth-Doped Perovskite-Type BaFeO₃ Catalysts

LI Feng-Li ¹ ,
GUO Li ¹ ,
XIAN Hui ¹ ,
MENG Ming ¹ ,
LI Zhi-Jun ² ,
BAO Jun ³ ,
LI Xin-Gang ^1,

1.
1 Tianjin Key Laboratory of Applied Catalysis Science & Technology, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, P. R. China;
2 State Key Laboratory of Engines, Tianjin University, Tianjin 300072, P. R. China;
3 National Synchrotron Radiation Laboratory, University of Science & Technology of China, Hefei 230029, P. R. China

Received Date: 25 October 2012
Available Online: 24 December 2012
Fund Project: 国家自然科学基金(U1162103, U1232118) (U1162103, U1232118) 国家高技术研究发展计划(863) (2008AA06Z323) (863) (2008AA06Z323) 天津市自然科学基金(11JCYBJC03700) (11JCYBJC03700) 教育部新世纪优秀人才支持计划(NCET-10-0615) (NCET-10-0615) 教育部留学归国人员科研启动基金(2011-1568) (2011-1568)天津大学内燃机燃烧学国家重点实验室开放基金(K2012-05)资助项目 (K2012-05)

A series of Ba_1-xM_xFeO₃ (M=Mg, Ca, Sr; x=0, 0.1, 0.2) perovskites were prepared by the sol-gel method as NO_x storage reduction (NSR) catalysts. The effect of doping with alkaline earth metals (Mg, Ca, and Sr) on the NO_x storage and oxidation performance of the BaFeO₃ perovskites was investigated. Doping with Mg enhanced the NO_x storage capacity (NSC) of the BaFeO₃ perovskites in the temperature range 250-400 ℃, the Ba_0.8Mg_0.2FeO₃ perovskite exhibited the best NO_x storage performance, which reached its maximum at 350 ℃, with NSC>1200 μmol·g^-1 and the NO→NO₂ conversion of 53.4%. Compared with BaFeO₃, the monodentate nitrate appeared clearly for the Ba_0.8Mg_0.2FeO₃ sample after storing NO_x at 250 ℃. The amount of the monodentate nitrate on Ba_0.8Mg_0.2FeO₃ varied with the NO_x storage temperature in a similar manner to that of its NSC. Fourier transform infrared (FTIR) spectra indicated that doping with Mg induced an A-site deficient perovskite structure in BaFeO₃, which readily generates oxygen vacancies that act as the active sites for NO_x adsorption. Moreover, the residual M on the catalyst might also improve the NSC of the sample by forming the monodentate nitrate.
- Perovskite,
- Alkaline-earth metal doping,
- NO_x storage,
- NO oxidation,
- Lean-burn
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沈阳化工大学材料科学与工程学院沈阳 110142

NOx Storage Performance of Alkaline Earth-Doped Perovskite-Type BaFeO3 Catalysts

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NO_x Storage Performance of Alkaline Earth-Doped Perovskite-Type BaFeO₃ Catalysts