Citation: KONG Xiang-Lei. Size Effect on the Signal Intensity Difference between Odd- and Even-Numbered Phosphorus Cluster Ions[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 486-490. doi: 10.3866/PKU.WHXB201212121 shu

Size Effect on the Signal Intensity Difference between Odd- and Even-Numbered Phosphorus Cluster Ions

KONG Xiang-Lei

1.
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, P. R. China

Received Date: 16 August 2012
Available Online: 12 December 2012
Fund Project: 国家自然科学基金(21172121, 21121002) (21172121, 21121002)

Intensity difference between odd- and even-numbered cluster ions is one of the characteristics of phosphorus clusters. Generally, for the clusters with cluster ion size n>25, intensities of odd-numbered cluster ions are much higher than those of their even-numbered neighbors. In order to better understand the size effect on the phenomenon, large phosphorus clusters (n~500) were generated by laser ablation on red phosphorus in vacuum. Their intensity distributions were also analyzed. Results show that the intensity difference between odd- and even-numbered cluster ions decreases with increasing cluster size for both cations and anions. Based on the observed trends for cations and anions, it can be estimated that the observed intensity alternation of even/odd numbered clusters may vanish for cluster ions with n>1000. These results exactly reflect the function of cluster as a bridge linking atoms in the gas phase and their bulk counterpart in the bulk phase.
- Phosphorus cluster,
- Laser ablation,
- Size effect,
- Mass spectrometry
1. [1]
  
  (1) (a) Castleman, A.W., Jr.; Jena, P. Proc. Natl. Acad. Sci. U. S. A.2006, 103, 10552. doi: 10.1073/pnas.0601783103
2. [2]
  (b) Castleman, A.W., Jr.; Jena, P. Proc. Natl. Acad. Sci. U. S. A.2006, 103, 10554.
3. [3]
  (c) Jena, P.; Castleman, A.W., Jr. Proc. Natl. Acad. Sci. U. S. A.2006, 103, 10560.
4. [4]
  (d) Cheng, P. Y.; Baskin, J. S.; Zewail, A. H. Proc. Natl. Acad.Sci. U. S. A. 2006, 103, 10570.
5. [5]
  (2) (a) Kroto, H.W.; Heath, J. R.; O'Brien, S. C.; Curl, R. F.;Smalley, R. E. Nature 1985, 318, 162.
6. [6]
  (b) Li, J.; Li, X.; Zhai, H. J.;Wang, L. S. Science 2003, 299,864.
7. [7]
  (3) (a) Kong, X.; Li, S.; Zhang, S.; Huang, Y.; Chen. Y. J. Am. Soc.Mass Spectrom. 2011, 22, 2033. doi: 10.1007/s13361-011-0221-x
8. [8]
  (b) Kong, X.; Huang, Y.; Chen, Y. J. Mass Spectrom. 2012, 47,523.
9. [9]
  (4) (a) Ruck, M.; Hoppe, D.;Wahl, B.; Simon, P.;Wang, Y.; Seifert,G. Angew. Chem. Int. Edit. 2005, 44, 7616.
10. [10]
  (b) Pfitzner, A. Angew. Chem. Int. Edit. 2006, 45, 699.
11. [11]
  (c)Winchester, R. A. L.; Whitby, M.; Shaffer, M. S. P. Angew.Chem. 2009, 121, 3670.
12. [12]
  (d) Russell, C. A. Angew. Chem. Int. Edit. 2009, 48, 4895.
13. [13]
  (5) Martin, T. P. Z. Phys. D 1986, 3, 211. doi: 10.1007/BF01384809
14. [14]
  (6) (a) Huang, R. B.; Zhang, P.; Li,W. Y.; Su, J. R.; Zheng, L. S.Acta Phys. -Chim. Sin. 1991, 7, 646. [黄荣彬, 张鹏, 李文莹, 苏剑瑞, 郑兰荪. 物理化学学报, 1991, 7, 646.] doi: 10.3866/PKU.WHXB19910602
15. [15]
  (b) Huang, R.; Li, H.; Lin, Z.; Yang, S. J. Phys. Chem. 1995,99, 1418.
16. [16]
  (c) Liu, Z.; Huang, R.; Zheng, L. Z. Phys. D 1996, 68, 171.
17. [17]
  (7) (a) Bulgakov, A. V.; Bobrenok, O. F.; Kosyakov, V. I. Chem.Phys. Lett. 2000, 320, 19. doi: 10.1016/S0009-2614(00)00234-7
18. [18]
  (b) Bulgakov, A. V.; Bobrenok, O. F.; Ozerov, I.; Marine,W.;Giorgio, S.; Lassesson, A.; Capbel, E. E. B. Appl. Phys. A 2004,79, 1369.
19. [19]
  (8) Sladkova, K.; Houska, J.; Havel, J. Rapid Commun. MassSpectrom. 2009, 23, 3114. doi: 10.1002/rcm.v23:19
20. [20]
  (9) Hu, C. H.; Shen, M.; Schaefer, H. F., III. Theor. Chim. Acta1994, 88, 129.
21. [21]
  (10) (a) Chen, M. D.; Huang, R. B.; Zheng, L. S.; Zhang, Q. E.; Au,C. T. Chem. Phys. Lett. 2000, 325, 22. doi: 10.1016/S0009-2614(00)00671-0
22. [22]
  (b) Chen, M. D.; Chen, Q. B.; Liu, J.; Zheng, L. S.; Zhang, Q.E.; Au, C. T. J. Phys. Chem. A 2007, 111, 216.
23. [23]
  (11) Karttunen, A. J.; Linnolahti, M.; Pakkanen, T. A.ChemPhysChem 2008, 9, 2550. doi: 10.1002/cphc.v9:17
24. [24]
  (12) Xue, T.; Luo, J.; Li, F.; Zhao, J. Chem. Phys. Lett. 2010, 485,26. doi: 10.1016/j.cplett.2009.12.019
25. [25]
  (13) Keki, S.; Szilagyi, L. S.; Totok, J.; Deak, G.; Zsuga, M. J. Phys.Chem. B 2003, 107, 4818. doi: 10.1021/jp0274334
26. [26]
  (14) Li, J.; Liu, J.; Chen, Y. J. Mass Spectrom. 2012, 47, 620. doi: 10.1002/jms.2994
27. [27]
  (15) Haberland, H.; Mail, M.; Mossier, M.; Qiang, Y.; Reiners, T.;Thurner, Y. J. Vac. Sci. Technol. A 1994, 12, 2925. doi: 10.1116/1.578967
1. [1]
  Linfeng Zhou , Yulin Zhang , Suhao Lin , Longguan Zhu . 2023年北京大学金秋营及第37届中国化学奥林匹克决赛磷团簇相关试题解析与拓展. University Chemistry, 2025, 40(8): 376-387. doi: 10.12461/PKU.DXHX202411030
2. [2]
  Wei Shao , Wanqun Zhang , Pingping Zhu , Wanqun Hu , Qiang Zhou , Weiwei Li , Kaiping Yang , Xisheng Wang . Design and Practice of Ideological and Political Cases in the Course of Instrument Analysis Experiment: Taking the GC-MS Experiment as an Example. University Chemistry, 2024, 39(2): 147-154. doi: 10.3866/PKU.DXHX202309048
3. [3]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
4. [4]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
5. [5]
  Xingyuan Lu , Yutao Yao , Junjing Gu , Peifeng Su . Energy Decomposition Analysis and Its Application in the Many-Body Effect of Water Clusters. University Chemistry, 2025, 40(3): 100-107. doi: 10.12461/PKU.DXHX202405074
6. [6]
  Wen Jiang , Jieli Lin , Zhongshu Li . 低配位含磷官能团的研究进展. University Chemistry, 2025, 40(8): 138-151. doi: 10.12461/PKU.DXHX202409144
7. [7]
  Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . Atomically Precise (AgPd)₂₇ Nanoclusters for Nitrate Electroreduction to NH₃: Modulating the Metal Core by a Ligand Induced Strategy. Acta Physico-Chimica Sinica, 2025, 41(1): 100008-0. doi: 10.3866/PKU.WHXB202403008
8. [8]
  Xiaohang JIN , Qi LIU , Jianping LANG . Room‑temperature solid‑state synthesis, structure, and third‑order nonlinear optical properties of phosphine‑ligand‑protected silver thiolate clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1505-1512. doi: 10.11862/CJIC.20250125
9. [9]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
10. [10]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
11. [11]
  Tianlong Zhang , Jiajun Zhou , Hongsheng Tang , Xiaohui Ning , Yan Li , Hua Li . Virtual Simulation Experiment for Laser-Induced Breakdown Spectroscopy (LIBS) Analysis. University Chemistry, 2024, 39(6): 295-302. doi: 10.3866/PKU.DXHX202312049
12. [12]
  Junjian Wang , Qingquan Yu , Shunyao Liu , Yuke Chen , Xiaoyu Liu , Guodong Li , Xiaoyan Liu , Hong Liu , Weijia Zhou . Laser-Induced Carbonization of Hydroxyapatite Sandwich Paper for Inkless Printing. Acta Physico-Chimica Sinica, 2024, 40(4): 2304024-0. doi: 10.3866/PKU.WHXB202304024
13. [13]
  Yue-Zhou Zhu , Kun Wang , Shi-Sheng Zheng , Hong-Jia Wang , Jin-Chao Dong , Jian-Feng Li . Application and Development of Electrochemical Spectroscopy Methods. Acta Physico-Chimica Sinica, 2024, 40(3): 2304040-0. doi: 10.3866/PKU.WHXB202304040
14. [14]
  Hanmei Lü , Xin Chen , Qifu Sun , Ning Zhao , Xiangxin Guo . Uniform Garnet Nanoparticle Dispersion in Composite Polymer Electrolytes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305016-0. doi: 10.3866/PKU.WHXB202305016
15. [15]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
16. [16]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 2309036-0. doi: 10.3866/PKU.WHXB202309036
17. [17]
  Xianyong Lu , Tao Hu . Developing an Innovative Inorganic Chemistry Teaching Model Based on Aerospace Specialty Characteristics. University Chemistry, 2025, 40(7): 127-131. doi: 10.12461/PKU.DXHX202409037
18. [18]
  Xinran Zhang , Siqi Liu , Yichi Chen , Qingli Zou , Qinghong Xu , Yaqin Huang . From Protein to Energy Storage Materials: Edible Gelatin Jelly Electrolyte. University Chemistry, 2025, 40(7): 255-266. doi: 10.12461/PKU.DXHX202408104
19. [19]
  Jiandong Liu , Zhijia Zhang , Kamenskii Mikhail , Volkov Filipp , Eliseeva Svetlana , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 2308048-0. doi: 10.3866/PKU.WHXB202308048
20. [20]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097

Get Citation

PDF

XML

Metrics

PDF Downloads(621)
Abstract views(1063)
HTML views(48)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142