Citation: ZHU Jun, ZHANG Yao-Hong, HU Lin-Lua, DAI Song-Yuan. Preparation of In₂S₃ Sensitized Solar Cells with Chemical Bath Deposition and Their Performance[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 89-94. doi: 10.3866/PKU.WHXB201211092 shu

Preparation of In₂S₃ Sensitized Solar Cells with Chemical Bath Deposition and Their Performance

1.
1 Key Lab of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, 230031, P. R. China;
2 Key Lab of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

Received Date: 9 October 2012
Available Online: 9 November 2012
Fund Project: 国家重点基础研究发展规划(973)(2011CBA00700) (973)(2011CBA00700) 国家高技术研究发展计划(863)(2011AA050527) (863)(2011AA050527)国家自然科学基金(21003130, 21103197, 21173227, 21173228)资助项目 (21003130, 21103197, 21173227, 21173228)

In₂S₃ is a stable semiconductor material with low toxicity. We prepared In₂S₃ sensitized solar cells using low-cost chemical bath deposition methodology. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) were used to reveal the microstructure of the In₂S₃ sensitized TiO₂ nanoporous films. Our results indicated that the deposition temperature has a remarkable effect on the morphology of In₂S₃ sensitized TiO₂ films, which in turn affects the photovoltaic performance of devices. When the deposition temperature was low, the deposition reaction rate was slow, resulting in only minimal deposition. However, if the deposition temperature was increased too much, there was insufficient time for the In₂S₃ to be deposited within the internal pore structure of the TiO₂ mesoporous films. The best homogeneous In₂S₃ sensitized TiO₂ films were obtained with a deposition temperature of 40℃. At this temperature, the optical absorption of the resulting film was optimal and displayed the largest short circuit current density among the films examined. Moreover, the fill factor was also the best, approaching 65%. The best overall power conversion efficiency was 0.32%.
- Indium sulfide,
- Sensitization,
- Solar cell,
- Chemical bath depostion,
- Recombination
1. [1]
  
  (1) Hodes, G. J. Phys. Chem. C 2008, 112, 17778. doi: 10.1021/jp803310s
2. [2]
  (2) Kamat, P. V. J. Phys. Chem. C 2008, 112, 18737. doi: 10.1021/jp806791s
3. [3]
  (3) Kamat, P. V.; Tvrdy, K.; Baker, D. R.; Radich, J. G. Chem. Rev.2010, 110, 6664. doi: 10.1021/cr100243p
4. [4]
  (4) Mora-Serö, I.; Bisquert, J. J. Phys. Chem. Lett. 2010, 1, 3046.doi: 10.1021/jz100863b
5. [5]
  (5) Semonin, O.; Luther, J. M.; Choi, S.; Chen, H. Y.; Gao, J.;Nozik, A. J.; Beard, M. C. Science 2011, 334, 1530. doi: 10.1126/science.1209845
6. [6]
  (6) Rühle, S.; Shalom, M.; Zaban, A. ChemPhysChem 2010, 11,2290. doi: 10.1002/cphc.201000069
7. [7]
  (7) Shi, J. F.; Fan, Y.; Xu, X. Q.; Xu, G.; Chen, L. H. Acta Phys. -Chim. Sin. 2012, 28, 857. [史继富, 樊晔, 徐雪青,徐刚, 陈丽华. 物理化学学报, 2012, 28, 857.] doi: 10.3866/PKU.WHXB201202204
8. [8]
  (8) Liu, Y.; Xu. H. Y.; Qian, Y. T. Crystal Growth & Design 2006, 6,1304. doi: 10.1021/cg0504298
9. [9]
  (9) Hodes, G.; Cahen, D. Accounts Chem. Res. 2012, 45, 705. doi: 10.1021/ar200219h
10. [10]
  (10) Qiu,W. M.; Xu, M. S.; Yang, X.; Chen, F.; Nan, Y. X.; Zhang, J.L.; Iwai, H.; Chen, H. Z. J. Mater. Chem. 2011, 21, 13327. doi: 10.1039/C1JM11616A
11. [11]
  (11) Hara, K.; Sayama, K.; Arakawa, H. Solar Energy Mater. Solar Cells 2000, 62, 441. doi: 10.1016/S0927-0248(00)00027-1
12. [12]
  (12) Sarkar, S. K.; Kim, J. Y.; ldstein, D. N.; Neale, N. R.; Zhu,K.; Elliott, C. M.; Frank, A. J.; George, S. M. J. Phys. Chem. C.2010, 114, 8032. doi: 10.1021/jp9086943
13. [13]
  (13) Gan, X.; Li, X.; Gao, X.; Qiu, J.; Zhuge, F. Nanotechnology2011, 22, 305601. doi: 10.1088/0957-4484/22/30/305601
14. [14]
  (14) Hu, L. H.; Dai, S. Y.;Weng, J.; Xiao, S. F.; Sui, Y. F.; Huang, Y.;Chen, S. H.; Kong, F. T.; Pan, X.; Liang, L. Y.;Wang, K. J.J. Phys. Chem. B 2007, 111, 358. doi: 10.1021/jp065541a
15. [15]
  (15) Zhang, Y.; Zhu, J.; Yu, X.;Wei, J.; Hu, L.; Dai, S. Solar Energy2012, 86, 964. doi: 10.1016/j.solener.2012.01.006
16. [16]
  (16) Rengaraj, S.; Venkataraj, S.; Tai, C.W.; Kim, Y.; Repo, E.;Sillanpaa, M. Langmuir 2011, 27, 5534. doi: 10.1021/la104780d
17. [17]
  (17) Chai, B.; Peng, T. Y.; Zeng, P.; Mao, J. J. Mater. Chem. 2011,21, 14587. doi: 10.1039/C1JM11566A
18. [18]
  (18) Kaufmann, C.; Bayon, R.; Bohne,W.; Röhrich, J.; Klenk, R.;Dobson, P. J. J Electro. Soc. 2002, 149, C1. doi: 10.1149/1.1419183
19. [19]
  (19) Mora-Serö, I.; Giménez, S.; Fabregat-Santia , F.; Gémez, R.;Shen, Q.; Toyoda, T.; Bisquert, J. Accounts Chem. Res. 2009,42, 1848. doi: 10.1021/ar900134d
20. [20]
  (20) Chakrapani, V.; Baker, D.; Kamat, P. V. J. Am. Chem. Soc. 2011,133, 967. doi: 10.1021/ja203131b
21. [21]
  (21) Hod, I.; Tachan, Z.; Shalom, M.; Zaban, A. J. Phys. Chem. Lett.2011, 2, 1032. doi: 10.1021/jz200399n
22. [22]
  (22) Zhang, Q. B.; Feng, Z. F.; Han, N. N.; Lin, L. L.; Zhou, J. Z.;Lin, Z. H. Acta Phys. -Chim. Sin. 2010, 26, 2927. [张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华. 物理化学学报, 2010,26, 2927.] doi: 10.3866/PKU.WHXB20101113
23. [23]
  (23) Diguna, L. J.; Shen, Q.; Kobayashi, J.; Toyoda, T. Appl. Phys. Lett. 2007, 91, 023116. doi: 10.1063/1.2757130
24. [24]
  (24) Shen, Q.; Kobayashi, J.; Diguna, L. J.; Toyoda, T. J. Appl. Phys.2008, 103, 084304. doi: 10.1063/1.2903059
25. [25]
  (25) nzález-Pedro, V.; Xu, X.; Mora-Seró, I.; Bisquert, J. ACS Nano 2010, 4, 5783. doi: 10.1021/nn101534y
26. [26]
  (26) Musselman, K. P.; Marin, A.; Schmidt-Mende, L.;MacManus-Driscoll, J. L. Adv. Funct. Mater. 2012, 22, 2202.doi: 10.1002/adfm.201102263
27. [27]
  (27) Boix, P. P.; Lee, Y. H.; Fabregat-Santia , F.; Im, S. H.;Mora-Serö, I.; Bisquert, J.; Seok, S., II. ACS Nano 2012, 6, 873.doi: 10.1021/nn204382k
1. [1]
  Zeyu Liu , Wenze Huang , Yang Xiao , Jundong Zhang , Weijin Kong , Peng Wu , Chenzi Zhao , Aibing Chen , Qiang Zhang . Nanocomposite Current Collectors for Anode-Free All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2305040-0. doi: 10.3866/PKU.WHXB202305040
2. [2]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
3. [3]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
4. [4]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036
5. [5]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 2310024-0. doi: 10.3866/PKU.WHXB202310024
6. [6]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
7. [7]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
8. [8]
  Liangyu Gong , Yongsheng Niu , Xiuzhong Wang , Lihua Lu , Lubin Xu , Shuaishuai Li , Jie Wang . “农科教”融合培养“农化”背景丰富的化学类复合应用型人才路径探索与实践. University Chemistry, 2025, 40(8): 330-337. doi: 10.12461/PKU.DXHX202410011
9. [9]
  Yongjian Zhang , Fangling Gao , Hong Yan , Keyin Ye . Electrochemical Transformation of Organosulfur Compounds. University Chemistry, 2025, 40(5): 311-317. doi: 10.12461/PKU.DXHX202407035
10. [10]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
11. [11]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
12. [12]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
13. [13]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
14. [14]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
15. [15]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
16. [16]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
17. [17]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . Sulfide Solid Electrolyte Synthesized by Liquid Phase Approach and Application in All-Solid-State Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(1): 100004-0. doi: 10.3866/PKU.WHXB202309019
18. [18]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
19. [19]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
20. [20]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117

Get Citation

PDF

XML

Metrics

PDF Downloads(772)
Abstract views(2262)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of In2S3 Sensitized Solar Cells with Chemical Bath Deposition and Their Performance

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of In₂S₃ Sensitized Solar Cells with Chemical Bath Deposition and Their Performance