Citation: GAN Yong-Ping, QIN Huai-Peng, HUANG Hui, TAO Xin-Yong, FANG Jun-Wu, ZHANG Wen-Kui. Preparation and Photocatalytic Activity of Rutile TiO₂-Graphene Composites[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 403-410. doi: 10.3866/PKU.WHXB201211022 shu

Preparation and Photocatalytic Activity of Rutile TiO₂-Graphene Composites

1.
College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Received Date: 11 September 2012
Available Online: 2 November 2012
Fund Project: 浙江省自然科学基金(Y4110523, LY12E01003)资助项目 (Y4110523, LY12E01003)

In this work, graphene oxide ( ) was prepared from natural flake graphite by the modified Hummers method. A series of composites consisting of rutile TiO₂ and graphene (r -TiO₂) were synthesized via a one-step hydrothermal reaction of graphene oxide and titanium isopropylate. The influence of the amount of graphene oxide on the photocatalytic activity of the r -TiO₂ composites was studied. The photocatalysts were characterized by Brunauer-Emmett-Teller sorption (BET), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, UV-Vis absorbance spectroscopy, and photoluminescence (PL) spectroscopy. The as-formed TiO₂ was formed in the rutile phase with a needle-cluster structure, and dispersed uniformly on the surface of graphene sheets. The composites possess higher specific areas than pure rutile TiO₂. The photo-degradation performance of Rhodamine B and methyl orange by the r -TiO₂ composites under ultraviolet and visible light was studied. The results indicated that r -TiO₂ composites prepared with 0.5 mg·mL^-1 of graphene oxide had the greatest photocatalytic activity.
- Rutile TiO₂,
- Graphene,
- Hydrothermal method,
- Photocatalysis,
- Organic pollutants
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Activity of Rutile TiO2-Graphene Composites

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通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Activity of Rutile TiO₂-Graphene Composites