Citation: HUANG Ping, PAN Si-Wei, HUANG Bi-Chun, CHENG Hua, YE Dai-Qi, WU Jun-Liang, FU Ming-Li, LU Sheng-Liang. Structural Properties of MnO_x/Al-SBA-15 in Low-Temperature Selective Catalytic Reduction of NO_x with NH₃[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 176-182. doi: 10.3866/PKU.WHXB201210094 shu

Structural Properties of MnO_x/Al-SBA-15 in Low-Temperature Selective Catalytic Reduction of NO_x with NH₃

HUANG Ping ¹ ,
PAN Si-Wei ² ,
HUANG Bi-Chun ^1,3, ,
CHENG Hua ¹ ,
YE Dai-Qi ^1,3 ,
WU Jun-Liang ^1,3 ,
FU Ming-Li ^1,3 ,
LU Sheng-Liang ⁴

1.
1 College of Environmental Science & Engineering, South China University of Technology, Guangzhou 510006, P. R. China;
2 Electric Power Research Institute of Guangdong Power Grid Corporation, P. R. China;
3 Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangzhou 510006, P. R. China;
4 Guangzhou Environment Protection Investment Co. Ltd., Guangzhou 510700, P. R. China

Received Date: 13 August 2012
Available Online: 9 October 2012
Fund Project: 广州市重大科技专项计划(X2DLB2080501)资助项目 (X2DLB2080501)

A series of MnO_x/Al-SBA-15 catalysts were prepared by post synthesis methods for lowtemperature selective catalytic reduction (SCR) of NO_x with NH₃. Structural properties and catalytic performance were comprehensively characterized by Fourier transform infrared (FTIR) spectroscopy, N₂ adsorption-desorption, X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and temperature programmed desorption of NH₃ (NH₃-TPD). The results showed that moderate addition of Al improved the SCR activity of the MnO_x/SBA-15 catalyst, and the MnO_x/Al-SBA-15 catalyst with n_Si/n_Al=50 had the highest activity. Characterization results revealed that the doped material MnO_x/Al-SBA-15 catalysts maintained high specific surface area, large pore volume, and uniform pore size. Al doping improved the concentration and valence state of Mn, where MnO₂ was determined to be the main active phase. Owing to a high dispersion of MnO_x and a stronger surface acidity, the MnO_x/Al(50)-SBA-15 catalyst exhibited higher SCR activity.
- Acetyl acetone manganese,
- Aluminum,
- SBA-15,
- High dispersion,
- Surface acidity,
- Selective catalytic reduction
1. [1]
  
  (1) Yang, S. J.;Wang, C. Z.; Li, J. H.; Yan, N. Q.; Ma, L.; Chang,H. Z. Appl. Catal B 2011, 110, 71. doi: 10.1016/j.apcatb.2011.08.027
2. [2]
  (2) Luo, H. C.; Huang, B. C.; Fu, M. L.;Wu, J. L.; Ye, D. Q. Acta Phys. -Chim. Sin. 2012, 28, 2175. [罗红成, 黄碧纯, 付名利,吴军良, 叶代启. 物理化学学报, 2012, 28, 2175.] doi: 10.3866/PKU.WHXB201207062
3. [3]
  (3) Fan, X. Y.; Qiu, F. M.; Yang, H.; Tian,W.; Hou, T. F.; Zhang, X.B. Catal. Commun. 2011, 12 (14), 1298. doi: 10.1016/j.catcom.2011.05.011
4. [4]
  (4) Shen, B.; Yao, Y.; Ma, H. S. Chin. J. Catal. 2011, 32 (11-12),1803. doi: 10.1016/S1872-2067(10)60269-0
5. [5]
  (5) Yao, G. H.; Gui, K. T.;Wang, F. Chem. Eng. Technol. 2010, 33
6. [6]
  (7), 1093. doi: 10.1002/ceat.v33:7
7. [7]
  (6) Tang, X. L.; Hao, J. M.; Yi, H. H.; Liu, J. H. Catal. Today 2007,126, 406. doi: 10.1016/j.cattod.2007.06.013
8. [8]
  (7) Shao, X. C.; Duan, L. H.;Wu, Y. Y.; Qin, Y. C.; Yu,W. G.;Wang, Y. Acta Phys. -Chim. Sin. 2012, 28, 1467. [邵新超,段林海, 武玉叶, 秦玉才, 于文广, 王源. 物理化学学报,2012, 28, 1467.] doi: 10.3866/PKU.WHXB201203312
9. [9]
  (8) Boutros, M.; Ttichard, J. M.; Patrick, D. C. Appl. Catal. B 2009,91, 640. doi: 10.1016/j.apcatb.2009.07.004
10. [10]
  (9) AnaK, M. M.; María, A.; Jose, A. Appl. Catal. B 2011, 106, 14.
11. [11]
  (10) Zukerman, R.; Vradman, L.; Titelman, L.; Zeiri, L. Mater. Chem. Phys. 2010, 122, 53. doi: 10.1016/j.matchemphys.2010.02.065
12. [12]
  (11) Zhang, H. L.; Tang, C. J.; Sun, C. Z.; Qi, L.; Gao, F.; Dong, L.;Chen, Y. Microporous Mesoporous Mat. 2012, 151, 44. doi: 10.1016/j.micromeso.2011.11.018
13. [13]
  (12) Chmielarz, L.; Kus'trowski, P.; Dziembaj, R.; Cool, P.;Vansant, E. F. Microporous Mesoporous Mat. 2010, 127, 133.doi: 10.1016/j.micromeso.2009.07.003
14. [14]
  (13) Shylesh, S.; Singh, A. P. J. Catal. 2006, 244, 52. doi: 10.1016/j.jcat.2006.08.002
15. [15]
  (14) Yan, B.;Wang, J.W.; Li, Y. J. J. Alloy. Compd. 2011, 509,9240. doi: 10.1016/j.jallcom.2011.07.006
16. [16]
  (15) Tang, J. Y.; Zu, Y. H.; Huo,W. T.;Wang, L.;Wang, J.; Jia, M.G.; Zhang,W. X. J. Mol. Catal. 2012, 355, 201. doi: 10.1016/j.molcata.2011.12.018
17. [17]
  (16) Min, J.; Jae, K. P.; Eun,W. S. Microporous Mesoporous Mat.2004, 75, 159. doi: 10.1016/j.micromeso.2004.05.018
18. [18]
  (17) Zhang, S. C.; Jiang, D.; Tang, T.; Li, J. H.; Xu, Y. Acta Phys. - Chim. Sin. 2010, 26, 1330. [张书翠, 姜东, 唐涛, 李军华,徐耀. 物理化学学报, 2010, 26, 1330.] doi: 10.3866/PKU.WHXB20100520
19. [19]
  (18) Esparza, J. M.; Ojeda, M. L.; Campero, A. Colloid. Surf. A2004, 241, 35. doi: 10.1016/j.colsurfa.2004.04.010
20. [20]
  (19) Michal, K.; Mietek, J. Chem. Master. 2001, 13 (10), 3169.
21. [21]
  (20) Tang, Q. H.; Hu, S. Q.; Chen, Y. T.; Guo, Z.; Hu, Y.; Yan, Y. H.Microporous Mesoporous Mat. 2010, 132, 501. doi: 10.1016/j.micromeso.2010.03.033
22. [22]
  (21) Xiang, D.; Chen, Y.; Zhao, G. T.;Wu, J. L.; Fu, M. L.; Huang,B. C.; Ye, D. Q. Chin. J. Environ. Eng. 2010, 4 (8), 1851.[向东, 陈颖, 赵国涛, 吴军良, 付名利, 黄碧纯, 叶代启.环境工程学报, 2010, 4 (8), 1851.]
23. [23]
  (22) Mikael, L.; Jan, L.; Tegenfeldt, J. J. Mater. Chem. 2001, 11,1269. doi: 10.1039/b005973k
24. [24]
  (23) Han, Y. F.; Chen, F. X.; Zhong, Z. Y.; Ramesh, K.;Widjaja, E.;Chen, L.W. Catal. Commun. 2006, 7, 739. doi: 10.1016/j.catcom.2006.08.006
25. [25]
  (24) Han, Y. F.; Chen, F. X.; Zhong, Z. Y.; Ramesh, K.; Chen, L.W.;Widjaja, E. J. Phys. Chem. B 2006, 110, 24450. doi: 10.1021/jp064941v
26. [26]
  (25) Chen, Y.; Li, Y. S.; Li, L.; Gu, J. L.; Zhao,W. R.; Li, L.; Shi, J.L. Chin. J. Catal. 2009, 30 (3), 230. [陈勇, 李永生,李亮, 顾金楼, 赵文茹, 李蕾, 施剑林. 催化学报, 2009,30 (3), 230.]
27. [27]
  (26) Zhong, B. C.; Zhou, G. Y.;Wang,W. H.; Fu, M. L.;Wu, J. L.;Chen, L. M.; Huang, B. C.; Ye, D. Q. Acta Sci. Circum. 2011, 31
28. [28]
  (10), 2091. [钟标诚, 周广英, 王文辉, 付名利, 吴军良, 陈礼敏, 黄碧纯, 叶代启. 环境科学学报, 2011, 31 (10), 2091.]
29. [29]
  (27) Qi, G.; Yang, R. T.; Chang, R. Appl. Catal. B 2004, 51, 93. doi: 10.1016/j.apcatb.2004.01.023
30. [30]
  (28) Min, K.; Eun, D. P.; Ji, M. K.; Jae, E. Y. Appl. Catal. A 2007,327, 261. doi: 10.1016/j.apcata.2007.05.024
31. [31]
  (29) Wang, L. S.; Huang, B. C.; Su, Y. X.; Zhou, G. Y.;Wang, K. L.;Luo, H. C. Chem. Eng. J. 2012, 192, 232. doi: 10.1016/j.cej.2012.04.012
32. [32]
  (30) Arenaa, F.; Dariob, R.; Parmaliana, A. Appl. Catal. A 1998, 170,127. doi: 10.1016/S0926-860X(98)00041-6
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Structural Properties of MnOx/Al-SBA-15 in Low-Temperature Selective Catalytic Reduction of NOx with NH3

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Structural Properties of MnO_x/Al-SBA-15 in Low-Temperature Selective Catalytic Reduction of NO_x with NH₃