Citation: LUO Wen-Li, SU Ya-Qiong, TIAN Xiang-Dong, ZHAO Liu-Bin, WU De-Yin, TIAN Zhong-Qun. Reaction of p-Chloronitrobenzene Adsorbed on Silver Nanoparticles[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201209052 shu

Reaction of p-Chloronitrobenzene Adsorbed on Silver Nanoparticles

1.
State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 25 July 2012
Available Online: 5 September 2012
Fund Project: 国家自然科学基金(20973143, 91027009, 21021002) (20973143, 91027009, 21021002) 国家重点基础研究发展规划项目(973)(2009CB930703) (973)(2009CB930703)厦门大学(2010121020)资助 (2010121020)

Surface-enhanced Raman spectroscopy (SERS) on silver nanoparticles is highly sensitive because of surface plasmon resonance. We have studied the structures and photoinduced chemical reactions of p-chloronitrobenzene (PCNB) molecules adsorbed on silver nanoparticles using a combination of SERS and density functional theory (DFT) calculations. When the PCNB molecules are adsorbed to the surface of silver nanoparticles in alkaline solution, the SERS spectra are very different from the normal Raman spectra of PCNB. Comparison of the DFT simulated Raman spectra of PCNB and p,p'-dichloroazobenzene (DCAB) indicates that the new peaks in the SERS spectrum of PCNB adsorbed on silver nanoparticles arise from the azo (C－N＝N－C) group of DCAB.
- Surface-enhanced Raman spectroscopy,
- Density functional theory,
- p-Chloronitrobenzene,
- p,p'-Dichloroazobenzene,
- Silver nanoparticle
1. [1]
  
  (1) Jeanmaire, D. L.; Van Duyne, R. P. J. Electroanal. Chem. 1977,84 (1), 1. doi: 10.1016/S0022-0728(77)80224-6
2. [2]
  (2) Futamata, M. J. Phys. Chem. 1995, 99, 11901. doi: 10.1021/j100031a018
3. [3]
  (3) Sakamoto, K.; Mizutani, G.; Ushioda, S. Phys. Rev. B 1993, 48 (12), 8993.
4. [4]
  (4) Gao, P.; sztola, D.;Weaver, M. J. J. Phys. Chem. 1988, 92,7122. doi: 10.1021/j100336a018
5. [5]
  (5) Osawa, M.; Matsuda, N.; Yoshii, K.; Uchida, I. J. Phys. Chem.1994, 98, 12702. doi: 10.1021/j100099a038
6. [6]
  (6) Wu, D. Y.; Liu, X. M.; Huang, Y. F.; Ren, B.; Xu, X.; Tian, Z. Q.J. Phys. Chem. C 2009, 113, 18212. doi: 10.1021/jp9050929
7. [7]
  (7) Huang, Y. F.; Zhu, H. P.; Liu, G. K.;Wu, D. Y.; Ren, B.; Tian, Z.Q. J. Am. Chem. Soc. 2010, 132 (27), 9244.
8. [8]
  (8) Fang, Y. R.; Li, Y. Z.; Xu, H. X.; Sun, M. T. Langmuir 2010, 26 (11), 7737.
9. [9]
  (9) Canpean, V.; Losin, M.; Astilean, S. Chem. Phys. Lett. 2010,500 (4-6), 277.
10. [10]
  (10) Arjunan, V.; Raj, A.; Sakiladevi, S.; Carthigayan, K.; Mohan, S.J. Mol. Struct. 2012, 1007 (11), 122.
11. [11]
  (11) Griffiths, P.; Thompson, H. Proc. Roy. Soc. London A Math. Phys. Sci. 1967, 298 (1452), 51.
12. [12]
  (12) Green, J.; Kynaston,W.; Lindsey, A. Spectrochim. Acta 1961,17, 486. doi: 10.1016/0371-1951(61)80103-3
13. [13]
  (13) Medhi, K. C. Indian Journal of Physics 1965, 39 (8), 390.
14. [14]
  (14) Green, J.; Harrison, D. Spectrochimica Acta Part A: Molecular Spectroscopy 1970, 26, 1925. doi: 10.1016/0584-8539(70)80130-1
15. [15]
  (15) Meriles, C.; Schneider, J.; Nunes, L. A. O.; Brunetti, A. J. Phys. Soc. Jpn. 1998, 67, 1296. doi: 10.1143/JPSJ.67.1296
16. [16]
  (16) Matsuda, N.; Sawaguchi, T.; Osawa, M.; Uchida, I. Chem. Lett.1995, 145. doi: 10.12461/cl.1995.437
17. [17]
  (17) Kuhn, A.; Eschwege, K. G.; Conradie, J. J. Phys. Org. Chem.2012, 25, 58. doi: 10.1002/poc.v25.1
18. [18]
  (18) Matsuda, N.; Yoshii, K.; Ataka, K. I.; Osawa, M.; Matsue, T.;Uchida, I. Chem. Lett. 1992, 1385. doi: 10.1246/cl.1992.1385
19. [19]
  (19) Khurana, J. M.; Ray, A. Bull. Chem. Soc. Jpn. 1996, 69, 407.doi: 10.1246/bcsj.69.407
20. [20]
  (20) Moglie, Y.; Vitale, C.; Radivoy, G. Tetrahedron Lett. 2008, 49,1828. doi: 10.1016/j.tetlet.2008.01.053
21. [21]
  (21) Han, S.W.; Lee, I.; Kim, K. Langmuir 2002, 18, 182. doi: 10.1021/la0115684
22. [22]
  (22) Dong, B.; Fang, Y.; Chen, X.; Xu, H.; Sun, M. Langmuir 2011,27, 10677. doi: 10.1021/la2018538
23. [23]
  (23) Shin, K. S.; Lee, H. S.; Joo, S.W.; Kim, K. J. Phys. Chem. C.2007, 111, 15223. doi: 10.1021/jp073053c
24. [24]
  (24) Tao, A.; Sinsermsuksakul, P.; Yang, P. Angew. Chem. Int. Edit.2006, 45, 4597.
25. [25]
  (25) Mammone, J.; Sharma, S.; Nicol, M. J. Phys. Chem. 1980, 84,3130. doi: 10.1021/j100460a032
26. [26]
  (26) Schweinsberg, D.; Hope, G.; Trueman, A.; Otieno-Ale , V.Corrosion Sci. 1996, 38, 587. doi: 10.1016/0010-938X(95)00148-D
27. [27]
  (27) Whiffen, D. H. J. Chem. Soc. 1956, 1350.
28. [28]
  (28) Moskovits, M.; DiLella, D.; Maynard, K. Langmuir 1988, 4, 67.doi: 10.1021/la00079a012
29. [29]
  (29) Kyziol, J. B.; Frej, H. Chemical Papers 1988, 42 (6), 781.
30. [30]
  (30) Stammreich, H. Experientia 1950, 6, 225.
31. [31]
  (31) Wu, D. Y.; Cao, Z. B.; Ren, B.; Xu, X.; Tian, Z. Q. J. Light Scattering 2002, 13, 199. [吴德印, 曹志霁, 任斌, 徐昕,田中群. 光散射学报, 2002, 13, 199.]
32. [32]
  (32) Wu, D. Y.; Hayashi, M.; Lin, S. H.; Tian, Z. Q. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2004,60, 137. doi: 10.1016/S1386-1425(03)00190-2
33. [33]
  (33) Wu, D. Y.; Liu, X. M.; Xu, Y. C.; Duan, S.; Ren, B.; Tian, Z. Q.J. Light Scattering 2006, 18, 323. [吴德印, 刘秀敏, 徐咏春,段赛, 任斌, 田中群. 光散射学报, 2006, 18, 323.]
34. [34]
  (34) Bauernschmitt, R.; Ahlrichs, R. Chem. Phys. Lett. 1996, 256,454. doi: 10.1016/0009-2614(96)00440-X
35. [35]
  (35) Badger, G. M.; Lewis, G. E. J. Chem. Soc. 1953, 2147.
36. [36]
  (36) Moskovits, M. J. Chem. Phys. 1982, 77, 4408. doi: 10.1063/1.444442
1. [1]
  Hao XU , Ruopeng LI , Peixia YANG , Anmin LIU , Jie BAI . Regulation mechanism of halogen axial coordination atoms on the oxygen reduction activity of Fe-N₄ site: A density functional theory study. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240302
2. [2]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230385
3. [3]
  Kaifu Zhang , Shan Gao , Bin Yang . Application of Theoretical Calculation with Fun Practice in Raman Spectroscopy Experimental Teaching. University Chemistry, doi: 10.12461/PKU.DXHX202404045
4. [4]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240213
5. [5]
  Wei Sun , Yongjing Wang , Kun Xiang , Saishuai Bai , Haitao Wang , Jing Zou , Arramel , Jizhou Jiang . CoP Decorated on Ti₃C₂T_x MXene Nanocomposites as Robust Electrocatalyst for Hydrogen Evolution Reaction. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202308015
6. [6]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, doi: 10.3866/PKU.DXHX202308034
7. [7]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, doi: 10.3866/PKU.DXHX202309057
8. [8]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, doi: 10.12461/PKU.DXHX202407022
9. [9]
  Tongqi Ye , Yanqing Wang , Qi Wang , Huaiping Cong , Xianghua Kong , Yuewen Ye . Reform of Classical Thermodynamics Curriculum from the Perspective of Computational Chemistry. University Chemistry, doi: 10.12461/PKU.DXHX202409128
10. [10]
  Xiaochen Zhang , Fei Yu , Jie Ma . Cutting-Edge Applications of Multi-Angle Numerical Simulations for Capacitive Deionization. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202311026
11. [11]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, doi: 10.12461/PKU.DXHX202404067
12. [12]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240075
13. [13]
  Ruiqin Feng , Ye Fan , Yun Fang , Yongmei Xia . Strategy for Regulating Surface Protrusion of Gold Nanoflowers and Their Surface-Enhanced Raman Scattering. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202304020
14. [14]
  Meifeng Zhu , Jin Cheng , Kai Huang , Cheng Lian , Shouhong Xu , Honglai Liu . Classical Density Functional Theory for Understanding Electrochemical Interface. University Chemistry, doi: 10.12461/PKU.DXHX202405166
15. [15]
  Yue-Zhou Zhu , Kun Wang , Shi-Sheng Zheng , Hong-Jia Wang , Jin-Chao Dong , Jian-Feng Li . Application and Development of Electrochemical Spectroscopy Methods. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202304040
16. [16]
  Yufan ZHAO , Jinglin YOU , Shixiang WANG , Guopeng LIU , Xiang XIA , Yingfang XIE , Meiqin SHENG , Feiyan XU , Kai TANG , Liming LU . Raman spectroscopic quantitative study of the melt microstructure in binary Li₂O-GeO₂ functional crystals. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20250063
17. [17]
  Gaopeng Liu , Lina Li , Bin Wang , Ningjie Shan , Jintao Dong , Mengxia Ji , Wenshuai Zhu , Paul K. Chu , Jiexiang Xia , Huaming Li . Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202306041
18. [18]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240007
19. [19]
  Zhengkun QIN , Zicong PAN , Hui TIAN , Wanyi ZHANG , Mingxing SONG . A series of iridium(Ⅲ) complexes with fluorophenyl isoquinoline ligand and low-efficiency roll-off properties: A density functional theory study. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240429
20. [20]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, doi: 10.3866/PKU.DXHX202310111

Get Citation

PDF

XML

Metrics

PDF Downloads(894)
Abstract views(2719)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142