Citation: GAO Ji-Ning, ZHAO Hua-Bo, QI Li-Min. Synthesis of Silver Sulfide Hollow Sphere-Silver Nanoparticle Heterostructures Based on Reactive Templates[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2487-2492. doi: 10.3866/PKU.WHXB201209031 shu

Synthesis of Silver Sulfide Hollow Sphere-Silver Nanoparticle Heterostructures Based on Reactive Templates

1.
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 17 July 2012
Available Online: 3 September 2012
Fund Project: 国家自然科学基金(21173010, 21073005, 51121091)资助项目 (21173010, 21073005, 51121091)

Silver sulfide hollow sphere-silver nanoparticle heterostructures were prepared by the simultaneous cation exchange and oxidation-reduction reactions of Cu₂S hollow spheres with Ag⁺ ions in aqueous solution. The obtained Ag₂S-Ag hybrid hollow spheres consisted of Ag₂S hollow spheres about 600 nm in diameter and 20-30 nm in thickness with a single Ag nanoparticle attached to the outer surface of each Ag₂S hollow sphere. The products were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDS). When CuS hollow spheres were used as the reactive template instead of Cu₂S hollow spheres, Ag₂S hollow spheres were the predominant product under similar reaction conditions, indicating that the Cu(I) in the Cu₂S hollow spheres served as a reductant for reducing Ag⁺ ions to metallic Ag, and hence played a key role in the formation of the Ag₂S-Ag hybrid hollow spheres. Furthermore, secondary deposition of Ag on the Ag₂S-Ag hybrid hollow spheres resulted in the formation of larger Ag₂S-Ag hybrid hollow spheres consisting of Ag₂S hollow spheres with around a half of the surface coated by a Ag film.
- Silver sulfide,
- Hollow sphere,
- Silver nanoparticle,
- Heterostructure,
- Reactive template,
- Chemical transformation,
- Cuprous sulfide
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