Citation: XU Da, LIU Shi-Yan, LIU Yun-Ling, WANG Zhen-Lü. Effect of pH Value on the Properties of Molybdenum-Based Multiphasic Oxide Catalysts in Selective Oxidation of Isobutene to Methacrolein[J]. Acta Physico-Chimica Sinica, ;2012, 28(11): 2690-2696. doi: 10.3866/PKU.WHXB201208282 shu

Effect of pH Value on the Properties of Molybdenum-Based Multiphasic Oxide Catalysts in Selective Oxidation of Isobutene to Methacrolein

1.
1 Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Changchun 130021, P. R. China;
2 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130021, P. R. China

Received Date: 21 June 2012
Available Online: 28 August 2012
Fund Project: 无机合成与制备化学国家重点实验室开放课题(2012-15) (2012-15)吉林大学科学前沿与交叉学科创新项目(2012)资助 (2012)

The effect of different pH values on Mo-Bi-Fe-Co-Mn multiphasic oxide catalysts prepared via co-precipitation methods was studied. In addition, selective oxidation of isobutylene to methacrolein (MAL) reaction was evaluated. The structures and crystal phases of the catalysts were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), N₂ adsorption-desorption, and temperature-programmed reduction of H₂ (H₂-TPR). The characterization results showed that the structures and properties depended on the pH during preparation. The amount of the special crystalline phase MX on the catalysts increased with increasing pH value during the preparation process. When the precipitation pH value was 7, the crystalline phase MX reached maximum levels on the corresponding sample. The conversion of isobutene and selectivity for methacrolein were 99.9% and 95.6%, respectively. When increasing the precipitation pH, the MX content decreased, and the conversion of isobutene and selectivity for methacrolein decreased. The results revealed that synergistic effects or cooperation between multiphasic oxides and the special phase MX might be important for improving catalytic performance.
- Molybdenum,
- Multiphasic oxides,
- pH value,
- Isobutene,
- Oxidation
1. [1]
  
  (1) Zhu,W. C.; Jia, M. J.;Wang, Z. L.;Wang, G. J.;Wu, T. H.Chem. J. Chin. Univ. 2007, 28 (2), 334. [朱万春, 贾明君,王振旅, 王国甲, 吴通好. 高等学校化学学报, 2007, 28 (2),334.]
2. [2]
  (2) Ono, T.; Utsumi, K.; Kataoka, M.; Tanaka, Y.; Noguchi, F.Catal. Today 2004, 91-92, 181.
3. [3]
  (3) Liu, H.; Gaigneaux, E. M.; Imoto, H.; Shido, T.; Iwasawa, Y.Appl. Catal. A 2000, 202, 251. doi: 10.1016/S0926-860X(00)00539-1
4. [4]
  (4) Inoue, T.; Oyama, S. T.; Imoto, H.; Asakura, K.; Iwasawa, Y.Appl. Catal. A2000, 191, 131. doi: 10.1016/S0926-860X(99)00314-2
5. [5]
  (5) Cai, T. J.; Yu, C. L.; Deng, Q.; Peng, Z. S.; Long, Y. F.; Jiang, S.L. Chin. J. Catal. 2003, 24, 951. [蔡铁军, 余长林, 邓谦,彭振山, 龙云飞, 蒋绍亮. 催化学报, 2003, 24, 951.]
6. [6]
  (6) Song, N.; Rhodes, C.; Bartley, J. K.; Taylor, S. H.; Chadwick,D.; Hutchings, G. J. J.Catal. 2005, 236, 282. doi: 10.1016/j.jcat.2005.10.008
7. [7]
  (7) Gaigneaux, E. M.; Genet, M. J.; Ruiz, P.; Delmon, B. J. Phys. Chem. B 2000, 104, 5724. doi: 10.1021/jp9913416
8. [8]
  (8) Guan, J. Q.; Xu, C.;Wang, Z. Q.; Yang, Y.; Liu, B.; Shang, F. P.;Shao, Y. Q.; Kan, Q. B. Catal. Lett. 2008, 124, 428. doi: 10.1007/s10562-008-9496-3
9. [9]
  (9) Wang, L.; Li, Z. X.; Zhang, S. J.; Zhang, X. P. The Chinese Journal of Process Engineering 2007, 7 (1), 202. [王蕾,李增喜, 张锁江, 张香平. 过程工程学报, 2007, 7 (1), 202.]
10. [10]
  (10) Grzybowska, B.; Haber, J.; Komorek, J. J. Catal. 1972, 25, 25.doi: 10.1016/0021-9517(72)90198-4
11. [11]
  (11) Wang, X. T.; Bi, C.; Zhong, S. H.; Xiao, X. F. Chin. J. Catal.2010, 31, 84. [王希涛, 毕超, 钟顺和, 肖秀芬. 催化学报,2010, 31, 84.] doi: 10.3724/SP.J.1088.2010.90634
12. [12]
  (12) Jung, J. C.; Lee, H.; Kim, H.; Chung, Y. M.; Kim, T. J.; Lee, S.J.; Oh, S. H.; Kim, Y. S.; Song, I. K.Catal. Commun. 2008, 9,1676. doi: 10.1016/j.catcom.2008.01.026
13. [13]
  (13) Jung, J. C.; Lee, H.; Seo, J. G.; Seo, J. G.; Park, S.; Chung, Y.M.; Kim, T. J.; Lee, S. J.; Oh, S. H.; Kim, Y. S.; Song, I. K.Catal. Today 2009, 141, 325.
14. [14]
  (14) Jung, J. C.; Lee, H.; Kim, H.; Park, S.; Chung, Y. M.; Kim, T. J.;Lee, S. J.; Oh, S. H.; Kim, Y. S.; Song, I. K. Catal. Commun. 2008, 9, 2059. doi: 10.1016/j.catcom.2008.03.052
15. [15]
  (15) Guan, J. Q.;Wu, S. J.;Wang, H. S.; Jing, S. B.;Wang, G. J.;Zhen, K. J.; Kan, Q. B. J. Catal. 2007, 251, 354. doi: 10.1016/j.jcat.2007.07.028
16. [16]
  (16) VanWell,W. J. M.; Le, M. T.; Schiødt, N. C.; Hoste, S.; Stoltze,P. J. Mol. Catal. A 2006, 256, 1. doi: 10.1016/j.molcata.2006.04.030
17. [17]
  (17) Jo, B. Y.; Kim, E. J.; Moon, S. H. Appl. Catal. A 2007, 332, 257.doi: 10.1016/j.apcata.2007.08.025
18. [18]
  (18) Le, M. T.; VanWell,W. J. M.; Stoltze, P.; Driessche, I. V.;Hoste, S. Appl. Catal. A 2005, 282, 189. doi: 10.1016/j.apcata.2004.12.010
19. [19]
  (19) Carrazán, S. R. G.; Martín, C.; Rives, V.; Vidal, R. Appl. Catal. A 1996, 135, 95. doi: 10.1016/0926-860X(95)00226-X
20. [20]
  (20) Moens, L.; Ruiz, P.; Delmon, B.; Devillers, M. Appl. Catal. A1998, 171, 131. doi: 10.1016/S0926-860X(98)00075-1
21. [21]
  (21) Moens, L.; Ruiz, P.; Delmon, B.; Devillers, M. Appl. Catal. A1999, 180, 299. doi: 10.1016/S0926-860X(98)00360-3
22. [22]
  (22) Moens, L.; Ruiz, P.; Delmon, B.; Devillers, M. Appl. Catal. A2003, 249, 365. doi: 10.1016/S0926-860X(03)00225-4
23. [23]
  (23) Xiong, Y. L.;Weng, L. T.; Bertrand, P.; Ladrière, J.; Daza, L.;Ruiz, P.; Delmon, B. J. Mol. Catal. A 2000, 155, 59. doi: 10.1016/S1381-1169(99)00319-2
24. [24]
  (24) Xiong, Y. L.; Cadus, L. E.; Daza, L.; Bertrand, P.; Ladrière, J.;Ruiz, P.; Delmon, B. Topics Catal. 2000, 11/12, 167.
25. [25]
  (25) Qu, Y. L.; Liu, S. Y.;Wang, Z. L.; Xu, J. N. Chem. J. Chin. Univ. 2010, 31 (2), 325. [曲渊立, 刘士艳, 王振旅, 徐家宁.高等学校化学学报, 2010, 31 (2), 325.]
26. [26]
  (26) Li, J.; Song,W.; Dou, B. S. Chin. J. Appl. Chem. 1996, 13 (5),58. [李静, 宋伟, 窦伯生. 应用化学, 1996, 13 (5), 58.]
27. [27]
  (27) Sun, R. Q.; Gu, X. Y.; Zhang, H. H.; Yang, R. S.; Yang, Q. Y.;Zhao, S. L. Spectroscopy and Spectral Analysis 2000, 20 (6),857. [孙瑞卿, 辜晓燕, 张汉辉, 杨融生, 杨齐愉, 赵士龙.光谱学与光谱分析, 2000, 20 (6), 857.]
28. [28]
  (28) Wang, G. J.;Wu, T. H.; Yang, H. M.; Jiang, Y. Z.; Ji, Y. S.Chem. J. Chin. Univ. 1994, 15 (12), 1845. [王国甲, 吴通好,杨洪茂, 姜玉子, 稽玉书. 高等学校化学学报, 1994, 15 (12),1845.]
29. [29]
  (29) Cai, T. J.; Deng, Q.; Huang, D. F.; Peng, Z. S.; Long, Y. F.;Chen, Y. Z. Chin. J. Inorg. Chem. 2002, 18 (6), 602. [蔡铁军,邓谦, 黄德发, 彭振山, 龙云飞, 陈亚中. 无机化学学报,2002, 18 (6), 602.]
30. [30]
  (30) Ma,W. P.; Kugler, E. L.;Wright, J.; Dadyburjor, D. B. Energy & Fuels 2006, 20, 2299. doi: 10.1021/ef0602372
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
3. [3]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
4. [4]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
5. [5]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . Rational Design of Bimetallic Oxide Anodes for Superior Li⁺ Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-0. doi: 10.3866/PKU.WHXB202311005
6. [6]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
7. [7]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
8. [8]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
9. [9]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
10. [10]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
11. [11]
  Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378
12. [12]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081
13. [13]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
14. [14]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
15. [15]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
16. [16]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 2404023-0. doi: 10.3866/PKU.WHXB202404023
17. [17]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
18. [18]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
19. [19]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . Performance and Electrochemical Asymmetry Optimization of Hydrogen Electrode Supported Reversible Solid Oxide Cell. Acta Physico-Chimica Sinica, 2025, 41(1): 100005-0. doi: 10.3866/PKU.WHXB202309037
20. [20]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059

Get Citation

PDF

XML

Metrics

PDF Downloads(812)
Abstract views(2777)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142