Citation: CHEN Wei, GAO Han-Yang, YANG Yu, LIN Pei-Bin, YUAN Jian, SHANGGUAN Wen-Feng, SU Jia-Chun, SUN Yang-Zhou. Polymerizable Complex Synthesis of Protonated Form of Layered Perovskite K_0.5La_0.5Bi₂Ta₂O₉ for Water Splitting into Hydrogen[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208011 shu

Polymerizable Complex Synthesis of Protonated Form of Layered Perovskite K_0.5La_0.5Bi₂Ta₂O₉ for Water Splitting into Hydrogen

1.
1 Research Center for Combustion and Environmental Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China;
2 CNOOC New Energy Investment Co. Ltd. Beijing 100016, P. R. China

Received Date: 6 July 2012
Available Online: 1 August 2012
Fund Project: 国家重点基础研究发展计划(973计划)(2009CN220000) (973计划)(2009CN220000)国家自然科学基金(20973110)资助项目 (20973110)

The protonated layered perovskite oxide H_1.9K_0.3La_0.5Bi_0.1Ta₂O₇ (HKLBT) was prepared from K_0.5La_0.5Bi₂Ta₂O₉ (KLBT) by H ion-exchange, and subsequently characterized by thermogravimetric analysis (TG-DSC), X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), and X-ray photoelectron spectroscopy (XPS). The effects of the calcining temperature on the material's photocatalytic activity were also investigated. Results showed that HKLBT with high crystalline quality could be synthesized at low temperatures and that HKLBT prepared from KLBT calcined at 900℃ exhibited the greatest photocatalytic activity, with an average water splitting hydrogen evolution rate of 236.6 μmol·h^-1 in pure water. The time course of water splitting indicated HKLBT has ability to split water into hydrogen and oxygen with long-term stability.
- Photocatalysis,
- Water splitting,
- Layered perovskite,
- Acid treatment
1. [1]
  
  (1) Maeda, K.; Domen, K. J. Phys. Chem. C 2007, 111, 7851. doi: 10.1021/jp070911w
2. [2]
  (2) Chen, X.; Shen, S.; Guo, L.; Mao, S. Chem. Rev. 2010, 110,6503. doi: 10.1021/cr1001645
3. [3]
  (3) Li, Y. X.;Wang, J. X.; Peng, X. Q.; Lu, G. X.; Li, S. B. Int. J. Hydrog. Energy 2010, 35, 7116. doi: 10.1016/j.ijhydene.2010.02.017
4. [4]
  (4) Shimizu, K.; Itoh, S.; Hatamachi, T.; Kodama, T.; Sato, M.;Toda, K. Chem. Mater. 2005, 17, 5161. doi: 10.1021/cm050982c
5. [5]
  (5) Shangguan,W.; Yoshida, A. J. Mater. Sci. 2001, 36, 4989. doi: 10.1023/A:1011877414129
6. [6]
  (6) Huang, Y.; Li, Y.;Wei, Y.; Huang, M.;Wu, J. Sol. Energy Mater. Sol. Cells 2011, 95, 1019. doi: 10.1016/j.solmat.2010.12.017
7. [7]
  (7) Tsunoda, Y.; Shirata, M.; Sugimoto,W.; Liu, Z.; Erasaki, O.;Kuroda, K. Inorg. Chem. 2001, 40, 5768. doi: 10.1021/ic010266m
8. [8]
  (8) Yan, S.; Huang, Q. D.; Lin, J. D.; Yuan, Y. Z.; Liao, D.W. Acta Phys. -Chim. Sin. 2011, 27, 2406. [闫石, 黄勤栋, 林敬东,袁友珠, 廖代伟. 物理化学学报, 2011, 27, 2406.] doi: 10.3866/PKU.WHXB20110929
9. [9]
  (9) Yoshino, M.; Kakihana, M. Chem. Mater. 2002, 14, 3369.doi: 10.1021/cm0109037
10. [10]
  (10) Kakihana, M.; Milanova, M.; Arima, M.; Okubo, T.; Yashima,M.; Yoshimura, M. J. Am. Ceram. Soc. 1996, 79, 1673. doi: 10.1111/jace.1996.79.issue-6
11. [11]
  (11) Maeda, K.; Terashima, H.; Kase, K.; Domen, K. Appl. Catal. A: Gen. 2009, 357, 206. doi: 10.1016/j.apcata.2009.01.024
12. [12]
  (12) Karthika, C.; Ravishankara, N.; Maglioneb, M.; Vondermuhllb,R.; Etourneaub, J.; Varmaa, K. Solid State Communications2006, 139, 268. doi: 10.1016/j.ssc.2006.06.019
13. [13]
  (13) Li, C.; Yuan, J.; Han, B.; Shangguan,W. Int. J. Hydrog. Energy2011, 36, 4271. doi: 10.1016/j.ijhydene.2011.01.022
14. [14]
  (14) Kudo, A.; Miseki, Y. Chem. Soc. Rev. 2009, 38, 253. doi: 10.1039/b800489g
15. [15]
  (15) Tsunoda, Y.; Sugimoto,W.; Sugahara, Y. Chem. Mater. 2003, 15,632. doi: 10.1021/cm0200893
16. [16]
  (16) Jiang, L.;Wang, Q.; Li, C.; Yan, J.; Shangguan,W. Int. J. Hydrog. Energy 2010, 35, 7043. doi: 10.1016/j.ijhydene.2009.12.187
17. [17]
  (17) Betley, T.;Wu, Q.; Voorhis, T.; Nocera, D. G. Inorg. Chem.2008, 47, 1849. doi: 10.1021/ic701972n
18. [18]
  (18) Kanan, M.; Nocera, D. Science 2008, 32, 1072. doi: 10.3321/j.issn:1006-9275.2008.07.010
19. [19]
  (19) Kiwi, J.; Morrison, C. J. Phys. Chem. 1984, 88, 6146. doi: 10.1021/j150669a018
20. [20]
  (20) Kiwi, J.; Grätzel, M. J. Phys. Chem. 1984, 88, 1302. doi: 10.1021/j150651a012
21. [21]
  (21) McGuire, G.; Schweitzer, K.; Carlson, T. Inorg. Chem. 1973,12, 2450. doi: 10.1021/ic50128a045
22. [22]
  (22) Shi, R.; Lin, J.;Wang, Y.; Xu, J.; Zhu, Y. J. Phys. Chem. C 2010,114, 6472.
23. [23]
  (23) Galenda, A.; Maria, M.; Krishnan, V.; Bertagnolli, H. Chem. Mater. 2007, 19, 2796.
24. [24]
  (24) Chen,W.; Dong, X. F.; Chen, Z. S.; Chen, S. Z.; Lin,W. M.Acta Phys. -Chim. Sin. 2009, 25, 1107. [陈威, 董新法, 陈之善, 陈胜洲, 林维明. 物理化学学报, 2009, 25, 1107.] doi: 10.3866/PKU.WHXB20090624
1. [1]
  Huasen Lu , Shixu Song , Qisen Jia , Guangbo Liu , Luhua Jiang . Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202304035
2. [2]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202405005
3. [3]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202308003
4. [4]
  Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202308024
5. [5]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240259
6. [6]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240067
7. [7]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of Electron Bridge and Activation of MoS₂ Inert Basal Planes by Ni Doping for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406024
8. [8]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202403009
9. [9]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230346
10. [10]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240037
11. [11]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, doi: 10.3866/PKU.DXHX202311101
12. [12]
  Xia ZHANG , Yushi BAI , Xi CHANG , Han ZHANG , Haoyu ZHANG , Liman PENG , Shushu HUANG . Preparation and photocatalytic degradation performance of rhodamine B of BiOCl/polyaniline. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240255
13. [13]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20250001
14. [14]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202305047
15. [15]
  Jiajia Wang , Sibo Huang , Xijing Gao , Chaoxun Liu , Haibo Zhang . 光催化硝酸根还原产氨的综合实验设计. University Chemistry, doi: 10.12461/PKU.DXHX202410050
16. [16]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202312014
17. [17]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202408005
18. [18]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202405016
19. [19]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202404030
20. [20]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202307040

Get Citation

PDF

XML

Metrics

PDF Downloads(765)
Abstract views(2178)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Polymerizable Complex Synthesis of Protonated Form of Layered Perovskite K0.5La0.5Bi2Ta2O9 for Water Splitting into Hydrogen

Metrics

通讯作者: 陈斌, bchen63@163.com

Polymerizable Complex Synthesis of Protonated Form of Layered Perovskite K_0.5La_0.5Bi₂Ta₂O₉ for Water Splitting into Hydrogen