Citation: BI Dong-Qin, XU Yi-Ming. Influence of Iron Oxide Doping on the Photocatalytic Degradation of Organic Dye X3B over Tungsten Oxide[J]. Acta Physico-Chimica Sinica, ;2012, 28(07): 1777-1782. doi: 10.3866/PKU.WHXB201205113 shu

Influence of Iron Oxide Doping on the Photocatalytic Degradation of Organic Dye X3B over Tungsten Oxide

BI Dong-Qin ,
XU Yi-Ming

1.
Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China

Received Date: 27 March 2012
Available Online: 11 May 2012
Fund Project: 国家自然科学基金(20873124) (20873124)国家重点基础研究发展规划项目(973) (2011CB936003)资助 (973) (2011CB936003)

Development of a highly active visible-light-driven photocatalyst is a challenge for chemical use of solar energy. In this work, WO₃ was simply mixed with Fe₂O₃, and used thereafter for the photocatalytic degradation of organic dye X3B in the presence of H₂O₂. It was observed that the composite activity was greatly influenced by the catalyst sintering temperature, and by Fe₂O₃ content in the mixed oxide. The optimum sintering temperature and Fe₂O₃ loading were 400 ° C and 1.0% (w), respectively. Through a spin trapping electron paramagetic spectroscopy, it was found that the composite produced a significantly larger amount of hydroxyl radicals, in relative to Fe₂O₃ and WO₃. It is proposed that the observed synergistic effect between Fe₂O₃ and WO₃ is due to the charge transfer between the two oxides, improving the separation of the photogenerated charge carriers, and thus accelerating the photocatalytic degradation of X3B.
- Photocatalysis,
- Tungsten oxide,
- Iron oxide,
- Synergism,
- Organic dye,
- Degradation
1. [1]
  
  (1) Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
2. [2]
  (2) Kabra, K.; Chaudhary, R.; Sawhney, R. L. Ind. Eng. Chem. Res.2004, 43, 7683. doi: 10.1021/ie0498551
3. [3]
  (3) Koka, M.; Sahin, M. Int. J. Hydrog. Energy 2002, 27, 363. doi: 10.1016/S0360-3199(01)00133-1
4. [4]
  (4) Serrano, B.; Lasa, H. Ind. Eng. Chem. Res.1997, 36, 4705. doi: 10.1021/ie970104r
5. [5]
  (5) Ni, M.; Leung, M. K. H.; Leung, D. Y. C.; Sumathy, K.Renewable and Sustainable Energy Rev. 2007, 11, 401. doi: 10.1016/j.rser.2005.01.009
6. [6]
  (6) Linsebigler, A. L.; Lu, G.; Yates, J. T., Jr. Chem. Rev. 1995, 95,735. doi: 10.1021/cr00035a013
7. [7]
  (7) Murakami, Y.; Endo, K.; Ohta, I.; Nosaka, A. Y.; Nosaka, Y.J. Phys. Chem. C 2007, 111, 11339. doi: 10.1021/jp0722049
8. [8]
  (8) Kumar, S. G.; Devi, L. G. J. Phys. Chem. A 2011, 115, 13211.doi: 10.1021/jp204364a
9. [9]
  (9) Tachikawa, T.; Majima, T. Langmuir 2009, 25, 7791. doi: 10.1021/la900790f
10. [10]
  (10) Zhao, Z. G.; Miyauchi, M. Angew. Chem. Int. Edit. 2008, 47,7051. doi: 10.1002/anie.200802207
11. [11]
  (11) Santato, C.; Ulmann, M.; Augustynski, J. Adv. Mater. 2001, 13,511. doi: 10.1002/1521-4095(200104)13:7<511:AIDADMA511>3.0.CO;2-W
12. [12]
  (12) Santato, C.; Odziemkowski, M.; Ulmann, M.; Augustynski, J.J. Am. Chem. Soc. 2001, 123, 10639. doi: 10.1021/ja011315x
13. [13]
  (13) Kay, A.; Cesar, I.; Grätzel, M. J. Am. Chem. Soc. 2006, 128,15714. doi: 10.1021/ja064380l
14. [14]
  (14) Abe, R.; Takami, H.; Murakami, N.; Ohtani, B. J. Am. Chem. Soc. 2008, 130, 7780. doi: 10.1021/ja800835q
15. [15]
  (15) Kim, J.; Lee, C.W.; Choi,W. Environ. Sci. Technol. 2010, 44,6849. doi: 10.1021/es101981r
16. [16]
  (16) Darwent, J. R.; Mills, A. J. Chem. Soc. Faraday Trans. 1982,78, 359. doi: 10.1039/f29827800359
17. [17]
  (17) Sclafani, A.; Palmisano, L.; Marci, G.; Venezia, A. M. Sol. Energy Mater. Sol. Cells 1998, 51, 203. doi: 10.1016/S0927-0248(97)00215-8
18. [18]
  (18) Arai, T.; Horiguchi, M.; Yanagida, M.; Gunji, T.; Sugihara, H.;Sayama, K. Chem. Commun. 2008, 5565. doi: 10.1039/b811657a
19. [19]
  (19) Sun, S.;Wang,W.; Zeng, S.; Shang, M.; Zhang L. J. Harzard. Mater. 2010, 178, 427. doi: 10.1016/j.jhazmat.2010.01.098
20. [20]
  (20) He, T.; Yao, J. N. J. Mater. Chem. 2007, 17, 4547. doi: 10.1039/b709380b
21. [21]
  (21) Du,W.; Xu, Y.;Wang, Y. Langmuir 2008, 24, 175. doi: 10.1021/la7021165
22. [22]
  (22) Wang, Y.; Du,W.; Xu, Y. Langmuir 2009, 25, 2895. doi: 10.1021/la803714m
23. [23]
  (23) Bi, D.; Xu, Y. Langmuir 2011, 27, 9359. doi: 10.1021/la2012793
24. [24]
  (24) Pope, M. T.; Varga, G. M. Inorg. Chem. 1966, 5, 1249. doi: 10.1021/ic50041a038
25. [25]
  (25) Yang, L.; Xiao, Y.; Liu, S.; Li, Y.; Cai, Q.; Luo, S.; Zeng, G.Appl. Catal. B: Environ. 2010, 94, 142. doi: 10.1016/j.apcatb.2009.11.002
26. [26]
  (26) Adán, C.; Bahamonde, A.; Fernández-García, M.; Martínez-Arias, A. Appl. Catal. B 2007, 72, 11. doi: 10.1016/j.apcatb.2006.09.018
27. [27]
  (27) Sherman, D. M. Geochim. Cosmochim. Acta 2005, 69, 3249.doi: 10.1016/j.gca.2005.01.023
28. [28]
  (28) Thompson, T. L.; Yates, J. T. Chem. Rev. 2006, 106, 4428. doi: 10.1021/cr050172k
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