Citation: SHEN Bao-Shou, FENG Wang-Jun, LANG Jun-Wei, WANG Ru-Tao, TAI Zhi-Xin, YAN Xing-Bin. Nitric Acid Modification of Graphene Nanosheets Prepared by Arc- Discharge Method and Their Enhanced Electrochemical Properties[J]. Acta Physico-Chimica Sinica, ;2012, 28(07): 1726-1732. doi: 10.3866/PKU.WHXB201204261 shu

Nitric Acid Modification of Graphene Nanosheets Prepared by Arc- Discharge Method and Their Enhanced Electrochemical Properties

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1School of Science, Lanzhou University of Technology, Lanzhou 730050, P. R. China; 2State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China

Received Date: 23 February 2012
Available Online: 26 April 2012
Fund Project: 项目, 中国博士后科学基金(20100480728) (20100480728)甘肃省青年科技基金计划项目(1107RJYA274)资助 (1107RJYA274)

Large-scale synthesis of few-layer graphene nanosheets (GNSs) with high crystallinity and electrical conductivity (1680 S·m^-1) is achieved by an arc-discharge method. The GNSs exhibited od morphologies as observed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). However, electrochemical testing showed that the performance of the graphene (GNS) electrodes in supercapacitors was poor. To increase the surface active sites for electrochemical reactions and promote the wettability by aqueous electrolyte of the GNSs, a nitric acid treatment was used to chemically modify their surface. The acid treatment introduced more oxygen/nitrogen-containing functional groups onto the GNS surface, and clearly enhanced the hydrophilicity. The nitric-acid-modified GNSs (H-GNSs) showed vastly better electrode performance, with a maximum specific capacitance of 65.5 F·g^-1 (about 30 times that of original GNSs) at a current density of 0.5 A·g^-1 in 2 mol·L^-1 KOH electrolyte. In addition, the H-GNS electrode showed od cycling stability and lifetime after running 2000 cycles. Therefore, H-GNSs may be an attractive candidate as electrode materials for supercapacitors.
- Graphene,
- Arc-discharge,
- Chemical modification,
- Specific capacitance,
- Supercapacitor
1. [1]
  
  (1) Winter, M.; Brodd, R. J. Chem. Rev. 2004, 104, 4245. doi: 10.1021/cr020730k
2. [2]
  (2) Conway, B. E. J. Electrochem. Soc. 1991, 138, 1539. doi: 10.1149/1.2085829
3. [3]
  (3) Xiong, S. L.; Yuan, C. Z.; Zhang, X. G.; Xi, B. J.; Qian, Y. T.Chem. Eur. J. 2009, 15, 5320. doi: 10.1002/chem.200802671
4. [4]
  (4) Wu, Z. S.;Wang, D.W.; Ren,W. C.; Zhao, J. P.; Zhou, G. M.;Li, F.; Cheng, H. M. Adv. Funct. Mater. 2010, 20, 3595. doi: 10.1002/adfm.201001054
5. [5]
  (5) Lang, J.W.; Kong, L. B.;Wu,W. J.; Luo, Y. C.; Kang, L. Chem. Commun. 2008, 4213.
6. [6]
  (6) Li, Y. M.; Van Zijll, M.; Chiang, S.; Pan, N. J. Power Sources2011, 196, 6003. doi: 10.1016/j.jpowsour.2011.02.092
7. [7]
  (7) Chang, J. K.; Tsai,W. T. J. Electrochem. Soc. 2005, 152, A2063.
8. [8]
  (8) Zhang, H.; Cao, G. P.;Wang, Z. Y.; Yang, Y. S.; Shi, Z. J.; Gu,Z. N. Electrochem. Commun. 2008, 10, 1056. doi: 10.1016/j.elecom.2008.05.007
9. [9]
  (9) Nam, K.W.; Kim, K. B. J. Electrochem. Soc. 2002, 149, A346.
10. [10]
  (10) Lei, Z. B.; Christov, N.; Zhao, X. S. Energy Environ. Sci. 2011,4, 1866. doi: 10.1039/c1ee01094h
11. [11]
  (11) Allen, M. J.; Tung, V. C.; Kaner, R. B. Chem. Rev. 2010, 110,132. doi: 10.1021/cr900070d
12. [12]
  (12) Zhang, H. X.; Lv, J.; Li, Y. M.;Wang, Y.; Li, J. H. ACS Nano2010, 4, 380. doi: 10.1021/nn901221k
13. [13]
  (13) Yoo, J. J.; Balakrishnan, K.; Huang, J.; Meunier, V.; Sumpter, B.G.; Srivastava, A.; Conway, M.; Reddy, A. L. M.; Yu, J.; Vajtai,R.; Ajayan, P. M. Nano Lett. 2011, 11, 1423. doi: 10.1021/nl200225j
14. [14]
  (14) Wang, Y.; Shi, Z. Q.; Huang, Y.; Ma, Y. F.;Wang, C. Y.; Chen,M. M.; Chen, Y. S. J. Phys. Chem. C 2009, 113, 13103. doi: 10.1021/jp902214f
15. [15]
  (15) Li, Z. J.; Yang, B. C.; Zhang, S. R.; Zhao, M. X. Appl. Surf. Sci.2011, 258, 3726.
16. [16]
  (16) Wang, D.W.; Li, F. Z.;Wu, S.; Ren,W.; Cheng, H. M.Electrochem. Commun. 2009, 11, 1729. doi: 10.1016/j.elecom.2009.06.034
17. [17]
  (17) Liu, C. G.; Yu, Z. N.; Neff, D.; Zhamu, A.; Jang, B. Z. Nano Lett. 2010, 10, 4863. doi: 10.1021/nl102661q
18. [18]
  (18) Stoller, M. D.; Park, S.; Zhu, Y.W.; An, J. H.; Ruoff, R. S. Nano Lett. 2008, 8, 3498. doi: 10.1021/nl802558y
19. [19]
  (19) Liu,W.W.; Yan, X. B.; Lang, J.W.; Xue, Q. J. J. Mater. Chem.2011, 21, 13205. doi: 10.1039/c1jm11930c
20. [20]
  (20) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A.Science 2004, 306, 666. doi: 10.1126/science.1102896
21. [21]
  (21) Tung, V. C.; Allen, M. J.; Yang, Y.; Kaner, R. B. Nat. Nanotechnol. 2009, 4, 25. doi: 10.1038/nnano.2008.329
22. [22]
  (22) Emtsev, K. V.; Bostwick, A.; Horn, K.; Jobst, J.; Kellogg, G. L.;Ley, L.; McChesney, J. L.; Ohta, T.; Reshanov, S. A.; Rohrl, J.;Rotenberg, E.; Schmid, A. K.;Waldmann, D.;Weber, H. B.;Seyller, T. Nat. Mater. 2009, 8, 203. doi: 10.1038/nmat2382
23. [23]
  (23) Sutter, P.W.; Flege, J. I.; Sutter, E. A. Nat. Mater. 2008, 7, 406.doi: 10.1038/nmat2166
24. [24]
  (24) Kim, K. S.; Zhao, Y.; Jang, H.; Lee, S. Y.; Kim, J. M.; Ahn, J.H.; Kim, P.; Choi, J. Y.; Hong, B. H. Nature 2009, 457, 706.doi: 10.1038/nature07719
25. [25]
  (25) Yang, X.; Dou, X.; Rouhanipour, A.; Zhi, L.; Rader, H. J.;Mullen, K. J. Am. Chem. Soc. 2008, 130, 4216. doi: 10.1021/ja710234t
26. [26]
  (26) Subrahmanyam, K. S.; Panchakarla, L. S.; vindaraj, A.; Rao,C. N. R. J. Phys. Chem. C 2009, 113, 4257.
27. [27]
  (27) Wu, Z.; Ren,W.; Gao, L.; Zhao, J.; Chen, Z.; Liu, B.; Tang, D.;Yu, B.; Jiang, C.; Cheng, H. ACS Nano 2009, 3, 411. doi: 10.1021/nn900020u
28. [28]
  (28) Yan, L.;Wang, Z. Y.; Zhang, H.; Fang, J.; Cao, G. P.; Shi, Z. J.;Wang, B. Y. Journal of Inorganic Materials 2010, 25, 725. doi: 10.3724/SP.J.1077.2010.00725
29. [29]
  (29) Yu, D. S.; Dai, L. M. J. Phys. Chem. Lett. 2009, 1, 467.
30. [30]
  (30) Du, Q. L.; Zheng, M. B.; Zhang, L. F.;Wang, Y.W.; Chen, J. H.;Xue, L. P.; Dai,W. J.; Ji, G. B.; Cao, J. M. Electrochim. Acta2010, 55, 3897. doi: 10.1016/j.electacta.2010.01.089
31. [31]
  (31) Qian, Y.; Lu, S. B.; Gao, F. L. J. Mater. Sci. 2011, 46, 3517. doi: 10.1007/s10853-011-5260-y
32. [32]
  (32) Lu, X.J.; Dou, H.; Yang, S. D.; Hao, L.; Zhang, F.; Zhang, X. G.Acta Phys. -Chim. Sin. 2011, 27, 2333. [卢向军, 窦辉, 杨苏东, 郝亮, 张方, 张校刚. 物理化学学报, 2011, 27, 2333.]doi: 10.3866/PKU.WHXB20111022
33. [33]
  (33) Wang, H. L.; Casalongue, H. S.; Liang, Y. Y.; Dai, H. J. J. Am. Chem. Soc. 2010, 132, 7472. doi: 10.1021/ja102267j
34. [34]
  (34) Liang, M. H.; Zhi, L. J. J. Mater. Chem. 2009, 19, 5871. doi: 10.1039/b901551e
35. [35]
  (35) Lang, J.W.; Yan, X. B.; Yuan, X. Y.; Yang, J.; Xue, Q. J.J. Power Sources 2011, 196, 10472. doi: 10.1016/j.jpowsour.2011.08.017
36. [36]
  (36) Shen, B. S.; Ding, J. J.; Yan, X. B.; Feng,W. J.; Li, J.; Xue, Q. J.Appl. Surf. Sci. 2012, 258, 4523. doi: 10.1016/j.apsusc.2012.01.019
37. [37]
  (37) Kong, L. B.; Lang, J.W.; Liu, M.; Luo, Y. C.; Kang, L. J. Power Sources 2009, 194, 1194. doi: 10.1016/j.jpowsour.2009.06.016
38. [38]
  (38) Wu, Y. P.;Wang, B.; Ma, Y. F.; Huang, Y.; Li, N.; Zhang, F.;Chen, Y. S. Nano Res. 2010, 3, 661. doi: 10.1007/s12274-010-0027-3
39. [39]
  (39) Chen, C. M.; Huang, J. Q.; Zhang, Q.; ng,W. Z.; Yang, Q.H.;Wang, M. Z.; Yang, Y. G. Carbon 2012, 50, 659. doi: 10.1016/j.carbon.2011.09.022
40. [40]
  (40) Bichat, M. P.; Raymundo-Piñero, E.; Béguin, F. Carbon 2010,48, 4351. doi: 10.1016/j.carbon.2010.07.049
41. [41]
  (41) Lufrano, F.; Staiti, P. Energy Fuels 2010, 24, 3313. doi: 10.1021/ef901447y
42. [42]
  (42) Wang, J.; Chen, M. M.;Wang, C. Y.;Wang, J. Z.; Zheng, J. M.J. Power Sources 2011, 196, 550. doi: 10.1016/j.jpowsour.2010.07.030
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