Citation: LIU Jian-Xin, GUO Yong-Jun, ZHU Yang-Wen, YANG Hong-Ping, YANG Xue-Shan, ZHONG Jin-Hang, LI Hua-Bing, LUO Ping-Ya. Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties[J]. Acta Physico-Chimica Sinica, ;2012, 28(07): 1757-1763. doi: 10.3866/PKU.WHXB201204231 shu

Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties

1.
1. State Key Laboratory of Oil and Gas Reservoirs Geology and Exploration, Southwest Petroleum University, Chengdu 610500, P. R. China;
2. School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, P. R. China;
3. Gelogical Scientific Research Institute, Shengli Oilfield Branch Company, SINOPEC, Dongying 257015, Shandong Province, P. R. China

Received Date: 20 February 2012
Available Online: 23 April 2012
Fund Project: 国家科技重大专项(2011ZX05011)资助项目 (2011ZX05011)

In this paper, mixed micelle composed of alcohol and polymerizable surfactant (surfmer) were constructed. The aggregated numbers of surfmer (hexadecyl trimethyl allylammonium chloride (C₁₆DMAAC)) in the mixed micelle were measured using a steady-state fluorescence quenching (SSFQ) technique. Using a mixed micellar method with adiabatic polymerization and post-hydrolyzation techniques, the high molecular weight (M_w) micro-block associative polymer of P(AM-NaAA-C₁₆DMAAC) was polymerized. Structures were characterized by Fourier transform-infrared (FT-IR) spectroscopy and ¹³C nuclear magnetic resonance (NMR) spectroscopy. Using rheological experiments, the effects of micro-block length and salt concentration of on the thickening and viscoelastic rheological properties of the polymers were studied. All experiments confirmed that the micro-block length could be adjusted using the mixed micellar method. Increases in the micro-block length were accompanied by decreases in the critical associative concentration (CAC). The viscosities and viscoelastic rheological properties increased to maximum then decreased steady with the length increasing, indicating that the length was at an optimum value.
- Alcohols,
- Polymerizable surfactant,
- Associative polymer,
- Micro-block length,
- Mixed micelle,
- Rheology
1. [1]
  
  (1) Taylor, K. C.; Nasr-El-Din, H. A. J. Pet. Sci. Eng. 1998, 19, 265.doi: 10.1016/S0920-4105(97)00048-X
2. [2]
  (2) Wever, D. A. Z.; Picchioni, F.; Broekhuis, A. A. Prog. Polym. Sci. 2011, 36, 1558. doi: 10.1016/j.progpolymsci.2011.05.006
3. [3]
  (3) Volpert, E.; Selb, J.; Candau, F. Macromolecules 1996, 29,1452. doi: 10.1021/ma951178m
4. [4]
  (4) Volpert, E.; Selb, J.; Candau, F. Polymer 1998, 39, 1025. doi: 10.1016/S0032-3861(97)00393-5
5. [5]
  (5) Stähler, K.; Selb, J.; Candau, F. Langmuir 1999, 15, 7565. doi: 10.1021/la990431z
6. [6]
  (6) Thunemann, A. F.; Kubowicz, S.; von Berlepsch, H.; Mohwald,H. Langmuir 2006, 22, 2506. doi: 10.1021/la0533720
7. [7]
  (7) Gao, B. J.; Jiang, L. D.; Kong, D. L. Colloid Polym. Sci. 2007,285, 839. doi: 10.1007/s00396-006-1613-5
8. [8]
  (8) Unsal, H.; Aydogan, N. Langmuir 2009, 25, 7884. doi: 10.1021/la900456t
9. [9]
  (9) Biggs, S.; Selb, J.; Candau, F. Langmuir 1992, 8, 838. doi: 10.1021/la00039a018
10. [10]
  (10) Bu, H.; Kjoniksen, A. L.; Elgsaeter, A.; Nystrom, B. Colloids Surf. A 2006, 278, 166. doi: 10.1016/j.colsurfa.2005.12.016
11. [11]
  (11) Penott-Chang, E. K.; uveia, L.; Fernandez, I. J.; Muller, A. J.;Diaz-Barrios, A.; Saez, A. E. Colloids Surf. A 2007, 295, 99.doi: 10.1016/j.colsurfa.2006.08.038
12. [12]
  (12) Talwar, S.; Scanu, L.; Raghavan, S. R.; Khan, S. A. Langmuir2008, 24, 7797. doi: 10.1021/la801030n
13. [13]
  (13) Chen, H.; Li, E. X.; Ye, Z. B.; Han, L. J.; Luo, P. Y. Acta Phys. -Chim. Sin. 2011, 27, 671. [陈洪, 李二晓, 叶仲斌,韩利娟, 罗平亚. 物理化学学报, 2011, 27, 671.] doi: 10.3866//PKU.WHXB20110306
14. [14]
  (14) Summers, M.; Eastoe, J. Adv. Colloid Interface Sci. 2003,100-102, 137.
15. [15]
  (15) Guyot, A. Adv. Colloid Interface Sci. 2004, 108, 3. doi: 10.1016/j.cis.2003.10.009
16. [16]
  (16) Tajima, K.; Aida, T. Chem. Commun. 2000, 2399.
17. [17]
  (17) Candau, F.; Regalado, E. J.; Selb, J. Macromolecules 1998, 31,5550. doi: 10.1021/ma9802982
18. [18]
  (18) Attwood, D.; Mosquera, V.; Rodriguez, J.; Garcia, M.; Suarez,M. J. Colloid & Polymer Science 1994, 272, 584. doi: 10.1007/BF00653225
19. [19]
  (19) Zhang, X. F.;Wu,W. H. Chin. Chem. Lett. 2009, 20, 1361. doi: 10.1016/j.cclet.2009.06.011
20. [20]
  (20) Lianos, P.; Zana, R. Chem. Phys. Lett. 1980, 76, 62. doi: 10.1016/0009-2614(80)80605-1
21. [21]
  (21) Zana, R.; Yiv, S.; Strazielle, C.; Lianos, P. J. Colloid Interface Sci. 1981, 80, 208. doi: 10.1016/0021-9797(81)90177-6
22. [22]
  (22) Zhou, Y. X.; Guo, Y. J.; Luo, P. Y. J. Southwest Pet. Inst. 2004,26, 62. [周云霞, 郭拥军, 罗平亚. 西南石油学院学报, 2004,26, 62.]
23. [23]
  (23) Zhang,W. C.; Li, G. Z.; Shen, Q.; Lu, Y. J. Acta Chim. Sin.2000, 58, 374. [张为灿, 李干佐, 沈强, 卢拥军. 化学学报,2000, 58, 374.]
24. [24]
  (24) Abdurrahmanoglu, S.; Can, V.; Okay, O. Polymer 2009, 50,5449. doi: 10.1016/j.polymer.2009.09.042
25. [25]
  (25) Candau, F.; Selb, J. Adv. Colloid Interface Sci. 1999, 79, 149.doi: 10.1016/S0001-8686(98)00077-3
26. [26]
  (26) Chassenieux, C.; Nicolai, T.; Benyahia, L. Curr. Opin. Colloid Interface Sci. 2011, 16, 18. doi: 10.1016/j.cocis.2010.07.007
27. [27]
  (27) Yu, Y. M.;Wang, Z. H.; Gao, B. J.;Wang, R. X. Acta Phys. -Chim. Sin. 2006, 22, 496. [于亚明, 王中华, 高保娇,王蕊欣. 物理化学学报, 2006, 22, 496.] doi: 10.3866/PKU.WHXB20060421
28. [28]
  (28) Kujawa, P.; Audibert-Hayet, A.; Selb, J.; Candau, F.Macromolecules 2006, 39, 384. doi: 10.1021/ma051312v
29. [29]
  (29) Regalado, E. J.; Selb, J.; Candau, F. Macromolecules 1999, 32,8580. doi: 10.1021/ma990999e
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Polymerization of Micro-Block Associative Polymer with Alcohol-Surfmer Mixed Micellar Method and Their Rheological Properties

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com