Citation: HU Wen-Liang, XU Gang, MA Jian-Wei, XIONG Bin, SHI Ji-Fu. Optical and Phase Transition Properties of Ti_xV_1-xO₂ Thin Films[J]. Acta Physico-Chimica Sinica, ;2012, 28(06): 1533-1538. doi: 10.3866/PKU.WHXB201203191 shu

Optical and Phase Transition Properties of Ti_xV_1-xO₂ Thin Films

HU Wen-Liang ^1,2,3 ,
XU Gang ^1,2, ,
MA Jian-Wei ^1,2,4 ,
XIONG Bin ^1,2,3 ,
SHI Ji-Fu ^1,2

1.
1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, P. R. China;
2. Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640, P. R. China;
3. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
4. Civil Engineering Institute, Northeast Petroleum University, Daqing 163318, Heilongjiang Province, P. R. China

Received Date: 13 December 2011
Available Online: 19 March 2012
Fund Project: 国家自然科学基金(51102235) (51102235) 广东省产学研结合计划(2010B090400109) (2010B090400109)广东省中国科学院全面战略合作计划(2011B090300044)资助项目 (2011B090300044)

Ti_xV_1-xO₂ (0≤x≤1) thin films with different molar ratios of V/Ti were prepared on c-plane sapphire (0001) substrates by radio frequency magnetron sputtering. The microstructure and optical properties of the thin films were determined by X-ray diffraction (XRD), Raman spectroscopy, and UV-visible-near infrared (UV-Vis-NIR) spectroscopy. The width of the optical band gap was calculated and the integrated solar transmittance of the films was characterized. As the content of titanium was increased, infrared regulation and thermal hysteresis were gradually reduced until they disappeared. The results show that the band gap of the thin films broadens as the content of titanium increases, causing the optical absorption edge to exhibit a blue shift. Conversely, the band gap narrows as the proportion of vanadium is increased, which causes a red shift of the optical absorption edge.
- VO₂ thin film,
- TiO₂ thin film,
- Magnetron sputtering,
- Optical property,
- Phase transition property
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Optical and Phase Transition Properties of TixV1-xO2 Thin Films

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Optical and Phase Transition Properties of Ti_xV_1-xO₂ Thin Films