Citation: WU Xiao-Na, ZOU Wen-Sheng, ZHAO Jian-Xi. Highly Stable Foams Generated by the Gemini Surfactant Ethanediyl-α,ω-bis(tetradecyldimethylammonium bromide)[J]. Acta Physico-Chimica Sinica, ;2012, 28(05): 1213-1217. doi: 10.3866/PKU.WHXB201203053 shu

Highly Stable Foams Generated by the Gemini Surfactant Ethanediyl-α,ω-bis(tetradecyldimethylammonium bromide)

1.
Institute of Colloid and Interface Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China

Received Date: 20 December 2011
Available Online: 5 March 2012
Fund Project: 国家自然科学基金(20673021, 20873024) (20673021, 20873024)福建省自然科学基金(2010J01038)资助项目 (2010J01038)

This paper reports a highly stable foam system generated by the gemini surfactant ethanediyl- α,ω-bis(tetradecyldimethylammonium bromide) (referred to as 14-2-14). The time measured for the collapse of the foam to half its initial height was used to characterize the foam stability; it was as high as 961 min for this system and significantly longer than that (754 min) for ethanediyl-α,ω-bis(dodecyldimethylammonium bromide) (12-2-12) foams. Thus the gemini surfactant structure of a short spacer together with two long tails enabled it to be a highly efficient foam stabilizer. The dilational rheology of the adsorbed films revealed the relationship between the interfacial elasticity and the foam stability. The high-frequency limit of elasticity of the adsorbed film at a specific surface coverage was again found to indicate foam stability. A larger limit of elasticity indicated a more stable foam.
- Foam stabilizer,
- Gemini surfactant,
- Short spacer,
- Long tail,
- High interfacial-elasticity
1. [1]
  (1) Wu, X. N.; Zhao, J. X.; Li, E. J.; Zou, W. S. Colloid Polym. Sci. 2011, 289, 1025.
2. [2]
  (2) Pei, X. M.; You, Y.; Zhao, J. X.; Deng, Y. S.; Li, E. J.; Li, Z. X. J. Colloid Interface Sci. 2010, 351, 457.
3. [3]
  (3) Bergeron, V. Langmuir 1997, 13, 3474.
4. [4]
  (4) Espert, A.; Klitzing, R. V.; Poulin, P.; Colin, A.; Zana, R.; Langevin, D. Langmuir 1998, 14, 4251.
5. [5]
  (5) Zana, R.; Benrraou, M.; Rueff, R. Langmuir 1991, 7, 1072.
6. [6]
  (6) You, Y.; Wu, X. N.; Zhao, J. X.; Ye, Y. Z.; Zou, W. S. Colloids Surf. A 2011, 384, 164.
7. [7]
  (7) Stubenrauch, C.; Miller, R. J. Phys. Chem. B 2004, 108, 6412.
8. [8]
  (8) Santini, E.; Ravera, F.; Ferrari, M.; Stubenrauch, C.; Makievski, A.; Krägel, J. Colloids Surf. A 2007, 298, 12.
9. [9]
  (9) Wang, L.; Yoon, R. H. Int. J. Miner. Process. 2008, 85, 101.
10. [10]
  (10) Georgieva, D.; Cagna, A.; Langevin, D. Soft Matter 2009, 5, 2063.
11. [11]
  (11) Acharya, D. P.; Gutiérrez, J. M.; Aramaki, K.; Aratani, K.; Kunieda, H. J. Colloid Interface Sci. 2005, 291, 236.
12. [12]
  (12) Espert, A.; Klitzing, R. V.; Poulin, P.; Colin, A.; Zana, R.; Langevin, D. Langmuir 1998, 14, 4251.
13. [13]
  (13) Sonin, A, A.; Bonfillon, A.; Langevin, D. J. Colloid Interface Sci. 1994, 162, 323.
14. [14]
  (14) Li, Y. M.; Xu, G. Y.; Xin, X.; Gao, X. R.; Wu, D. Carbohydrate Polym. 2008, 72, 211.
15. [15]
  (15) Lucassen, J.; van den Tempel, M. Chem. Eng. Sci. 1972, 27, 1283.
16. [16]
  (16) Lucassen, J.; van den Tempel, M. J. Colloid Interface Sci. 1972, 41, 491.
17. [17]
  (17) Rosen, M. J. Surfactants and Interfacial Phenomena; Wiley: New York, 1988.
1. [1]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
2. [2]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
3. [3]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
4. [4]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034
5. [5]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
6. [6]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
7. [7]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
8. [8]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
9. [9]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
10. [10]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
11. [11]
  Jingkun Yu , Xue Yong , Ang Cao , Siyu Lu . Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity. Acta Physico-Chimica Sinica, 2024, 40(6): 2307015-0. doi: 10.3866/PKU.WHXB202307015
12. [12]
  Yuanyuan JIANG , Fangfang TU , Yuhong ZHANG , Shi CHEN , Jiayuan XIANG , Xinhui XIA . Preparation and electrochemical properties of high-stability cathode prelithiation additive. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1101-1111. doi: 10.11862/CJIC.20240441
13. [13]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
14. [14]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
15. [15]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
16. [16]
  Shijie Ren , Mingze Gao , Rui-Ting Gao , Lei Wang . Bimetallic Oxyhydroxide Cocatalyst Derived from CoFe MOF for Stable Solar Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(7): 2307040-0. doi: 10.3866/PKU.WHXB202307040
17. [17]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
18. [18]
  Tao Xu , Wei Sun , Tianci Kong , Jie Zhou , Yitai Qian . Stable Graphite Interface for Potassium Ion Battery Achieving Ultralong Cycling Performance. Acta Physico-Chimica Sinica, 2024, 40(2): 2303021-0. doi: 10.3866/PKU.WHXB202303021
19. [19]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
20. [20]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004

Get Citation

PDF

XML

Metrics

PDF Downloads(714)
Abstract views(2266)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142