Citation: YANG Zhi-Bin, DING Wei-Zhong. Reaction Pathway for Reforming Coke Oven Gas over NiO/M Catalyst in an Oxygen Permeation Membrane Reactor[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 935-941. doi: 10.3866/PKU.WHXB201202133 shu

Reaction Pathway for Reforming Coke Oven Gas over NiO/M Catalyst in an Oxygen Permeation Membrane Reactor

YANG Zhi-Bin ^1, ,
DING Wei-Zhong ²

1.
1. School of Metallurgy and Materials Engineering, Zhangjiagang Campus, Jiangsu University of Science and Technology, Zhangjiagang 215600, Jiangsu Province, P. R. China;
2. Shanghai Key Laboratory of Modern Metallurgy and Material Processing, Shanghai University, Shanghai 200072, P. R. China

Received Date: 22 October 2011
Available Online: 13 February 2012
Fund Project: 国家高技术研究发展计划(863)(2006AA11A189) (863)(2006AA11A189) 江苏科技大学人才引进(35271103) (35271103)

The reaction pathway for reforming coke oven gas (COG) in an oxygen permeation membrane was analyzed. Through the reforming experiments of H₂+N₂, CH₄+N₂, CO+N₂, H₂+CH₄+N₂ mixtures, with or without a catalyst and the catalyst bed, the reaction scheme is proposed: H₂ in COG is absorbed and dissociates on Ni particle on catalyst, the H* of dissociation migrates to high active site (“triphase boundary”) and reacts with diffused oxygen or lattice oxygen on film surface to form H₂O. The CH₄ also could be dissociated on active metal surface to form CH₃^* and H^*. The H₂O formed reacts with the C species to form H₂ and CO. At last the residual H₂O reacts with the residual CH₄ on the catalyst bed to form H₂ and CO.
- Oxygen permeation membrane reactor,
- Coke oven gas,
- Reforming,
- Reaction pathway
1. [1]
  (1) Chen, J. X.; Qiu, Y. J.; Zhang, J. Y.; Su,W. H. Acta Phys . -Chim. Sin. 2004, 20, 76. [陈吉祥, 邱业君, 张继炎, 苏万华. 物理化学学报, 2004, 20, 76.]
2. [2]
  (2) Ai, X. P.; Yue, B. H.;Wang, X. G.; Yang, J.; Lu, X. G.; Ding,W. Z. Acta Phys . -Chim. Sin. 2009, 25, 1517. [艾馨鹏, 岳宝华, 汪学广, 杨军, 鲁雄刚, 丁伟中. 物理化学学报, 2009, 25, 1517.]
3. [3]
  (3) Yang, Z. B.; Zhang, Y.W.; Zhang, Y. Y.; Ding,W. Z.; Shen, P. J.; Liu, Y.; Zhou, Y. D.; Huang, S. Q. Acta Phys . -Chim. Sin. 2010, 26, 350.
4. [4]
  (4) Zhang, Y. Y.; Li, Q.; Shen, P. J.; Liu, Y.; Yang, Z. B.; Ding,W. Z.; Lu, X. G. Int. J. Hydrog. Energy 2008, 33, 3311.
5. [5]
  (5) Yang, Z. B.; Ding,W. Z.; Zhang, Y. Y.; Lu, X. G.; Zhang, Y.W.; Shen, P. J. Int. J. Hydrogen Energy 2010, 35, 6239.
6. [6]
  (6) Cheng, H.W.; Zhang, Y.W.; Lu, X. G.; Ding,W. Z.; Li, Q. Energy & Fuels 2009, 23, 414.
7. [7]
  (7) Yang, Z. B.; Zhang, Y. Y.; Ding,W. Z.; Zhang, Y.W.; Shen, P. J.; Zhou, Y. D.; Liu, Y.; Huang, S. Q.; Lu, X. G. J .Natural Gas Chemistry 2009, 18, 407.
8. [8]
  (8) Nakagawa, K.; Ikenalca, N.; Teng, Y.; Kobayaslii, T.; Suzulci, T. J. Catal. 1999, 186, 405.
9. [9]
  (9) Ashcroft, A. T.; Cheetham, A. K.; Foord, J. S.; Green, M. L. H.; Grey, C. P.; Murrell, A. J.; Vernon, P. D. F. Nature 1990, 344, 319.
10. [10]
  (10) Hickman, D. A.; Schmidt, L. D. Science 1993, 259, 343.
11. [11]
  (11) Hickman, D. A.; Schmidt, L. D. J. Catal. 1992,138, 267.
12. [12]
  (12) Shao, Z. P.; Xiong, G. X.; Dong, H.; Yang,W. S.; Lin, L.W. Separ. Purif. Technol. 2001, 25, 97.
13. [13]
  (13) Ikeguchi, M.; Mimura, T.; Sekine, Y.; Kikuchi, E.; Matsukata, M. Appl. Catal. A: Gen. 2005, 290, 212.
14. [14]
  (14) Wang, B. Dense Oxygen Permeable Membranes and Membrane-based Process. Ph. D. Dissertation, University of Science and Technology of China, Hefei, 2006. [汪波. 高温致密透氧膜材料和膜过程研究[D]. 合肥: 中国科技大学, 2006]
15. [15]
  (15) Wang, H. H.; Cong, Y.; Yang,W. S. Catal. Today 2003, 82, 157.
16. [16]
  (16) Chen, C. S.; Feng, S. J.; Ran, S.; Zhu, D. C.; Liu,W.; Bouwmeester, H. J. M. Angew Chem. Int. Edit. 2003, 42, 5196.
17. [17]
  (17) FisherⅡ, J. C.; Steven, S.; Chuang, C. Catal. Commun. 2009, 10, 772.
18. [18]
  (18) Zhu, D. C.; Xu, X.Y.; Feng, S. J.; Liu,W.; Chen, C. S. Catal. Today 2003, 82, 151.
19. [19]
  (19) Karmer, R.; Andre, M. J. Catal. 1979, 58, 287.
20. [20]
  (20) Sen, B.; Falconer, J. L.; Mao, T. F.; Tu, M. J. Catal. 1990, 126, 465.
21. [21]
  (21) Shen, P. J.; Ding,W. Z.; Zhou, Y. D.; Huang, S. Q. Applied Surface Science 2010, 256, 5094.
22. [22]
  (22) Zhang,W. X.; Smit, J.; Van Sint Annaland, M.; Kuipers, J. A. M. J. Membr. Sci. 2007, 291, 19.
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