Citation: YANG Wei-Hua, YANG Wu-Tao, LIN Xiao-Yan. Preparation and Characterization of a Novel Bi-Doped PbO₂ Electrode[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 831-836. doi: 10.3866/PKU.WHXB201202101 shu

Preparation and Characterization of a Novel Bi-Doped PbO₂ Electrode

1.
College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, Fujian Province, P. R. China

Received Date: 3 January 2012
Available Online: 10 February 2012
Fund Project: 国家自然科学基金(21103055) (21103055)华侨大学基本科研业务专项基金(JB-ZR1139)资助项目 (JB-ZR1139)

A novel high-performance PbO₂ electrode modified with Bi³⁺ (Bi-PbO₂) was prepared by electrodeposition. The microstructure and electrochemical properties of the modified electrode were investigated using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), fluorospectrophotometry (FP), Mott-Schottky analysis, electrochemical impedance spectroscopy (EIS), and linear-sweep voltammetry (LSV). The results of SEM, EDS, XPS, XRD, and UV-Vis DRS show that insertion of Bi³⁺ , which is in the form of Bi₂O₃, into the PbO₂ film can reduce its particle size, change its crystal cell parameters, and narrow its bandgap (E_g). FP analysis reveals that the electrocatalytic activity of the Bi-PbO₂ electrode in the degradation of organic materials is higher than that of the PbO₂ electrode because more hydroxyl radicals can be generated on its surface. Electrochemical performance tests show that the modified electrode has a more negative flat-band potential (E_fb), larger active surface area, lower charge-transfer resistance, and higher oxygen-evolution potential; these characteristics promote the electrocatalytic activity of the Bi-PbO₂ electrode in the decomposition of organic materials.
- Bismuth,
- Lead dioxide,
- Bandgap,
- Flatband potential,
- Electro-catalytic activity
1. [1]
  (1) Martínez-Huitle, C. A.; Ferro, S. Chem. Soc. Rev. 2006, 35, 1324.
2. [2]
  (2) Awad, H. S.; Galwa, N. A. Chemosphere 2005, 61, 1327.
3. [3]
  (3) Panizza, M.; Cerisola, G. Electrochim. Acta 2003, 48, 3491.
4. [4]
  (4) Kokoh, K. B.; Hahn, F.; Belgsir, E. M.; Lamy, C.; Andrade, A. R.; Olivi, P.; Motheo, A. J.; Tremiliosi-Filho, G. Electrochim. Acta 2004, 49, 2077.
5. [5]
  (5) Andradea, L. S.; Rocha-Filhoa, R. C.; Bocchia, N.; Biaggioa, S. R.; Iniestab, J.; García-Garciab, V.; Montielb, V. J. Hazard Mater. 2008, 153, 252.
6. [6]
  (6) Kong, J.; Shi, S.; Kong, L.; Zhu, X.; Ni, J. Electrochim. Acta 2007, 53, 2048.
7. [7]
  (7) Song, Y.;Wei, G.; Xiong, R. Electrochim. Acta 2007, 52, 7022.
8. [8]
  (8) Ai, S.; Gao, M.; Zhang,W.;Wang, Q.; Xie, Y.; Jin, L. Talanta 2004, 62, 445.
9. [9]
  (9) Velichenko, A. B.; Amadelli, R.; Baranova, E. A. J. Electroanal. Chem. 2002, 527, 56.
10. [10]
  (10) Li, G.; Qu, J.; Zhang, X.; Ge, J. Water Res. 2006, 40, 213.
11. [11]
  (11) Tong, S.; Ma, C.; Feng, H. Electrochim. Acta 2008, 53, 3002.
12. [12]
  (12) Liu, Y.; Liu, H. Electrochim. Acta 2008, 53, 5077.
13. [13]
  (13) Anglada, A.; Urtiaga, A.; Ortiz, I. Environ. Sci. Technol. 2009, 43, 2035.
14. [14]
  (14) Lindsey, M. E.; Tarr, M. A. Chemosphere 2000, 41, 409.
15. [15]
  (15) Lindsey, M. E.; Tarr, M. A. Environ. Sci. Technol. 2000, 34, 444.
16. [16]
  (16) Baumanis, C.; Bahnemann, D.W. J. Phys. Chem. C 2008, 112, 19097.
17. [17]
  (17) Cong, Y.;Wu, Z. J. Phys. Chem. C 2007, 111, 3442.
18. [18]
  (18) Yua, N.; Gao, L.; Zhao, S.;Wang, Z. Electrochim. Acta 2009, 54, 3835.
19. [19]
  (19) Liu, H.; Liu, Y.; Zhang, C.; Shen, R. J. Appl. Electrochem. 2008, 38, 101.
20. [20]
  (20) Radecka, M.; Rekas, M.; Trenczek-Zajac, A.; Zakrzewska, K.; J. Power Sources 2008, 181, 46.
21. [21]
  (21) El-Bahy, Z. M.; Ismail, A. A.; Mohamed, R. M. J. Hazard. Mater. 2009, 166, 138.
22. [22]
  (22) Li, H.;Wang, D.; Fan, H.;Wang, P.; Jiang, T.; Xie, T. J. Colloid Interface Sci. 2011, 354, 175.
23. [23]
  (23) Banerjee, S.; Banerjee, S. Int. J. Eng. Sci. 2011, 3, 2134.
24. [24]
  (24) Ciríaco, L.; Anjo, C.; Correia, J.; Pacheco, M. J.; Lopes, A. Electrochim. Acta 2009, 54, 1464.
25. [25]
  (25) Kong, D.; Lu,W.; Feng, Y.; Bi, S. Prog. Chem. 2009, 21, 1107.
26. [26]
  (26) Harrington, S. P.; Devine, T. M. J. Electrochem. Soc. 2008, 155, 381.
27. [27]
  (27) Cheng, F.; Su, Y.; Liang, J.; Tao, Z. Chem. Mater. 2010, 22, 898.
28. [28]
  (28) Song, S.; Zhang, H.; Ma, X.; Shao, Z.; Baker, R. T.; Yi, B. Int . J. Hydrog. Energy 2008, 33, 4955.
29. [29]
  (29) Donne, S.W.; Kennedy, J. H. J. Appl. Electrochem. 2004, 34, 159.
30. [30]
  (30) Lao, G. H.; Shao, H. B.; Fan, Y. Q.;Wang, J. M.; Zhang, J. Q.; Cao, C. N. Acta Phys. -Chim. Sin. 2011, 27, 627. [劳国洪, 邵海波, 樊玉欠, 王建明, 张鉴清, 曹楚南. 物理化学学报, 2011, 27, 627.]
1. [1]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
2. [2]
  Jia Zhou , Huaying Zhong . Experimental Design of Computational Materials Science Combined with Machine Learning. University Chemistry, 2025, 40(3): 171-177. doi: 10.12461/PKU.DXHX202406004
3. [3]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
4. [4]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
5. [5]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
6. [6]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
7. [7]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
8. [8]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
9. [9]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
10. [10]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
11. [11]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
12. [12]
  Yifan ZHAO , Qiyun MAO , Meijing GUO , Guoying ZHANG , Tongliang HU . Z-scheme bismuth-based multi-site heterojunction: Synthesis and hydrogen production from photocatalytic hydrogen production. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1318-1330. doi: 10.11862/CJIC.20250001
13. [13]
  Huiwei Ding , Bo Peng , Zhihao Wang , Qiaofeng Han . Advances in Metal or Nonmetal Modification of Bismuth-Based Photocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2305048-0. doi: 10.3866/PKU.WHXB202305048
14. [14]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
15. [15]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
16. [16]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 2309047-0. doi: 10.3866/PKU.WHXB202309047
17. [17]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
18. [18]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-0. doi: 10.1016/j.actphy.2025.100074
19. [19]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
20. [20]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004

Get Citation

PDF

XML

Metrics

PDF Downloads(778)
Abstract views(2452)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Characterization of a Novel Bi-Doped PbO2 Electrode

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Characterization of a Novel Bi-Doped PbO₂ Electrode