Citation: ZHAO Lei, XU Xiang-Sheng, ZHANG Kai-Chao, YAN Xin-Huan. Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts[J]. Acta Physico-Chimica Sinica, ;2012, 28(04): 923-927. doi: 10.3866/PKU.WHXB201202081 shu

Selective Hydrogenation of Cinnamaldehyde with Efficient Assembled Pt-Fe/C Catalysts

1.
State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Received Date: 21 October 2011
Available Online: 8 February 2012

Platinum nanoparticles (d=2.0 nm) were obtained by decomposition of Pt₂(dba)₃ (dba: dibenzalacetone) and captured by active carbon modified with Fe to prepare a Pt-Fe/C catalyst. Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and energy dispersive X-ray spectrometry (EDS) were used to characterize the size, distribution, electronic state of the Pt and Fe nanoparticles, and surface elements of the catalysts. The catalysts selectively hydrogenated cinnamaldehyde (CAL) to cinnamyl alcohol (COL), and the activity was more than one time that of a Pt/C catalyst prepared by the impregnation method. The 1% (w, mass fraction)Pt-1.5% (w)Fe/C catalyst exhibited the highest activity and selectivity at 60 °C, 2.5 h, and 4.0 MPa H₂. The conversion for CAL was 99.2%, and the selectivity of CAL to COL was 85.0%.
- Pt,
- Fe,
- Active carbon,
- Cinnamaldehyde,
- Cinnamyl alcohol,
- Selective hydrogenation
1. [1]
  (1) Arvela, P. M.; Hajek, J.; Salmi, T.; Murzin, D. Y. Appl. Catal. A: Gen. 2005, 292, 1.
2. [2]
  (2) Gallezot, P.; Richard, D. Catal. Rev. 1998, 40, 81.
3. [3]
  (3) Chen, X. F.; Li, H. X.; Dai,W. L. Appl. Catal. A: Gen. 2003, 253, 359.
4. [4]
  (4) Li, H. X.; Chen, X. F.;Wang, M. H. Appl. Catal. A: Gen. 2002, 225, 117.
5. [5]
  (5) Wang, H.; Shu, Y. Y.; Zheng, M. Y. Catal. Lett. 2008, 124, 219.
6. [6]
  (6) Galletti, A. M. R.; Antonetti, C.; Venezia, A. M.; Giambastiani, G. Appl. Catal. A: Gen. 2010, 386, 124.
7. [7]
  (7) Qiu, J. S.; Zhang, H. Z.;Wang, X. N. Catal. Lett. 2006, 88, 269.
8. [8]
  (8) Li, Y.; Li, Z. G.; Zhou, R. X. J. Mol. Catal. A 2008, 279, 140.
9. [9]
  (9) Mahata, N.; ncalves, F.; Pereira, M. F. R.; Figueiredo, J. L. Appl. Catal. A: Gen. 2008, 339, 159.
10. [10]
  (10) Hajek, J.; Murzin, D. Y. Chem. Res. 2004, 43, 2030.
11. [11]
  (11) Hajek, J.;Warna, J.; Murzin, D. Y. Chem. Res. 2004, 43, 2039.
12. [12]
  (12) Carrillo, J. H.; Aramendia, M. A.; Marinas, A.; Marinas, J. M.; Urbano, F. J. Appl. Catal. A: Gen. 2010, 385, 190.
13. [13]
  (13) Hsu, C. Y.; Chiu, T. C.; Shih, M. H.; Tsai,W. J.; Chen,W. Y.; Lin, C. H. J. Phys. Chem. 2010, 114, 4502.
14. [14]
  (14) Chatterjee, M.; Ikushima, Y.; Yokoyama, T.; Suzuki, T. Microporous Mesoporous Mat. 2009, 117, 201.
15. [15]
  (15) Plomp, A. J.; Vuori, H.; Krause, A. O. I.; Jong, K. P.; Bitter, J. H. Appl. Catal. A: Gen. 2008, 351, 9.
16. [16]
  (16) Li, Y.; Ge, C. H.; Zhao, J.; Zhou, R. X. Catal. Lett. 2008, 126, 280.
17. [17]
  (17) Ma, H. X.;Wang, L. C.; Chen, L. Y.; Dong, C.; Yu,W. C.; Huang, T.; Qian, Y. T. Catal. Commun. 2007, 8, 452.
18. [18]
  (18) Han, X. X.; Zhou, R. X.; Yue, B. H.; Zheng, X. M. Catal. Lett. 2006, 109, 3.
19. [19]
  (19) Mao, J. Z.; Yan, X. H.; Gu, H. Z.; Jiang, L. C. Chin. J. Catal. 2009, 30, 182. [毛建忠, 严新焕, 顾辉子, 江玲超. 催化学报, 2009, 30, 182.]
20. [20]
  (20) Englisch, M.; Ranade, V. S.; Lercher, J. A. Mol. Catal. A: Chem. 1997, 121, 69.
21. [21]
  (21) Amornpattana,W. K.;Winterbottom, J. M. Catal. Today 2001, 66, 277.
1. [1]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
2. [2]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
3. [3]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
4. [4]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
5. [5]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
6. [6]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . Hollow AgPt@Pt core-shell cocatalyst with electron-rich Pt^δ^- shell for boosting selectivity of photocatalytic H₂O₂ production for faceted BiVO₄. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-. doi: 10.1016/j.actphy.2025.100081
7. [7]
  Yukun Chang , Haoqin Huang , Baolei Wang . Preparation of Trans-Cinnamic Acid via “One-Pot” Protocol of Aldol Condensation-Hydrolysis Reaction: Recommending an Improved Organic Synthesis Experiment. University Chemistry, 2024, 39(4): 322-328. doi: 10.3866/PKU.DXHX202309095
8. [8]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
9. [9]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
10. [10]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
11. [11]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
12. [12]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
13. [13]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
14. [14]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
15. [15]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
16. [16]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
17. [17]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
18. [18]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
19. [19]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
20. [20]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003

Get Citation

PDF

XML

Metrics

PDF Downloads(865)
Abstract views(2605)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142