Citation: GUO Pei-Zhi, JI Qian-Qian, ZHANG Li-Li, ZHAO Shan-Yu, ZHAO Xiu-Song. Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2011, 27(12): 2836-2840. doi: 10.3866/PKU.WHXB20112836 shu

Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors

1.
1. Laboratory of New Fiber Materials and Modern Textile, the Growing Base for State Key Laboratory, School of Chemistry,Chemical Engineering and Environmental Sciences, Qingdao University, Qingdao 266071, Shandong Province,P. R. China;
2. Department of Chemical and Biomolecular Engineering, National University of Singapore,4 Engineering Drive 4, Singapore 117576

Received Date: 18 July 2011
Available Online: 13 October 2011
Fund Project: 国家自然科学基金(20803037, 21143006) (20803037, 21143006) 青岛市应用基础研究项目(11-2-4-2-(8)-jch) (11-2-4-2-(8)-jch)

Microporous carbons (PSC-1 and PSC-2) were obtained directly by the carbonization of peanut shells without and with NaOH solution pretreatment, respectively. Both samples have a main pore size of ~0.8 nm. The surface area increases from 552 m²·g^-1 for PSC-1 to 726 m²·g^-1 for PSC-2. Cyclic voltammograms (CVs) of the PSC-1 and PSC-2 electrodes and the symmetrical supercapacitors show almost rectangular shape indicating excellent capacitance features. The specific capacitances of PSC-1 and PSC-2 can reach 233 and 378 F·g^-1, respectively, at a current density of 0.1 A·g^-1 in a three-electrode system using porous carbon as the working electrode, a platinum electrode as the counter electrode and a Ag/AgCl electrode as the reference electrode. Furthermore, the electrodes in both three-electrode systems and supercapacitors show high stability and capacitance retainability after 1000 cycles. The formation mechanisms for the two microporous carbons and the relationship between the carbon materials and their electrochemical properties are discussed based on the experimental results.
- Supercapacitor,
- Electrode,
- Microporous carbon,
- Peanut shell,
- Capacitance
1. [1]
  (1) Chmiola, J.; Yushin, G.; tsi, Y.; Portet, C.; Simon, P.; Taberna, P. L. Science 2006, 313, 1760.
2. [2]
  (2) Winter, M.; Brodd, R. J. Chem. Rev. 2004, 104, 4245.
3. [3]
  (3) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; Kluwer Academic/Plenum Publisher: New York, 1999.
4. [4]
  (4) Burke, A. J. Power Sources 2000, 91, 37.
5. [5]
  (5) Kötz, R.; Carlen, M. Electrochim. Acta 2000, 45, 2483.
6. [6]
  (6) Zhang, L. L.; Zhao, X. S. Chem. Soc. Rev. 2009, 38, 2520.
7. [7]
  (7) Alvarez, S.; Blanco-Lopez, C.; Miranda-Ordieres, A. J.; Fuertes, A. B.; Centeno, T. A. Carbon 2005, 43, 866-870.
8. [8]
  (8) Li,W.; Zhou, J.; Xing,W.; Zhuo, S. P.; Lü, Y. M. Acta Phys. -Chim. Sin. 2011, 27, 620. [李文, 周晋, 邢伟, 禚淑萍, 吕忆民. 物理化学学报, 2011, 27, 620.]
9. [9]
  (9) Wang, D.W.; Li, F.; Liu, M.; Lu, G. Q.; Cheng, H. M. Angew. Chem. Int. Ed. 2008, 47, 373.
10. [10]
  (10) Raymundo-Piñero, E.; Leroux, F.; Béguin, F. Adv. Mater. 2006, 18, 1877.
11. [11]
  (11) Ji, Q. Q.; Guo, P. Z.; Zhao, X. S. Acta Phys. –Chim. Sin. 2010, 26, 1254. [季倩倩, 郭培志, 赵修松. 物理化学学报, 2010, 26, 1254.]
12. [12]
  (12) Zhang, C. X.; Long, D. H.; Xing, B. L.; Qiao,W. M.; Zhang, R.; Zhan, L.; Liang, X. Y.; Ling, L. C. Electrochem. Commun. 2008, 10, 1809.
13. [13]
  (13) Vilaplana-Orte , E.; Lillo-Ródenas, M. A.; Alcañiz-Monge, J.; Cazorla-Amorós, D.; Linares-Solano, A. Carbon 2009, 47, 2141.
14. [14]
  (14) Wilson, K.; Yang, H.; Seo C.W.; MarshallW. E. Bioresour. Technol. 2006, 97, 2266.
15. [15]
  (15) Watanabe, I.; Doi, T.; Yamaki, J.; Lin, Y. Y.; Fey, G. T. K. J. Power Sources 2008, 176, 347.
16. [16]
  (16) Girgis, B. S.; Yunis, S. S.; Soliman, A. F. Mater. Lett. 2002, 57, 164.
17. [17]
  (17) Li, Y. H.; Du, Q. J.;Wang, X. D.; Zhang, P.;Wang, D. C.;Wang, Z. H.; Xia, Y. Z. J. J. Hazard. Mater. 2010, 183, 583.
18. [18]
  (18) Yang, J.; Qiu, K. Q. Chem. Eng. J. 2010, 165, 209.
19. [19]
  (19) Garg, U. K.; Kaur, M. P.; Garg, V. K.; Sud, D. J. Hazard. Mater. 2007, 140, 60.
20. [20]
  (20) Singh, K. P.; Mohan, D.; Sinha, S.; Tondon, G. S.; sh, D. Ind. Eng. Chem. Res. 2003, 42, 1965.
21. [21]
  (21) Kara z, S.; Tay, T.; Ucar, S.; Erdem, M. Bioresour. Technol. 2008, 99, 6214.
22. [22]
  (22) Wang, L. L.; Han, G. T.; Zhang, Y. M. Carbohyd. Polym. 2007, 69, 391.
23. [23]
  (23) Janes, A.; Permann, L.; Arulepp, M.; Lust, E. Electrochem. Commun. 2004, 6, 313.
24. [24]
  (24) Wang, D.W.; Li, F.; Zhao, J. P.; Ren,W. C.; Chen, Z. G.; Tan, J.;Wu, Z. S.; Gentle, I.; Lu, G. Q.; Cheng, H. M. ACS Nano 2009, 3, 1745.
25. [25]
  (25) Peng, C.; Jin, J.; Chen, G. Z. Electrochim. Acta 2007, 53, 525.
26. [26]
  (26) Zheng, J. P. J. Electrochem. Soc. 2003, 150, A484.
27. [27]
  (27) Eliad, L.; Salitra, G.; Soffer, A.; Aurbach, D. J. Phys. Chem. B 2002, 106, 10128.
28. [28]
  (28) Yang, X. H.;Wang, Y. G.; Xiong, H. M.; Xia, Y. Y. Electrochim. Acta 2007, 53, 752.
29. [29]
  (29) Stoller, M. D.; Ruoff, R. S. Energy Environ. Sci. 2010, 3, 1294.
30. [30]
  (30) Khomenko, V.; Frackowiak, E.; Béguin, F. Electrochim. Acta 2005, 50, 2499.
1. [1]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
2. [2]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-0. doi: 10.1016/j.actphy.2025.100063
3. [3]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
4. [4]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . Preparation of High Density Activated Carbon by Mechanical Compression of Precursors for Compact Capacitive Energy Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-0. doi: 10.3866/PKU.WHXB202406009
5. [5]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
6. [6]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
7. [7]
  Yingtong FAN , Yujin YAO , Shouhao WAN , Yihang SHEN , Xiang GAO , Cuie ZHAO . Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043
8. [8]
  Huimin Liu , Kezhi Li , Xin Zhang , Xuemin Yin , Qiangang Fu , Hejun Li . SiC Nanomaterials and Their Derived Carbons for High-Performance Supercapacitors. Acta Physico-Chimica Sinica, 2024, 40(2): 2304026-0. doi: 10.3866/PKU.WHXB202304026
9. [9]
  Qing Xue , Shengyi Li , Yanan Zhao , Peng Sheng , Li Xu , Zhengxi Li , Bo Zhang , Hui Li , Bo Wang , Libin Yang , Yuliang Cao , Zhongxue Chen . Novel Alkaline Sodium-Ion Battery Capacitor Based on Active Carbon||Na_0.44MnO₂ towards Low Cost, High-Rate Capability and Long-Term Lifespan. Acta Physico-Chimica Sinica, 2024, 40(2): 2303041-0. doi: 10.3866/PKU.WHXB202303041
10. [10]
  Zeqiu Chen , Limiao Cai , Jie Guan , Zhanyang Li , Hao Wang , Yaoguang Guo , Xingtao Xu , Likun Pan . Advanced electrode materials in capacitive deionization for efficient lithium extraction. Acta Physico-Chimica Sinica, 2025, 41(8): 100089-0. doi: 10.1016/j.actphy.2025.100089
11. [11]
  Jun Huang , Pengfei Nie , Yongchao Lu , Jiayang Li , Yiwen Wang , Jianyun Liu . 丝光沸石负载自支撑氮掺杂多孔碳纳米纤维电容器及高效选择性去除硬度离子. Acta Physico-Chimica Sinica, 2025, 41(7): 100066-0. doi: 10.1016/j.actphy.2025.100066
12. [12]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
13. [13]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yamauchi Yusuke , Melhi Saad , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 2404006-0. doi: 10.3866/PKU.WHXB202404006
14. [14]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
15. [15]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
16. [16]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
17. [17]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
18. [18]
  Hongren RONG , Gexiang GAO , Zhiwei LIU , Ke ZHOU , Lixin SU , Hao HUANG , Wenlong LIU , Qi LIU . High-performance supercapacitor based on 1D cobalt-based coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034
19. [19]
  Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-0. doi: 10.1016/j.actphy.2025.100072
20. [20]
  Xiaochen Zhang , Fei Yu , Jie Ma . Cutting-Edge Applications of Multi-Angle Numerical Simulations for Capacitive Deionization. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-0. doi: 10.3866/PKU.WHXB202311026

Get Citation

PDF

XML

Metrics

PDF Downloads(1323)
Abstract views(3251)
HTML views(35)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142