Citation: ZHAO Jing-Mao, LI Jun. Corrosion Inhibition Performance of Carbon Steel in Brine Solution Containing H₂S and CO₂by Novel Gemini Surfactants[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 623-629. doi: 10.3866/PKU.WHXB201112293 shu

Corrosion Inhibition Performance of Carbon Steel in Brine Solution Containing H₂S and CO₂by Novel Gemini Surfactants

ZHAO Jing-Mao ,
LI Jun

1.
College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received Date: 17 October 2011
Available Online: 29 December 2011
Fund Project: 国家自然科学基金(51171013)资助项目 (51171013)

A series of novel gemini surfactants containing hydroxyl group have been synthesized including 1,3-bis(dodecyl dimethyl ammonium chloride)-2-propanol, 1,3-bis(myristyl dimethyl ammonium chloride)-2-propanol, 1,3-bis(hexadecyl dimethyl ammonium chloride)-2-propanol, and 1,3-bis(octadecyl dimethyl ammonium chloride)-2-propanol, designated as n-3OH-n (n=12, 14, 16, 18, respectively). The corrosion inhibition for carbon steel in brine solution containing H₂S and CO₂ was investigated using weight loss method, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). The results showed that the inhibition efficiencies (IEs) obtained from all of the methods employed demonstrated a clear trend, with the IEs of the gemini surfactants ranked as 14-3OH-14>12-3OH-12> 16-3OH-16>18-3OH-18. Among them, 14-3OH-14 and 12-3OH-12 acted as excellent corrosion inhibitors with IE values greater than 95% at an additive concentration of 35 mg·L^-1. Potentiodynamic polarization curves clearly revealed that the gemini surfactants are mixed-type inhibitors which preferentially inhibit the anodic corrosion process. Adsorption of the synthesized gemini surfactants n-3OH-n (n=12, 14, 16) onto a carbon steel surface obeys the Langmuir adsorption isotherm and they exhibit a mixed physical and chemical adsorption. An adsorption model was proposed to elucidate the inhibition mechanism of gemini surfactants.
- Corrosion inhibitor,
- Gemini surfactant,
- Corrosion,
- Hydrogen sulfide,
- Carbon dioxide
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Corrosion Inhibition Performance of Carbon Steel in Brine Solution Containing H₂S and CO₂by Novel Gemini Surfactants